catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]
In the crystal structure of the title compound, [Fe3(NCS)6(C4H4N2)8]n, each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thiocyanate anions in a distorted octahedral environment. The asymmetric unit consists of one iron cation located on a crystallographic cent...
| Format: | Article |
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| Language: | English |
| Published: |
International Union of Crystallography
2009-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809005509 |
| _version_ | 1818282914400436224 |
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| collection | DOAJ |
| description | In the crystal structure of the title compound, [Fe3(NCS)6(C4H4N2)8]n, each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thiocyanate anions in a distorted octahedral environment. The asymmetric unit consists of one iron cation located on a crystallographic center of inversion, as well as one iron cation, three thiocyanate anions and four pyrimidine ligands occupying general positions. The structure consists of square secondary building units (SBUs) with an Fe atom at each corner, which are μ-N1:N3-bridged by the pyrimidine ligands. The SBUs are linked into infinite chains running in the c-axis direction via common opposite corners. |
| first_indexed | 2024-12-13T00:28:35Z |
| format | Article |
| id | doaj.art-c7ae9a8d3e7d4fc3aaaa238c26b60af3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:28:35Z |
| publishDate | 2009-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c7ae9a8d3e7d4fc3aaaa238c26b60af32022-12-22T00:05:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653m296m29710.1107/S1600536809005509catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]In the crystal structure of the title compound, [Fe3(NCS)6(C4H4N2)8]n, each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thiocyanate anions in a distorted octahedral environment. The asymmetric unit consists of one iron cation located on a crystallographic center of inversion, as well as one iron cation, three thiocyanate anions and four pyrimidine ligands occupying general positions. The structure consists of square secondary building units (SBUs) with an Fe atom at each corner, which are μ-N1:N3-bridged by the pyrimidine ligands. The SBUs are linked into infinite chains running in the c-axis direction via common opposite corners.http://scripts.iucr.org/cgi-bin/paper?S1600536809005509 |
| spellingShingle | catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine] Acta Crystallographica Section E |
| title | catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine] |
| title_full | catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine] |
| title_fullStr | catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine] |
| title_full_unstemmed | catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine] |
| title_short | catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine] |
| title_sort | catena poly bis cis dipyrimidine trans dithiocyanatoiron ii di amp 956 pyrimidine trans dithiocyanatoiron ii di amp 956 pyrimidine |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809005509 |