Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry
Metal–organic frameworks (MOFs) are emerging porous materials with highly tunable structures developed in the 1990s, while organometallic chemistry is of fundamental importance for catalytic transformation in the academic and industrial world for many decades. Through the years, organometallic chemi...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2021-04-01
|
| Series: | Inorganics |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2304-6740/9/4/27 |
| _version_ | 1827695583758909440 |
|---|---|
| author | Fan Chen Hannah F. Drake Liang Feng Joshua A. Powell Kun-Yu Wang Tian-Hao Yan Hong-Cai Zhou |
| author_facet | Fan Chen Hannah F. Drake Liang Feng Joshua A. Powell Kun-Yu Wang Tian-Hao Yan Hong-Cai Zhou |
| author_sort | Fan Chen |
| collection | DOAJ |
| description | Metal–organic frameworks (MOFs) are emerging porous materials with highly tunable structures developed in the 1990s, while organometallic chemistry is of fundamental importance for catalytic transformation in the academic and industrial world for many decades. Through the years, organometallic chemistry has been incorporated into functional MOF construction for diverse applications. Here, we will focus on how organometallic chemistry is applied in MOF design and modifications from linker-centric and metal-cluster-centric perspectives, respectively. Through structural design, MOFs can function as a tailorable platform for traditional organometallic transformations, including reaction of alkenes, cross-coupling reactions, and C–H activations. Besides, an overview will be made on other application categories of organometallic MOFs, such as gas adsorption, magnetism, quantum computing, and therapeutics. |
| first_indexed | 2024-03-10T12:29:19Z |
| format | Article |
| id | doaj.art-c8548c9057094d46b2ba537caec6b7fe |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-03-10T12:29:19Z |
| publishDate | 2021-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-c8548c9057094d46b2ba537caec6b7fe2023-11-21T14:50:34ZengMDPI AGInorganics2304-67402021-04-01942710.3390/inorganics9040027Metal–Organic Frameworks as Versatile Platforms for Organometallic ChemistryFan Chen0Hannah F. Drake1Liang Feng2Joshua A. Powell3Kun-Yu Wang4Tian-Hao Yan5Hong-Cai Zhou6Department of Chemistry, Texas A&M University, College Station, TX 77843-3255, USADepartment of Chemistry, Texas A&M University, College Station, TX 77843-3255, USADepartment of Chemistry, Texas A&M University, College Station, TX 77843-3255, USADepartment of Chemistry, Texas A&M University, College Station, TX 77843-3255, USADepartment of Chemistry, Texas A&M University, College Station, TX 77843-3255, USADepartment of Chemistry, Texas A&M University, College Station, TX 77843-3255, USADepartment of Chemistry, Texas A&M University, College Station, TX 77843-3255, USAMetal–organic frameworks (MOFs) are emerging porous materials with highly tunable structures developed in the 1990s, while organometallic chemistry is of fundamental importance for catalytic transformation in the academic and industrial world for many decades. Through the years, organometallic chemistry has been incorporated into functional MOF construction for diverse applications. Here, we will focus on how organometallic chemistry is applied in MOF design and modifications from linker-centric and metal-cluster-centric perspectives, respectively. Through structural design, MOFs can function as a tailorable platform for traditional organometallic transformations, including reaction of alkenes, cross-coupling reactions, and C–H activations. Besides, an overview will be made on other application categories of organometallic MOFs, such as gas adsorption, magnetism, quantum computing, and therapeutics.https://www.mdpi.com/2304-6740/9/4/27metal–organic frameworkorganometalliccoordination bondssupramolecular chemistrycatalysis |
| spellingShingle | Fan Chen Hannah F. Drake Liang Feng Joshua A. Powell Kun-Yu Wang Tian-Hao Yan Hong-Cai Zhou Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry Inorganics metal–organic framework organometallic coordination bonds supramolecular chemistry catalysis |
| title | Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry |
| title_full | Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry |
| title_fullStr | Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry |
| title_full_unstemmed | Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry |
| title_short | Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry |
| title_sort | metal organic frameworks as versatile platforms for organometallic chemistry |
| topic | metal–organic framework organometallic coordination bonds supramolecular chemistry catalysis |
| url | https://www.mdpi.com/2304-6740/9/4/27 |
| work_keys_str_mv | AT fanchen metalorganicframeworksasversatileplatformsfororganometallicchemistry AT hannahfdrake metalorganicframeworksasversatileplatformsfororganometallicchemistry AT liangfeng metalorganicframeworksasversatileplatformsfororganometallicchemistry AT joshuaapowell metalorganicframeworksasversatileplatformsfororganometallicchemistry AT kunyuwang metalorganicframeworksasversatileplatformsfororganometallicchemistry AT tianhaoyan metalorganicframeworksasversatileplatformsfororganometallicchemistry AT hongcaizhou metalorganicframeworksasversatileplatformsfororganometallicchemistry |