Study on initiating approach of (3-(tert-butylperoxy)propyl) trimethoxysilane on the polymerization of acrylonitrile as an initiator
(3-(tert-butylperoxy)propyl) trimethoxysilane (TBPT), is a tailor-made new style silane coupling agent with peroxide group, which have ability of initiating polymerization. This study used TBPT to generate free radical, and initiated the polymerization of acrylonitrile (AN), thereby forming polyacry...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Taylor & Francis Group
2017-01-01
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| Series: | Designed Monomers and Polymers |
| Subjects: | |
| Online Access: | http://dx.doi.org/10.1080/15685551.2017.1364031 |
| _version_ | 1818258232695586816 |
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| author | Yazhen Wang Yutao Di Shaobo Dong Zijian He Xueze Zhang Jia Shi Tianyu Lan |
| author_facet | Yazhen Wang Yutao Di Shaobo Dong Zijian He Xueze Zhang Jia Shi Tianyu Lan |
| author_sort | Yazhen Wang |
| collection | DOAJ |
| description | (3-(tert-butylperoxy)propyl) trimethoxysilane (TBPT), is a tailor-made new style silane coupling agent with peroxide group, which have ability of initiating polymerization. This study used TBPT to generate free radical, and initiated the polymerization of acrylonitrile (AN), thereby forming polyacrylonitrile (PAN) in two approaches, thermal initiation system and redox initiation system. Meanwhile this study bonded TBPT onto nano-TiO2 to get modified nano-TiO2 by means of the coupling function of TBPT, and then made the peroxide group of the modified nano-TiO2 decompose and initiate the polymerization of AN in thermal initiation system and redox initiation system respectively. The products were investigated and analyzed by FTIR, XPS and TG. The result showed that on one hand, in the products of the thermal initiation there was PAN, which both attached and unattached to the modified nano-TiO2; on the other hand, in the products of the redox initiation system the PAN unattached to the modified nano-TiO2 was produced, while the PAN attached to the modified nano-TiO2 was not. |
| first_indexed | 2024-12-12T17:56:17Z |
| format | Article |
| id | doaj.art-c8d119b5a40544179a47c6f397317f1e |
| institution | Directory Open Access Journal |
| issn | 1568-5551 |
| language | English |
| last_indexed | 2024-12-12T17:56:17Z |
| publishDate | 2017-01-01 |
| publisher | Taylor & Francis Group |
| record_format | Article |
| series | Designed Monomers and Polymers |
| spelling | doaj.art-c8d119b5a40544179a47c6f397317f1e2022-12-22T00:16:43ZengTaylor & Francis GroupDesigned Monomers and Polymers1568-55512017-01-0120146847510.1080/15685551.2017.13640311364031Study on initiating approach of (3-(tert-butylperoxy)propyl) trimethoxysilane on the polymerization of acrylonitrile as an initiatorYazhen Wang0Yutao Di1Shaobo Dong2Zijian He3Xueze Zhang4Jia Shi5Tianyu Lan6Qiqihar UniversityQiqihar UniversityQiqihar UniversityQiqihar UniversityQiqihar UniversityQiqihar UniversityQiqihar University(3-(tert-butylperoxy)propyl) trimethoxysilane (TBPT), is a tailor-made new style silane coupling agent with peroxide group, which have ability of initiating polymerization. This study used TBPT to generate free radical, and initiated the polymerization of acrylonitrile (AN), thereby forming polyacrylonitrile (PAN) in two approaches, thermal initiation system and redox initiation system. Meanwhile this study bonded TBPT onto nano-TiO2 to get modified nano-TiO2 by means of the coupling function of TBPT, and then made the peroxide group of the modified nano-TiO2 decompose and initiate the polymerization of AN in thermal initiation system and redox initiation system respectively. The products were investigated and analyzed by FTIR, XPS and TG. The result showed that on one hand, in the products of the thermal initiation there was PAN, which both attached and unattached to the modified nano-TiO2; on the other hand, in the products of the redox initiation system the PAN unattached to the modified nano-TiO2 was produced, while the PAN attached to the modified nano-TiO2 was not.http://dx.doi.org/10.1080/15685551.2017.1364031(3-(tert-butylperoxy)propyl) trimethoxysilanepolymerization of ANredox initiation systemmodified nano-TiO2 |
| spellingShingle | Yazhen Wang Yutao Di Shaobo Dong Zijian He Xueze Zhang Jia Shi Tianyu Lan Study on initiating approach of (3-(tert-butylperoxy)propyl) trimethoxysilane on the polymerization of acrylonitrile as an initiator Designed Monomers and Polymers (3-(tert-butylperoxy)propyl) trimethoxysilane polymerization of AN redox initiation system modified nano-TiO2 |
| title | Study on initiating approach of (3-(tert-butylperoxy)propyl) trimethoxysilane on the polymerization of acrylonitrile as an initiator |
| title_full | Study on initiating approach of (3-(tert-butylperoxy)propyl) trimethoxysilane on the polymerization of acrylonitrile as an initiator |
| title_fullStr | Study on initiating approach of (3-(tert-butylperoxy)propyl) trimethoxysilane on the polymerization of acrylonitrile as an initiator |
| title_full_unstemmed | Study on initiating approach of (3-(tert-butylperoxy)propyl) trimethoxysilane on the polymerization of acrylonitrile as an initiator |
| title_short | Study on initiating approach of (3-(tert-butylperoxy)propyl) trimethoxysilane on the polymerization of acrylonitrile as an initiator |
| title_sort | study on initiating approach of 3 tert butylperoxy propyl trimethoxysilane on the polymerization of acrylonitrile as an initiator |
| topic | (3-(tert-butylperoxy)propyl) trimethoxysilane polymerization of AN redox initiation system modified nano-TiO2 |
| url | http://dx.doi.org/10.1080/15685551.2017.1364031 |
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