cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate
The metal site in the title compound [MnCl2(C12H12N2)2]·2.5H2O has a distorted octahedral geometry, coordinated by four N atoms of two 5,5′-dimethyl-2,2′-dipyridine ligands and two Cl atoms. Two and a half water molecules of hydration per complex unit are obs...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811021805 |
| _version_ | 1818959641957105664 |
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| author | Lívia Batista Lopes Charlane Cimini Corrêa Renata Diniz |
| author_facet | Lívia Batista Lopes Charlane Cimini Corrêa Renata Diniz |
| author_sort | Lívia Batista Lopes |
| collection | DOAJ |
| description | The metal site in the title compound [MnCl2(C12H12N2)2]·2.5H2O has a distorted octahedral geometry, coordinated by four N atoms of two 5,5′-dimethyl-2,2′-dipyridine ligands and two Cl atoms. Two and a half water molecules of hydration per complex unit are observed in the crystal structure. The compounds extend along the c axis with O—H...Cl, O—H...O, C—H...Cl and C—H...O hydrogen bonds and π–π interactions [centroid-centroid distance = 3.70 (2) Å] contributing substantially to the crystal packing. The Mn and one of the water O atoms, the latter being half-occupied, are located on special positions, in this case a rotation axis of order 2. |
| first_indexed | 2024-12-20T11:44:53Z |
| format | Article |
| id | doaj.art-c781478eb39145a7b480502bd3b20e29 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:44:53Z |
| publishDate | 2011-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c781478eb39145a7b480502bd3b20e292022-12-21T19:41:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m906m90710.1107/S1600536811021805cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrateLívia Batista LopesCharlane Cimini CorrêaRenata DinizThe metal site in the title compound [MnCl2(C12H12N2)2]·2.5H2O has a distorted octahedral geometry, coordinated by four N atoms of two 5,5′-dimethyl-2,2′-dipyridine ligands and two Cl atoms. Two and a half water molecules of hydration per complex unit are observed in the crystal structure. The compounds extend along the c axis with O—H...Cl, O—H...O, C—H...Cl and C—H...O hydrogen bonds and π–π interactions [centroid-centroid distance = 3.70 (2) Å] contributing substantially to the crystal packing. The Mn and one of the water O atoms, the latter being half-occupied, are located on special positions, in this case a rotation axis of order 2.http://scripts.iucr.org/cgi-bin/paper?S1600536811021805 |
| spellingShingle | Lívia Batista Lopes Charlane Cimini Corrêa Renata Diniz cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate Acta Crystallographica Section E |
| title | cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate |
| title_full | cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate |
| title_fullStr | cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate |
| title_full_unstemmed | cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate |
| title_short | cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate |
| title_sort | cis dichloridobis 5 5 amp 8242 dimethyl 2 2 amp 8242 bipyridine manganese ii 2 5 hydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811021805 |
| work_keys_str_mv | AT lamp237viabatistalopes cisdichloridobis55amp8242dimethyl22amp8242bipyridinemanganeseii25hydrate AT charlaneciminicorramp234a cisdichloridobis55amp8242dimethyl22amp8242bipyridinemanganeseii25hydrate AT renatadiniz cisdichloridobis55amp8242dimethyl22amp8242bipyridinemanganeseii25hydrate |