Introducing Well-Defined Nanowrinkles in CVD Grown Graphene

The control of graphene’s topography at the nanoscale level opens up the possibility to greatly improve the surface functionalization, change the doping level or create nanoscale reservoirs. However, the ability to control the modification of the topography of graphene on a wafer scale is...

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Main Authors: Tim Verhagen, Barbara Pacakova, Martin Kalbac, Jana Vejpravova
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Nanomaterials
Subjects:
Online Access:http://www.mdpi.com/2079-4991/9/3/353
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author Tim Verhagen
Barbara Pacakova
Martin Kalbac
Jana Vejpravova
author_facet Tim Verhagen
Barbara Pacakova
Martin Kalbac
Jana Vejpravova
author_sort Tim Verhagen
collection DOAJ
description The control of graphene’s topography at the nanoscale level opens up the possibility to greatly improve the surface functionalization, change the doping level or create nanoscale reservoirs. However, the ability to control the modification of the topography of graphene on a wafer scale is still rather challenging. Here we present an approach to create well-defined nanowrinkles on a wafer scale using nitrocellulose as the polymer to transfer chemical vapor deposition grown graphene from the copper foil to a substrate. During the transfer process, the complex tertiary nitrocellulose structure is imprinted into the graphene area layer. When the graphene layer is put onto a substrate this will result in a well-defined nanowrinkle pattern, which can be subsequently further processed. Using atomic force and Raman microscopy, we characterized the generated nanowrinkles in graphene.
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spelling doaj.art-c7c4ae1562724587948cec5dc8aaf4202022-12-22T02:40:53ZengMDPI AGNanomaterials2079-49912019-03-019335310.3390/nano9030353nano9030353Introducing Well-Defined Nanowrinkles in CVD Grown GrapheneTim Verhagen0Barbara Pacakova1Martin Kalbac2Jana Vejpravova3Department of Condensed Matter Physics, Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 121 16 Prague 2, Czech RepublicJ. Heyrovsky Institute of Physical Chemistry of the CAS, v.v.i., Dolejskova 2155/3, CZ-182 23 Prague 8, Czech RepublicJ. Heyrovsky Institute of Physical Chemistry of the CAS, v.v.i., Dolejskova 2155/3, CZ-182 23 Prague 8, Czech RepublicDepartment of Condensed Matter Physics, Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 121 16 Prague 2, Czech RepublicThe control of graphene’s topography at the nanoscale level opens up the possibility to greatly improve the surface functionalization, change the doping level or create nanoscale reservoirs. However, the ability to control the modification of the topography of graphene on a wafer scale is still rather challenging. Here we present an approach to create well-defined nanowrinkles on a wafer scale using nitrocellulose as the polymer to transfer chemical vapor deposition grown graphene from the copper foil to a substrate. During the transfer process, the complex tertiary nitrocellulose structure is imprinted into the graphene area layer. When the graphene layer is put onto a substrate this will result in a well-defined nanowrinkle pattern, which can be subsequently further processed. Using atomic force and Raman microscopy, we characterized the generated nanowrinkles in graphene.http://www.mdpi.com/2079-4991/9/3/353CVD graphenetransferrugawrinklerippleRaman spectroscopyAFM
spellingShingle Tim Verhagen
Barbara Pacakova
Martin Kalbac
Jana Vejpravova
Introducing Well-Defined Nanowrinkles in CVD Grown Graphene
Nanomaterials
CVD graphene
transfer
ruga
wrinkle
ripple
Raman spectroscopy
AFM
title Introducing Well-Defined Nanowrinkles in CVD Grown Graphene
title_full Introducing Well-Defined Nanowrinkles in CVD Grown Graphene
title_fullStr Introducing Well-Defined Nanowrinkles in CVD Grown Graphene
title_full_unstemmed Introducing Well-Defined Nanowrinkles in CVD Grown Graphene
title_short Introducing Well-Defined Nanowrinkles in CVD Grown Graphene
title_sort introducing well defined nanowrinkles in cvd grown graphene
topic CVD graphene
transfer
ruga
wrinkle
ripple
Raman spectroscopy
AFM
url http://www.mdpi.com/2079-4991/9/3/353
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AT barbarapacakova introducingwelldefinednanowrinklesincvdgrowngraphene
AT martinkalbac introducingwelldefinednanowrinklesincvdgrowngraphene
AT janavejpravova introducingwelldefinednanowrinklesincvdgrowngraphene