Direct Arylation in the Presence of Palladium Pincer Complexes
Direct arylation is an atom-economical alternative to more established procedures such as Stille, Suzuki or Negishi arylation reactions. In comparison with other palladium sources and ligands, the use of palladium pincer complexes as catalysts or pre-catalysts for direct arylation has resulted in im...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-07-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/26/14/4385 |
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| author | Garazi Urgoitia Maria Teresa Herrero Fátima Churruca Nerea Conde Raul SanMartin |
| author_facet | Garazi Urgoitia Maria Teresa Herrero Fátima Churruca Nerea Conde Raul SanMartin |
| author_sort | Garazi Urgoitia |
| collection | DOAJ |
| description | Direct arylation is an atom-economical alternative to more established procedures such as Stille, Suzuki or Negishi arylation reactions. In comparison with other palladium sources and ligands, the use of palladium pincer complexes as catalysts or pre-catalysts for direct arylation has resulted in improved efficiency, higher reaction yields, and advantageous reaction conditions. In addition to a revision of the literature concerning intra- and intermolecular direct arylation reactions performed in the presence of palladium pincer complexes, the role of these remarkably active catalysts will also be discussed. |
| first_indexed | 2024-03-10T09:30:52Z |
| format | Article |
| id | doaj.art-c7cb38a44b294efa804d55ce8b891bec |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T09:30:52Z |
| publishDate | 2021-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-c7cb38a44b294efa804d55ce8b891bec2023-11-22T04:33:03ZengMDPI AGMolecules1420-30492021-07-012614438510.3390/molecules26144385Direct Arylation in the Presence of Palladium Pincer ComplexesGarazi Urgoitia0Maria Teresa Herrero1Fátima Churruca2Nerea Conde3Raul SanMartin4Department of Organic and Inorganic Chemistry, Faculty of Science and Technology, University of the Basque Country (UPV/EHU), 48940 Leioa, SpainDepartment of Organic and Inorganic Chemistry, Faculty of Science and Technology, University of the Basque Country (UPV/EHU), 48940 Leioa, SpainDepartment of Organic and Inorganic Chemistry, Faculty of Science and Technology, University of the Basque Country (UPV/EHU), 48940 Leioa, SpainDepartment of Organic and Inorganic Chemistry, Faculty of Science and Technology, University of the Basque Country (UPV/EHU), 48940 Leioa, SpainDepartment of Organic and Inorganic Chemistry, Faculty of Science and Technology, University of the Basque Country (UPV/EHU), 48940 Leioa, SpainDirect arylation is an atom-economical alternative to more established procedures such as Stille, Suzuki or Negishi arylation reactions. In comparison with other palladium sources and ligands, the use of palladium pincer complexes as catalysts or pre-catalysts for direct arylation has resulted in improved efficiency, higher reaction yields, and advantageous reaction conditions. In addition to a revision of the literature concerning intra- and intermolecular direct arylation reactions performed in the presence of palladium pincer complexes, the role of these remarkably active catalysts will also be discussed.https://www.mdpi.com/1420-3049/26/14/4385direct arylationpalladiumpincer complexes |
| spellingShingle | Garazi Urgoitia Maria Teresa Herrero Fátima Churruca Nerea Conde Raul SanMartin Direct Arylation in the Presence of Palladium Pincer Complexes Molecules direct arylation palladium pincer complexes |
| title | Direct Arylation in the Presence of Palladium Pincer Complexes |
| title_full | Direct Arylation in the Presence of Palladium Pincer Complexes |
| title_fullStr | Direct Arylation in the Presence of Palladium Pincer Complexes |
| title_full_unstemmed | Direct Arylation in the Presence of Palladium Pincer Complexes |
| title_short | Direct Arylation in the Presence of Palladium Pincer Complexes |
| title_sort | direct arylation in the presence of palladium pincer complexes |
| topic | direct arylation palladium pincer complexes |
| url | https://www.mdpi.com/1420-3049/26/14/4385 |
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