5-[(E)-4-Fluorobenzylidene]-8-(4-fluorophenyl)-2-hydroxy-9-phenyl-3,10-diazahexacyclo[10.7.1.13,7.02,11.07,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one
In the title compound, C38H28F2N2O2, the piperidine ring adopts a chair conformation and the pyrrolidine ring adopts an envelope conformation with the spiro C atom as the flap atom. The naphthalene ring system makes dihedral angles of 39.89 (8), 35.33 (8) and 46.45&am...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811040633 |
| _version_ | 1818321474220457984 |
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| author | Raju Suresh Kumar Hasnah Osman A. S. Abdul Rahim Madhukar Hemamalini Hoong-Kun Fun |
| author_facet | Raju Suresh Kumar Hasnah Osman A. S. Abdul Rahim Madhukar Hemamalini Hoong-Kun Fun |
| author_sort | Raju Suresh Kumar |
| collection | DOAJ |
| description | In the title compound, C38H28F2N2O2, the piperidine ring adopts a chair conformation and the pyrrolidine ring adopts an envelope conformation with the spiro C atom as the flap atom. The naphthalene ring system makes dihedral angles of 39.89 (8), 35.33 (8) and 46.45 (8)° with the two fluoro-substituted benzene rings and the phenyl ring, respectively, while the dihedral angle between the two fluoro-substituted benzene rings is 75.21 (10)°. An intramolecular O—H...N hydrogen bond generates an S(5) ring. In the crystal, molecules are connected by C—H...O hydrogen bonds, forming supramolecular chains propagating along the c-axis direction. Weak C—H...π interactions further consolidate the structure. |
| first_indexed | 2024-12-13T10:41:28Z |
| format | Article |
| id | doaj.art-c8a8de3613164bac838ae7799af10097 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:41:28Z |
| publishDate | 2011-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c8a8de3613164bac838ae7799af100972022-12-21T23:50:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711o2879o288010.1107/S16005368110406335-[(E)-4-Fluorobenzylidene]-8-(4-fluorophenyl)-2-hydroxy-9-phenyl-3,10-diazahexacyclo[10.7.1.13,7.02,11.07,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-oneRaju Suresh KumarHasnah OsmanA. S. Abdul RahimMadhukar HemamaliniHoong-Kun FunIn the title compound, C38H28F2N2O2, the piperidine ring adopts a chair conformation and the pyrrolidine ring adopts an envelope conformation with the spiro C atom as the flap atom. The naphthalene ring system makes dihedral angles of 39.89 (8), 35.33 (8) and 46.45 (8)° with the two fluoro-substituted benzene rings and the phenyl ring, respectively, while the dihedral angle between the two fluoro-substituted benzene rings is 75.21 (10)°. An intramolecular O—H...N hydrogen bond generates an S(5) ring. In the crystal, molecules are connected by C—H...O hydrogen bonds, forming supramolecular chains propagating along the c-axis direction. Weak C—H...π interactions further consolidate the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811040633 |
| spellingShingle | Raju Suresh Kumar Hasnah Osman A. S. Abdul Rahim Madhukar Hemamalini Hoong-Kun Fun 5-[(E)-4-Fluorobenzylidene]-8-(4-fluorophenyl)-2-hydroxy-9-phenyl-3,10-diazahexacyclo[10.7.1.13,7.02,11.07,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one Acta Crystallographica Section E |
| title | 5-[(E)-4-Fluorobenzylidene]-8-(4-fluorophenyl)-2-hydroxy-9-phenyl-3,10-diazahexacyclo[10.7.1.13,7.02,11.07,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one |
| title_full | 5-[(E)-4-Fluorobenzylidene]-8-(4-fluorophenyl)-2-hydroxy-9-phenyl-3,10-diazahexacyclo[10.7.1.13,7.02,11.07,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one |
| title_fullStr | 5-[(E)-4-Fluorobenzylidene]-8-(4-fluorophenyl)-2-hydroxy-9-phenyl-3,10-diazahexacyclo[10.7.1.13,7.02,11.07,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one |
| title_full_unstemmed | 5-[(E)-4-Fluorobenzylidene]-8-(4-fluorophenyl)-2-hydroxy-9-phenyl-3,10-diazahexacyclo[10.7.1.13,7.02,11.07,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one |
| title_short | 5-[(E)-4-Fluorobenzylidene]-8-(4-fluorophenyl)-2-hydroxy-9-phenyl-3,10-diazahexacyclo[10.7.1.13,7.02,11.07,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one |
| title_sort | 5 e 4 fluorobenzylidene 8 4 fluorophenyl 2 hydroxy 9 phenyl 3 10 diazahexacyclo 10 7 1 13 7 02 11 07 11 016 20 henicosa 1 20 12 14 16 18 pentaen 6 one |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811040633 |
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