Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate
The reaction of aqueous solutions of aminoguanidine hydrogennitrate and acetylacetone produces the title pyrazole salt, C7H18N82+·2NO3−. The crystal structure is stabilized by a complex N—H...O hydrogen-bonding network. The difference in the engagement of the...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-08-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810025006 |
| _version_ | 1819279740081537024 |
|---|---|
| author | Sladjana B. Novaković Mirjana Lalović Vladimir Divjaković Ljiljana S. Vojinović-Ješić Valerija I. Češljević |
| author_facet | Sladjana B. Novaković Mirjana Lalović Vladimir Divjaković Ljiljana S. Vojinović-Ješić Valerija I. Češljević |
| author_sort | Sladjana B. Novaković |
| collection | DOAJ |
| description | The reaction of aqueous solutions of aminoguanidine hydrogennitrate and acetylacetone produces the title pyrazole salt, C7H18N82+·2NO3−. The crystal structure is stabilized by a complex N—H...O hydrogen-bonding network. The difference in the engagement of the two nitrate anions in hydrogen bonding is reflected in the variation of the corresponding N—O bond lengths. |
| first_indexed | 2024-12-24T00:32:42Z |
| format | Article |
| id | doaj.art-c7f740f6dc7b45c399528ed3401a4049 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:32:42Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c7f740f6dc7b45c399528ed3401a40492022-12-21T17:24:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668o1916o191710.1107/S1600536810025006Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrateSladjana B. NovakovićMirjana LalovićVladimir DivjakovićLjiljana S. Vojinović-JešićValerija I. ČešljevićThe reaction of aqueous solutions of aminoguanidine hydrogennitrate and acetylacetone produces the title pyrazole salt, C7H18N82+·2NO3−. The crystal structure is stabilized by a complex N—H...O hydrogen-bonding network. The difference in the engagement of the two nitrate anions in hydrogen bonding is reflected in the variation of the corresponding N—O bond lengths.http://scripts.iucr.org/cgi-bin/paper?S1600536810025006 |
| spellingShingle | Sladjana B. Novaković Mirjana Lalović Vladimir Divjaković Ljiljana S. Vojinović-Ješić Valerija I. Češljević Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate Acta Crystallographica Section E |
| title | Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate |
| title_full | Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate |
| title_fullStr | Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate |
| title_full_unstemmed | Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate |
| title_short | Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate |
| title_sort | amino 5 2 amino iminio methyl hydrazin 1 yl 3 5 dimethyl 4 5 dihydro 1h pyrazol 1 yl methaniminium dinitrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810025006 |
| work_keys_str_mv | AT sladjanabnovakoviamp263 amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate AT mirjanalaloviamp263 amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate AT vladimirdivjakoviamp263 amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate AT ljiljanasvojinoviamp263jeamp353iamp263 amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate AT valerijaiamp268eamp353ljeviamp263 amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate |