catena-Poly[[[diaquadiformatonickel(II)]-μ-1,4-bis(1H-benzimidazol-1-yl)benzene] dihydrate]
In the title one-dimensional coordination polymer, {[Ni(CHO2)2(C20H14N4)(H2O)2]·2H2O}n, the NiII atom lies on a crystallographic inversion centre. It is coordinated by two formate O atoms, two water O atoms and two N atoms from two 1,4-bis(1H-benzimidazol-1-yl)benzene (bzb) ligands, res...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681200284X |
| _version_ | 1818320868944642048 |
|---|---|
| author | Hui Li Hong Sun Xiaochuan Chai Chenzhong Yao |
| author_facet | Hui Li Hong Sun Xiaochuan Chai Chenzhong Yao |
| author_sort | Hui Li |
| collection | DOAJ |
| description | In the title one-dimensional coordination polymer, {[Ni(CHO2)2(C20H14N4)(H2O)2]·2H2O}n, the NiII atom lies on a crystallographic inversion centre. It is coordinated by two formate O atoms, two water O atoms and two N atoms from two 1,4-bis(1H-benzimidazol-1-yl)benzene (bzb) ligands, resulting in a distorted trans-NiN2O4 octahedral coordination geometry. The bzb molecule acts as a bridging ligand to connect the metal atoms into a chain propagating in [1-1-1]. The dihedral angle between the benzimidazole ring and the central benzene ring in the ligand is 38.16 (9)°. In the crystal, O—H...O hydrogen bonds crosslink the chains into (010) sheets. |
| first_indexed | 2024-12-13T10:31:51Z |
| format | Article |
| id | doaj.art-c80315d20e154f019ee554626c576f85 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:31:51Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c80315d20e154f019ee554626c576f852022-12-21T23:50:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m216m21610.1107/S160053681200284Xcatena-Poly[[[diaquadiformatonickel(II)]-μ-1,4-bis(1H-benzimidazol-1-yl)benzene] dihydrate]Hui LiHong SunXiaochuan ChaiChenzhong YaoIn the title one-dimensional coordination polymer, {[Ni(CHO2)2(C20H14N4)(H2O)2]·2H2O}n, the NiII atom lies on a crystallographic inversion centre. It is coordinated by two formate O atoms, two water O atoms and two N atoms from two 1,4-bis(1H-benzimidazol-1-yl)benzene (bzb) ligands, resulting in a distorted trans-NiN2O4 octahedral coordination geometry. The bzb molecule acts as a bridging ligand to connect the metal atoms into a chain propagating in [1-1-1]. The dihedral angle between the benzimidazole ring and the central benzene ring in the ligand is 38.16 (9)°. In the crystal, O—H...O hydrogen bonds crosslink the chains into (010) sheets.http://scripts.iucr.org/cgi-bin/paper?S160053681200284X |
| spellingShingle | Hui Li Hong Sun Xiaochuan Chai Chenzhong Yao catena-Poly[[[diaquadiformatonickel(II)]-μ-1,4-bis(1H-benzimidazol-1-yl)benzene] dihydrate] Acta Crystallographica Section E |
| title | catena-Poly[[[diaquadiformatonickel(II)]-μ-1,4-bis(1H-benzimidazol-1-yl)benzene] dihydrate] |
| title_full | catena-Poly[[[diaquadiformatonickel(II)]-μ-1,4-bis(1H-benzimidazol-1-yl)benzene] dihydrate] |
| title_fullStr | catena-Poly[[[diaquadiformatonickel(II)]-μ-1,4-bis(1H-benzimidazol-1-yl)benzene] dihydrate] |
| title_full_unstemmed | catena-Poly[[[diaquadiformatonickel(II)]-μ-1,4-bis(1H-benzimidazol-1-yl)benzene] dihydrate] |
| title_short | catena-Poly[[[diaquadiformatonickel(II)]-μ-1,4-bis(1H-benzimidazol-1-yl)benzene] dihydrate] |
| title_sort | catena poly diaquadiformatonickel ii amp 956 1 4 bis 1h benzimidazol 1 yl benzene dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681200284X |
| work_keys_str_mv | AT huili catenapolydiaquadiformatonickeliiamp95614bis1hbenzimidazol1ylbenzenedihydrate AT hongsun catenapolydiaquadiformatonickeliiamp95614bis1hbenzimidazol1ylbenzenedihydrate AT xiaochuanchai catenapolydiaquadiformatonickeliiamp95614bis1hbenzimidazol1ylbenzenedihydrate AT chenzhongyao catenapolydiaquadiformatonickeliiamp95614bis1hbenzimidazol1ylbenzenedihydrate |