Use of the Asymmetrical Chelating N-Donor 2-Imino-Pyridine as a Redox [Fe4S4] Cubane Surrogate at a Di-Iron Site Related to [FeFe]-Hydrogenases

Use of the Asymmetrical Chelating N-Donor 2-Imino-Pyridine as a Redox [Fe4S4] Cubane Surrogate at a Di-Iron Site Related to [FeFe]-Hydrogenases

Two complexes, related to the active site of [FeFe]-hydrogenases, [Fe<sub>2</sub>(CO)<sub>4</sub>(<i>κ</i><sup>2</sup>-pma)(<i>µ</i>-bdt)] (<b>1</b>) and [Fe<sub>2</sub>(CO)<sub>4</sub>(<i>κ</i&g...

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Bibliographic Details
Main Authors: Andrea Mele, Federica Arrigoni, Luca De Gioia, Catherine Elleouet, François Y. Pétillon, Philippe Schollhammer, Giuseppe Zampella
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Inorganics
Subjects:
iron
dinuclear
diaza chelate
imino-pyridine
cyclic voltammetry
potential inversion
Online Access:https://www.mdpi.com/2304-6740/11/12/463

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