Investigation of Nitrate and Ammonium Removal from Groundwater by Mineral Filters

Increasing surface and groundwater pollution by ammonium and nitrate makes it necessary to find solutions with minimal environmental impacts. For this purpose, using abundant and high sorption potential soil minerals offers cost-effective and environmentally sound remediation techniques. In this stu...

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Main Authors: Mohsen Soleimani, Arash Ansarie, Mohammadali Haj Abassie, Jahangir Abedie
Format: Article
Language:English
Published: Water and Wastewater Consulting Engineers Research Development 2008-09-01
Series:آب و فاضلاب
Subjects:
Online Access:http://www.wwjournal.ir/article_2185_cae88196b915f41671f3b30a7b3da80c.pdf
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author Mohsen Soleimani
Arash Ansarie
Mohammadali Haj Abassie
Jahangir Abedie
author_facet Mohsen Soleimani
Arash Ansarie
Mohammadali Haj Abassie
Jahangir Abedie
author_sort Mohsen Soleimani
collection DOAJ
description Increasing surface and groundwater pollution by ammonium and nitrate makes it necessary to find solutions with minimal environmental impacts. For this purpose, using abundant and high sorption potential soil minerals offers cost-effective and environmentally sound remediation techniques. In this study, Firoozkouh and Semnan zeolites were used for removal of nitrate and ammonium from laboratory solutions and groundwater (Batch method). Zeolite minerals were modified by using the organic surfactant hexadecyltrimethylammonium. A one to tenth ratio of absorbent to solution was used. Results showed that the Semnan natural zeolite and the Firoozkouh modified zeolite treatements, respectively, had the highest and the lowest ammonium sorption levels. The Firoozkouh modified zeolite had the highest nitrate sorption while Semnan natural zeolite had the lowest ammonium sorption. The highest sorption level for ammonium was found to be 0.96 meq g-1 for the Semnan natural zeolite treatment at a concentration of 10 meql-1 and pH=5.5 while the highest sorption for nitrate was found to be 0.8 meq g-1 for the Firoozkouh modified zeolite. Isotherms of nitrate and ammonium sorption levels by natural and modified zeolites showed to match with those of the linear and Fraundlich models.
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spelling doaj.art-c7f8137e2fce4f5f91c1dc1ea354269c2022-12-21T22:26:26ZengWater and Wastewater Consulting Engineers Research Developmentآب و فاضلاب1024-59362383-09052008-09-0119318262185Investigation of Nitrate and Ammonium Removal from Groundwater by Mineral FiltersMohsen Soleimani0Arash Ansarie1Mohammadali Haj Abassie2Jahangir Abedie3Ph.D. Student of Soil Science, College of Agriculture, Isfahan University of TechnologyResearcher, Safir Sabz Co., Isfahan Science & Technology TownAssoc. Prof. of Soil Science, Isfahan University of TechnologyAssoc. Prof. of Irrigation, Isfahan University of TechnologyIncreasing surface and groundwater pollution by ammonium and nitrate makes it necessary to find solutions with minimal environmental impacts. For this purpose, using abundant and high sorption potential soil minerals offers cost-effective and environmentally sound remediation techniques. In this study, Firoozkouh and Semnan zeolites were used for removal of nitrate and ammonium from laboratory solutions and groundwater (Batch method). Zeolite minerals were modified by using the organic surfactant hexadecyltrimethylammonium. A one to tenth ratio of absorbent to solution was used. Results showed that the Semnan natural zeolite and the Firoozkouh modified zeolite treatements, respectively, had the highest and the lowest ammonium sorption levels. The Firoozkouh modified zeolite had the highest nitrate sorption while Semnan natural zeolite had the lowest ammonium sorption. The highest sorption level for ammonium was found to be 0.96 meq g-1 for the Semnan natural zeolite treatment at a concentration of 10 meql-1 and pH=5.5 while the highest sorption for nitrate was found to be 0.8 meq g-1 for the Firoozkouh modified zeolite. Isotherms of nitrate and ammonium sorption levels by natural and modified zeolites showed to match with those of the linear and Fraundlich models.http://www.wwjournal.ir/article_2185_cae88196b915f41671f3b30a7b3da80c.pdfZeoliteFraundlichLangmuirSurfactantHexadecyltrimethylammonium (HDTMA)
spellingShingle Mohsen Soleimani
Arash Ansarie
Mohammadali Haj Abassie
Jahangir Abedie
Investigation of Nitrate and Ammonium Removal from Groundwater by Mineral Filters
آب و فاضلاب
Zeolite
Fraundlich
Langmuir
Surfactant
Hexadecyltrimethylammonium (HDTMA)
title Investigation of Nitrate and Ammonium Removal from Groundwater by Mineral Filters
title_full Investigation of Nitrate and Ammonium Removal from Groundwater by Mineral Filters
title_fullStr Investigation of Nitrate and Ammonium Removal from Groundwater by Mineral Filters
title_full_unstemmed Investigation of Nitrate and Ammonium Removal from Groundwater by Mineral Filters
title_short Investigation of Nitrate and Ammonium Removal from Groundwater by Mineral Filters
title_sort investigation of nitrate and ammonium removal from groundwater by mineral filters
topic Zeolite
Fraundlich
Langmuir
Surfactant
Hexadecyltrimethylammonium (HDTMA)
url http://www.wwjournal.ir/article_2185_cae88196b915f41671f3b30a7b3da80c.pdf
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AT jahangirabedie investigationofnitrateandammoniumremovalfromgroundwaterbymineralfilters