Microwave Heating Improvement: Permittivity Characterization of Water–Ethanol and Water–NaCl Binary Mixtures

Microwave heating offers a lot of advantages compared to conventional heating methods in the chemical reactions field due to its positive effects on reaction time and selectivity. Dielectric properties, and in particular permittivity, of substances and mixtures, are important for the optimization of...

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Main Authors: Fabio Fanari, Giacomo Muntoni, Chiara Dachena, Renzo Carta, Francesco Desogus
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/13/18/4861
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author Fabio Fanari
Giacomo Muntoni
Chiara Dachena
Renzo Carta
Francesco Desogus
author_facet Fabio Fanari
Giacomo Muntoni
Chiara Dachena
Renzo Carta
Francesco Desogus
author_sort Fabio Fanari
collection DOAJ
description Microwave heating offers a lot of advantages compared to conventional heating methods in the chemical reactions field due to its positive effects on reaction time and selectivity. Dielectric properties, and in particular permittivity, of substances and mixtures, are important for the optimization of microwave heating processes; notwithstanding this, specific databases are poor and far from being complete, and in the scientific literature very little data regarding these properties can be found. In this work, impedance measurements were carried out using a specially designed system to get the real and imaginary parts of the dielectric constant. The apparatus was tested in the estimation of permittivity of water–ethanol and water–NaCl mixtures, varying their composition to obtain a wide range of permittivity values. The results were compared to literature data and fitted with available literature models to verify the correspondence between them, finding that permittivity dependence on mixture composition can be effectively described by the models.
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spelling doaj.art-c772d2ec24d04483a4167a0db0fc296a2023-11-20T14:01:58ZengMDPI AGEnergies1996-10732020-09-011318486110.3390/en13184861Microwave Heating Improvement: Permittivity Characterization of Water–Ethanol and Water–NaCl Binary MixturesFabio Fanari0Giacomo Muntoni1Chiara Dachena2Renzo Carta3Francesco Desogus4Department of Mechanical, Chemical and Material Engineering, University of Cagliari, 09123 Cagliari, ItalyDepartment of Electric and Electronic Engineering, University of Cagliari, 09123 Cagliari, ItalyDepartment of Electric and Electronic Engineering, University of Cagliari, 09123 Cagliari, ItalyDepartment of Mechanical, Chemical and Material Engineering, University of Cagliari, 09123 Cagliari, ItalyDepartment of Mechanical, Chemical and Material Engineering, University of Cagliari, 09123 Cagliari, ItalyMicrowave heating offers a lot of advantages compared to conventional heating methods in the chemical reactions field due to its positive effects on reaction time and selectivity. Dielectric properties, and in particular permittivity, of substances and mixtures, are important for the optimization of microwave heating processes; notwithstanding this, specific databases are poor and far from being complete, and in the scientific literature very little data regarding these properties can be found. In this work, impedance measurements were carried out using a specially designed system to get the real and imaginary parts of the dielectric constant. The apparatus was tested in the estimation of permittivity of water–ethanol and water–NaCl mixtures, varying their composition to obtain a wide range of permittivity values. The results were compared to literature data and fitted with available literature models to verify the correspondence between them, finding that permittivity dependence on mixture composition can be effectively described by the models.https://www.mdpi.com/1996-1073/13/18/4861Acree modeldielectric constantethanolimpedanceKing and Queen modelmicrowave heating
spellingShingle Fabio Fanari
Giacomo Muntoni
Chiara Dachena
Renzo Carta
Francesco Desogus
Microwave Heating Improvement: Permittivity Characterization of Water–Ethanol and Water–NaCl Binary Mixtures
Energies
Acree model
dielectric constant
ethanol
impedance
King and Queen model
microwave heating
title Microwave Heating Improvement: Permittivity Characterization of Water–Ethanol and Water–NaCl Binary Mixtures
title_full Microwave Heating Improvement: Permittivity Characterization of Water–Ethanol and Water–NaCl Binary Mixtures
title_fullStr Microwave Heating Improvement: Permittivity Characterization of Water–Ethanol and Water–NaCl Binary Mixtures
title_full_unstemmed Microwave Heating Improvement: Permittivity Characterization of Water–Ethanol and Water–NaCl Binary Mixtures
title_short Microwave Heating Improvement: Permittivity Characterization of Water–Ethanol and Water–NaCl Binary Mixtures
title_sort microwave heating improvement permittivity characterization of water ethanol and water nacl binary mixtures
topic Acree model
dielectric constant
ethanol
impedance
King and Queen model
microwave heating
url https://www.mdpi.com/1996-1073/13/18/4861
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