Digital Etch Technique for Forming Ultra-Scaled Germanium-Tin (Ge 1−x Sn x ) Fin Structure

Abstract We developed a new digital etch process that allows precise etching of Germanium or Germanium-tin (Ge1−x Sn x ) materials. The digital etch approach consists of Ge1−x Sn x oxide formation by plasma oxidation and oxide removal in diluted hydrochloric acid at room temperature. The first step...

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Main Authors: Wei Wang, Dian Lei, Yuan Dong, Xiao Gong, Eng Soon Tok, Yee-Chia Yeo
Format: Article
Language:English
Published: Nature Portfolio 2017-05-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-017-01449-1
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author Wei Wang
Dian Lei
Yuan Dong
Xiao Gong
Eng Soon Tok
Yee-Chia Yeo
author_facet Wei Wang
Dian Lei
Yuan Dong
Xiao Gong
Eng Soon Tok
Yee-Chia Yeo
author_sort Wei Wang
collection DOAJ
description Abstract We developed a new digital etch process that allows precise etching of Germanium or Germanium-tin (Ge1−x Sn x ) materials. The digital etch approach consists of Ge1−x Sn x oxide formation by plasma oxidation and oxide removal in diluted hydrochloric acid at room temperature. The first step is a self-limiting process, as the thickness of oxide layer grows logarithmically with the oxidation time and saturates fast. Consistent etch rates in each cycle were found on the Ge1−x Sn x samples, with the surfaces remaining smooth after etch. The digital etch process parameters were tuned to achieve various etch rates. By reducing the radio frequency power to 70 W, etch rate of sub-1.2 nm was obtained on a Ge0.875Sn0.125 sample. The digital etch process was employed to fabricate the Ge1−x Sn x fin structures. Extremely scaled Ge0.95Sn0.05 fins with 5 nm fin width were realized. The side walls of the Ge0.95Sn0.05 fins are smooth, and no crystal damage can be observed. This technique provides an option to realize aggressively scaled nanostructure devices based on Ge1−x Sn x materials with high-precision control.
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spelling doaj.art-c890dc39b6ee446f9ae6b0f5ddd284032022-12-21T22:56:14ZengNature PortfolioScientific Reports2045-23222017-05-01711910.1038/s41598-017-01449-1Digital Etch Technique for Forming Ultra-Scaled Germanium-Tin (Ge 1−x Sn x ) Fin StructureWei Wang0Dian Lei1Yuan Dong2Xiao Gong3Eng Soon Tok4Yee-Chia Yeo5Department of Electrical and Computer Engineering, National University of SingaporeDepartment of Electrical and Computer Engineering, National University of SingaporeDepartment of Electrical and Computer Engineering, National University of SingaporeDepartment of Electrical and Computer Engineering, National University of SingaporeDepartment of Physics, National University of SingaporeDepartment of Electrical and Computer Engineering, National University of SingaporeAbstract We developed a new digital etch process that allows precise etching of Germanium or Germanium-tin (Ge1−x Sn x ) materials. The digital etch approach consists of Ge1−x Sn x oxide formation by plasma oxidation and oxide removal in diluted hydrochloric acid at room temperature. The first step is a self-limiting process, as the thickness of oxide layer grows logarithmically with the oxidation time and saturates fast. Consistent etch rates in each cycle were found on the Ge1−x Sn x samples, with the surfaces remaining smooth after etch. The digital etch process parameters were tuned to achieve various etch rates. By reducing the radio frequency power to 70 W, etch rate of sub-1.2 nm was obtained on a Ge0.875Sn0.125 sample. The digital etch process was employed to fabricate the Ge1−x Sn x fin structures. Extremely scaled Ge0.95Sn0.05 fins with 5 nm fin width were realized. The side walls of the Ge0.95Sn0.05 fins are smooth, and no crystal damage can be observed. This technique provides an option to realize aggressively scaled nanostructure devices based on Ge1−x Sn x materials with high-precision control.https://doi.org/10.1038/s41598-017-01449-1
spellingShingle Wei Wang
Dian Lei
Yuan Dong
Xiao Gong
Eng Soon Tok
Yee-Chia Yeo
Digital Etch Technique for Forming Ultra-Scaled Germanium-Tin (Ge 1−x Sn x ) Fin Structure
Scientific Reports
title Digital Etch Technique for Forming Ultra-Scaled Germanium-Tin (Ge 1−x Sn x ) Fin Structure
title_full Digital Etch Technique for Forming Ultra-Scaled Germanium-Tin (Ge 1−x Sn x ) Fin Structure
title_fullStr Digital Etch Technique for Forming Ultra-Scaled Germanium-Tin (Ge 1−x Sn x ) Fin Structure
title_full_unstemmed Digital Etch Technique for Forming Ultra-Scaled Germanium-Tin (Ge 1−x Sn x ) Fin Structure
title_short Digital Etch Technique for Forming Ultra-Scaled Germanium-Tin (Ge 1−x Sn x ) Fin Structure
title_sort digital etch technique for forming ultra scaled germanium tin ge 1 x sn x fin structure
url https://doi.org/10.1038/s41598-017-01449-1
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