Release of phosphorus, aluminium and iron in fractionation of inorganic soil phosphorus

Release of phosphorus, aluminium and iron by a modified Chang and Jackson procedure was studied in five mineral soils. Quantities of aluminium and iron released during the procedure and extracted by acid ammonium oxalate were compared. The extractability of P, Al and Fe by 1 M NH4CI and that of Al a...

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Main Author: Raina Niskanen
Format: Article
Language:English
Published: Scientific Agricultural Society of Finland 1987-04-01
Series:Agricultural and Food Science
Online Access:https://journal.fi/afs/article/view/72256
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author Raina Niskanen
author_facet Raina Niskanen
author_sort Raina Niskanen
collection DOAJ
description Release of phosphorus, aluminium and iron by a modified Chang and Jackson procedure was studied in five mineral soils. Quantities of aluminium and iron released during the procedure and extracted by acid ammonium oxalate were compared. The extractability of P, Al and Fe by 1 M NH4CI and that of Al and Fe by alkaline 0.5 M NH4F was poor. Proportions of P extracted by 0.5 M NH4F (0.2—10.4 mmol/kg soil) and 0.1 M NaOH (0.1— 9.8 mmol/kg soil) were related to the molar ratio of oxalate-extractable iron and aluminium. P extracted by 0.25 M H2SO4 amounted to 2.1—12.2 mmol/kg soil. Al extracted by 0.1 M NaOH (7—174 mmol/kg soil) and 0.25 M H2SO4 (17—112 mmol/kg soil) amounted to 55—94 % and 16—245 % of oxalate-extractable Al, respectively. Fe released by 0.1 M NaOH (1—10 mmol/kg soil) and 0.25 M H2SO4 (30—196 mmol/kg soil) amounted to 1—13 % and 62—272 % of oxalate-extractable Fe, respectively. In total, 91—309 % of oxalate-extractable Al and 70—285 % of oxalate-extractable Fe were released by NaOH and H2SO4.
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spelling doaj.art-c7c0512a4d944f8b8015adb734cd07b22022-12-22T00:58:05ZengScientific Agricultural Society of FinlandAgricultural and Food Science1459-60671795-18951987-04-01592Release of phosphorus, aluminium and iron in fractionation of inorganic soil phosphorusRaina Niskanen0University of Helsinki, Department of Agricultural Chemistry, SF-00710 HELSINKI, Finland Release of phosphorus, aluminium and iron by a modified Chang and Jackson procedure was studied in five mineral soils. Quantities of aluminium and iron released during the procedure and extracted by acid ammonium oxalate were compared. The extractability of P, Al and Fe by 1 M NH4CI and that of Al and Fe by alkaline 0.5 M NH4F was poor. Proportions of P extracted by 0.5 M NH4F (0.2—10.4 mmol/kg soil) and 0.1 M NaOH (0.1— 9.8 mmol/kg soil) were related to the molar ratio of oxalate-extractable iron and aluminium. P extracted by 0.25 M H2SO4 amounted to 2.1—12.2 mmol/kg soil. Al extracted by 0.1 M NaOH (7—174 mmol/kg soil) and 0.25 M H2SO4 (17—112 mmol/kg soil) amounted to 55—94 % and 16—245 % of oxalate-extractable Al, respectively. Fe released by 0.1 M NaOH (1—10 mmol/kg soil) and 0.25 M H2SO4 (30—196 mmol/kg soil) amounted to 1—13 % and 62—272 % of oxalate-extractable Fe, respectively. In total, 91—309 % of oxalate-extractable Al and 70—285 % of oxalate-extractable Fe were released by NaOH and H2SO4.https://journal.fi/afs/article/view/72256
spellingShingle Raina Niskanen
Release of phosphorus, aluminium and iron in fractionation of inorganic soil phosphorus
Agricultural and Food Science
title Release of phosphorus, aluminium and iron in fractionation of inorganic soil phosphorus
title_full Release of phosphorus, aluminium and iron in fractionation of inorganic soil phosphorus
title_fullStr Release of phosphorus, aluminium and iron in fractionation of inorganic soil phosphorus
title_full_unstemmed Release of phosphorus, aluminium and iron in fractionation of inorganic soil phosphorus
title_short Release of phosphorus, aluminium and iron in fractionation of inorganic soil phosphorus
title_sort release of phosphorus aluminium and iron in fractionation of inorganic soil phosphorus
url https://journal.fi/afs/article/view/72256
work_keys_str_mv AT rainaniskanen releaseofphosphorusaluminiumandironinfractionationofinorganicsoilphosphorus