| Summary: | The modification of apolar carbon materials by heteroatom doping is an effective method that can effectively improve the surface polarity of carbon materials. In the main body of the lithium–sulfur battery cathode, the structural properties of the carbon material itself with porous structure and large specific surface area provide sufficient space for sulfur accommodation and mitigate the bulk effect of the sulfur cathode (79%). The polarized surface of the reconstructed carbon material possesses strong adsorption effect on LiPs, which mitigates the notorious “shuttle effect.” In this paper, the surface structure of the Ketjen black cathode body was reconstructed by B and N double heteroatoms to polarize it. The modified polarized Ketjen black improves the adsorption and anchoring ability of LiPs during the reaction and accelerates their kinetic conversion, while its own uniformly distributed small mesopores and oversized BET structural properties are beneficial to mitigate the bulk effect of sulfur cathodes. Lithium–sulfur batteries using B and N modified cathodes have an initial discharge capacity of 1344.49 mAh/g at 0.1 C and excellent cycling stability at 0.5 C (381.4 mAh/g after 100 cycles).
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