Aging of ceria-stabilized zirconia in water and its mechanism

In this study, the aging behavior of ceria-stabilized zirconia (Ce–TZP) in water is evaluated, and the aging mechanism is proposed. To eliminate the effect of processing parameters, a methodology involving the introduction of various amounts of the m-phase into one specimen disc is explored. With th...

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Main Authors: Chi-Shen Tien, Ce-Lung Tung, Wei-Hsing Tuan, Po-Liang Lai
Format: Article
Language:English
Published: Elsevier 2024-03-01
Series:Open Ceramics
Online Access:http://www.sciencedirect.com/science/article/pii/S2666539524000282
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author Chi-Shen Tien
Ce-Lung Tung
Wei-Hsing Tuan
Po-Liang Lai
author_facet Chi-Shen Tien
Ce-Lung Tung
Wei-Hsing Tuan
Po-Liang Lai
author_sort Chi-Shen Tien
collection DOAJ
description In this study, the aging behavior of ceria-stabilized zirconia (Ce–TZP) in water is evaluated, and the aging mechanism is proposed. To eliminate the effect of processing parameters, a methodology involving the introduction of various amounts of the m-phase into one specimen disc is explored. With this method, the formation of the m phase can be attributed to the reduction of Ce4+ to Ce3+ in Ce–TZP. Oxygen vacancies play a key role in the aging behavior. Although the addition of Al2O3 particles refines the Ce–TZP microstructure, their presence reduces the aging resistance of Ce–TZP.
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spelling doaj.art-c8ac2a46092b4194b811523e34d1f2402024-03-22T05:40:58ZengElsevierOpen Ceramics2666-53952024-03-0117100564Aging of ceria-stabilized zirconia in water and its mechanismChi-Shen Tien0Ce-Lung Tung1Wei-Hsing Tuan2Po-Liang Lai3Department of Materials Science and Engineering, National Taiwan University, Taipei, TaiwanDepartment of Materials Science and Engineering, National Taiwan University, Taipei, TaiwanDepartment of Materials Science and Engineering, National Taiwan University, Taipei, Taiwan; Corresponding author.Department of Orthopedic Surgery, Bone and Joint Research Center, Chang Gung Memorial Hospital at Linkou, College of Medicine, Chang Gung University, Taoyuan, Taiwan; Corresponding author.In this study, the aging behavior of ceria-stabilized zirconia (Ce–TZP) in water is evaluated, and the aging mechanism is proposed. To eliminate the effect of processing parameters, a methodology involving the introduction of various amounts of the m-phase into one specimen disc is explored. With this method, the formation of the m phase can be attributed to the reduction of Ce4+ to Ce3+ in Ce–TZP. Oxygen vacancies play a key role in the aging behavior. Although the addition of Al2O3 particles refines the Ce–TZP microstructure, their presence reduces the aging resistance of Ce–TZP.http://www.sciencedirect.com/science/article/pii/S2666539524000282
spellingShingle Chi-Shen Tien
Ce-Lung Tung
Wei-Hsing Tuan
Po-Liang Lai
Aging of ceria-stabilized zirconia in water and its mechanism
Open Ceramics
title Aging of ceria-stabilized zirconia in water and its mechanism
title_full Aging of ceria-stabilized zirconia in water and its mechanism
title_fullStr Aging of ceria-stabilized zirconia in water and its mechanism
title_full_unstemmed Aging of ceria-stabilized zirconia in water and its mechanism
title_short Aging of ceria-stabilized zirconia in water and its mechanism
title_sort aging of ceria stabilized zirconia in water and its mechanism
url http://www.sciencedirect.com/science/article/pii/S2666539524000282
work_keys_str_mv AT chishentien agingofceriastabilizedzirconiainwateranditsmechanism
AT celungtung agingofceriastabilizedzirconiainwateranditsmechanism
AT weihsingtuan agingofceriastabilizedzirconiainwateranditsmechanism
AT polianglai agingofceriastabilizedzirconiainwateranditsmechanism