(Methanol-κO){1-[2-(piperazin-4-ium-1-yl-κN1)ethyliminomethyl-κN]naphthalen-2-olato-κO}bis(thiocyanato-κN)nickel(II) methanol monosolvate
In the title solvated complex, [Ni(C17H21N3O)(NCS)2(CH3OH)]·CH3OH, the Ni2+ ion is coordinated by one phenolate O, one imine N, and one amine N atom of the tridentate Schiff base ligand, two thiocyanate N atoms and one methanol O atom, resulting in a distorted cis-NiO2N4 octahedral geom...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812013773 |
| _version_ | 1818999211368120320 |
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| author | Pin-Ai Li |
| author_facet | Pin-Ai Li |
| author_sort | Pin-Ai Li |
| collection | DOAJ |
| description | In the title solvated complex, [Ni(C17H21N3O)(NCS)2(CH3OH)]·CH3OH, the Ni2+ ion is coordinated by one phenolate O, one imine N, and one amine N atom of the tridentate Schiff base ligand, two thiocyanate N atoms and one methanol O atom, resulting in a distorted cis-NiO2N4 octahedral geometry. The chelate ring formed by the phenolate O and imine N atoms approximates to an envelope with the Ni atom as the flap, whereas the chelate ring formed by the two N atoms is twisted about the C—C bond. In the crystal, the components are linked by O—H...O, N—H...O, N—H...S, and O—H...S hydrogen bonds. |
| first_indexed | 2024-12-20T22:13:49Z |
| format | Article |
| id | doaj.art-c77464dc62084e1ab4ea847be2e02cd2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:13:49Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c77464dc62084e1ab4ea847be2e02cd22022-12-21T19:25:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m549m54910.1107/S1600536812013773(Methanol-κO){1-[2-(piperazin-4-ium-1-yl-κN1)ethyliminomethyl-κN]naphthalen-2-olato-κO}bis(thiocyanato-κN)nickel(II) methanol monosolvatePin-Ai LiIn the title solvated complex, [Ni(C17H21N3O)(NCS)2(CH3OH)]·CH3OH, the Ni2+ ion is coordinated by one phenolate O, one imine N, and one amine N atom of the tridentate Schiff base ligand, two thiocyanate N atoms and one methanol O atom, resulting in a distorted cis-NiO2N4 octahedral geometry. The chelate ring formed by the phenolate O and imine N atoms approximates to an envelope with the Ni atom as the flap, whereas the chelate ring formed by the two N atoms is twisted about the C—C bond. In the crystal, the components are linked by O—H...O, N—H...O, N—H...S, and O—H...S hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812013773 |
| spellingShingle | Pin-Ai Li (Methanol-κO){1-[2-(piperazin-4-ium-1-yl-κN1)ethyliminomethyl-κN]naphthalen-2-olato-κO}bis(thiocyanato-κN)nickel(II) methanol monosolvate Acta Crystallographica Section E |
| title | (Methanol-κO){1-[2-(piperazin-4-ium-1-yl-κN1)ethyliminomethyl-κN]naphthalen-2-olato-κO}bis(thiocyanato-κN)nickel(II) methanol monosolvate |
| title_full | (Methanol-κO){1-[2-(piperazin-4-ium-1-yl-κN1)ethyliminomethyl-κN]naphthalen-2-olato-κO}bis(thiocyanato-κN)nickel(II) methanol monosolvate |
| title_fullStr | (Methanol-κO){1-[2-(piperazin-4-ium-1-yl-κN1)ethyliminomethyl-κN]naphthalen-2-olato-κO}bis(thiocyanato-κN)nickel(II) methanol monosolvate |
| title_full_unstemmed | (Methanol-κO){1-[2-(piperazin-4-ium-1-yl-κN1)ethyliminomethyl-κN]naphthalen-2-olato-κO}bis(thiocyanato-κN)nickel(II) methanol monosolvate |
| title_short | (Methanol-κO){1-[2-(piperazin-4-ium-1-yl-κN1)ethyliminomethyl-κN]naphthalen-2-olato-κO}bis(thiocyanato-κN)nickel(II) methanol monosolvate |
| title_sort | methanol amp 954 o 1 2 piperazin 4 ium 1 yl amp 954 n1 ethyliminomethyl amp 954 n naphthalen 2 olato amp 954 o bis thiocyanato amp 954 n nickel ii methanol monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812013773 |
| work_keys_str_mv | AT pinaili methanolamp954o12piperazin4ium1ylamp954n1ethyliminomethylamp954nnaphthalen2olatoamp954obisthiocyanatoamp954nnickeliimethanolmonosolvate |