Synthesis, characterization of new homo and heteronuclear Schiff base copper(II) complexes
This article describes the synthesis of isonitrosomethyl-p-tolyl ketone [HL] as the starting material and then we prepared the schiff base ligand from the reactions of the amine compounds with o-phenylenediamine [H2L1]. A new series of mono-, homo and heterodinuclear copper(II)/nickel(II) complexes...
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| Format: | Article |
| Language: | English |
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Turkish Chemical Society
2018-01-01
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| Series: | Journal of the Turkish Chemical Society, Section A: Chemistry |
| Subjects: | |
| Online Access: | http://dergipark.gov.tr/jotcsa/issue/33408/324878 |
| _version_ | 1797922762374774784 |
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| author | Tufan Topal Emin Karapınar |
| author_facet | Tufan Topal Emin Karapınar |
| author_sort | Tufan Topal |
| collection | DOAJ |
| description | This article describes the synthesis of isonitrosomethyl-p-tolyl ketone [HL] as the starting material and then we prepared the schiff base ligand from the reactions of the amine compounds with o-phenylenediamine [H2L1]. A new series of mono-, homo and heterodinuclear copper(II)/nickel(II) complexes have been synthesized using an oxime ligand. The complexes were characterized by IR, elemental analysis, magnetic moment measurements, molar conductivity, mass spectra and TGA studies. The free ligand were also described 13C and 1H-NMR spectra. For complexes using stoichiometric and spectroscopic data of the metal complexes showed that metal:ligand ratio of mononuclear copper(II) complex was found to be 1:1 while this ratio was 2:1 in homo- and heterodinuclear copper(II) complex and 3:2 in the trinuclear copper (II) complex and metal ions are coordinated to the imine and oxime nitrogen atoms. |
| first_indexed | 2024-04-10T14:36:30Z |
| format | Article |
| id | doaj.art-c768c7d24668491f82008707869aea27 |
| institution | Directory Open Access Journal |
| issn | 2149-0120 2149-0120 |
| language | English |
| last_indexed | 2024-04-10T14:36:30Z |
| publishDate | 2018-01-01 |
| publisher | Turkish Chemical Society |
| record_format | Article |
| series | Journal of the Turkish Chemical Society, Section A: Chemistry |
| spelling | doaj.art-c768c7d24668491f82008707869aea272023-02-15T16:08:33ZengTurkish Chemical SocietyJournal of the Turkish Chemical Society, Section A: Chemistry2149-01202149-01202018-01-015278580210.18596/jotcsa.324878Synthesis, characterization of new homo and heteronuclear Schiff base copper(II) complexesTufan TopalEmin KarapınarThis article describes the synthesis of isonitrosomethyl-p-tolyl ketone [HL] as the starting material and then we prepared the schiff base ligand from the reactions of the amine compounds with o-phenylenediamine [H2L1]. A new series of mono-, homo and heterodinuclear copper(II)/nickel(II) complexes have been synthesized using an oxime ligand. The complexes were characterized by IR, elemental analysis, magnetic moment measurements, molar conductivity, mass spectra and TGA studies. The free ligand were also described 13C and 1H-NMR spectra. For complexes using stoichiometric and spectroscopic data of the metal complexes showed that metal:ligand ratio of mononuclear copper(II) complex was found to be 1:1 while this ratio was 2:1 in homo- and heterodinuclear copper(II) complex and 3:2 in the trinuclear copper (II) complex and metal ions are coordinated to the imine and oxime nitrogen atoms.http://dergipark.gov.tr/jotcsa/issue/33408/324878Schiff baseheteronucleartrinuclearnickel |
| spellingShingle | Tufan Topal Emin Karapınar Synthesis, characterization of new homo and heteronuclear Schiff base copper(II) complexes Journal of the Turkish Chemical Society, Section A: Chemistry Schiff base heteronuclear trinuclear nickel |
| title | Synthesis, characterization of new homo and heteronuclear Schiff base copper(II) complexes |
| title_full | Synthesis, characterization of new homo and heteronuclear Schiff base copper(II) complexes |
| title_fullStr | Synthesis, characterization of new homo and heteronuclear Schiff base copper(II) complexes |
| title_full_unstemmed | Synthesis, characterization of new homo and heteronuclear Schiff base copper(II) complexes |
| title_short | Synthesis, characterization of new homo and heteronuclear Schiff base copper(II) complexes |
| title_sort | synthesis characterization of new homo and heteronuclear schiff base copper ii complexes |
| topic | Schiff base heteronuclear trinuclear nickel |
| url | http://dergipark.gov.tr/jotcsa/issue/33408/324878 |
| work_keys_str_mv | AT tufantopal synthesischaracterizationofnewhomoandheteronuclearschiffbasecopperiicomplexes AT eminkarapınar synthesischaracterizationofnewhomoandheteronuclearschiffbasecopperiicomplexes |