Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene

A series of iron oxide nanocatalysts were prepared using an ultrasonically assisted co-precipitation technique. Molybdenum promoted Fe3O4 and Fe2O3 were prepared from the original materials by wet impregnation using a solution of ammonium molybdate. The catalysts were tested in the liquid phase oxid...

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Main Authors: Lokhat David, Oliver Mike, Carsky Milan
Format: Article
Language:English
Published: Sciendo 2015-06-01
Series:Polish Journal of Chemical Technology
Subjects:
Online Access:https://doi.org/10.1515/pjct-2015-0027
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author Lokhat David
Oliver Mike
Carsky Milan
author_facet Lokhat David
Oliver Mike
Carsky Milan
author_sort Lokhat David
collection DOAJ
description A series of iron oxide nanocatalysts were prepared using an ultrasonically assisted co-precipitation technique. Molybdenum promoted Fe3O4 and Fe2O3 were prepared from the original materials by wet impregnation using a solution of ammonium molybdate. The catalysts were tested in the liquid phase oxidation of benzene at atmospheric pressure and at 60°C using molecular oxygen. Phenol yields between 7% and 14.5% were obtained. The major products were pyrogallol and catechol.
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spelling doaj.art-c8eb2c2f2c4d44dc91e36cb63ae6f0582022-12-21T21:27:42ZengSciendoPolish Journal of Chemical Technology1899-47412015-06-01172434610.1515/pjct-2015-0027Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzeneLokhat David0Oliver Mike1Carsky Milan2University of KwaZulu-Natal, School of Engineering, Reactor Technology Research Group, Durban 4041, South AfricaEnergy Engineering International, Durban, 3610, South AfricaUniversity of KwaZulu-Natal, School of Engineering, Reactor Technology Research Group, Durban 4041, South AfricaA series of iron oxide nanocatalysts were prepared using an ultrasonically assisted co-precipitation technique. Molybdenum promoted Fe3O4 and Fe2O3 were prepared from the original materials by wet impregnation using a solution of ammonium molybdate. The catalysts were tested in the liquid phase oxidation of benzene at atmospheric pressure and at 60°C using molecular oxygen. Phenol yields between 7% and 14.5% were obtained. The major products were pyrogallol and catechol.https://doi.org/10.1515/pjct-2015-0027iron oxide nanocatalystbenzeneoxidationphenolliquid phase
spellingShingle Lokhat David
Oliver Mike
Carsky Milan
Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene
Polish Journal of Chemical Technology
iron oxide nanocatalyst
benzene
oxidation
phenol
liquid phase
title Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene
title_full Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene
title_fullStr Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene
title_full_unstemmed Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene
title_short Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene
title_sort preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene
topic iron oxide nanocatalyst
benzene
oxidation
phenol
liquid phase
url https://doi.org/10.1515/pjct-2015-0027
work_keys_str_mv AT lokhatdavid preparationofironoxidenanocatalystsandapplicationintheliquidphaseoxidationofbenzene
AT olivermike preparationofironoxidenanocatalystsandapplicationintheliquidphaseoxidationofbenzene
AT carskymilan preparationofironoxidenanocatalystsandapplicationintheliquidphaseoxidationofbenzene