catena-Poly[[(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)cadmium]-di-μ-bromido]
In the crystal of the title polymeric compound, [CdBr2(C12H12N2)]n, the CdII cation is located on a twofold rotation axis and is six-coordinated in a distorted octahedral geometry formed by two N atoms from the 4,4′-dimethyl-2,2′-bipyridine ligand and by four bridging Br&...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812046636 |
| Summary: | In the crystal of the title polymeric compound, [CdBr2(C12H12N2)]n, the CdII cation is located on a twofold rotation axis and is six-coordinated in a distorted octahedral geometry formed by two N atoms from the 4,4′-dimethyl-2,2′-bipyridine ligand and by four bridging Br− anions. The bridging function of the Br− anions leads to a polymeric chain running along the c axis. Weak C—H...π interactions observed between adjacent chains are effective in the stabilization of the three-dimensional packing. |
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| ISSN: | 1600-5368 |