Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene
A series of iron oxide nanocatalysts were prepared using an ultrasonically assisted co-precipitation technique. Molybdenum promoted Fe3O4 and Fe2O3 were prepared from the original materials by wet impregnation using a solution of ammonium molybdate. The catalysts were tested in the liquid phase oxid...
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Format: | Article |
Language: | English |
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Sciendo
2015-06-01
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Series: | Polish Journal of Chemical Technology |
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Online Access: | https://doi.org/10.1515/pjct-2015-0027 |
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author | Lokhat David Oliver Mike Carsky Milan |
author_facet | Lokhat David Oliver Mike Carsky Milan |
author_sort | Lokhat David |
collection | DOAJ |
description | A series of iron oxide nanocatalysts were prepared using an ultrasonically assisted co-precipitation technique. Molybdenum promoted Fe3O4 and Fe2O3 were prepared from the original materials by wet impregnation using a solution of ammonium molybdate. The catalysts were tested in the liquid phase oxidation of benzene at atmospheric pressure and at 60°C using molecular oxygen. Phenol yields between 7% and 14.5% were obtained. The major products were pyrogallol and catechol. |
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format | Article |
id | doaj.art-c8eb2c2f2c4d44dc91e36cb63ae6f058 |
institution | Directory Open Access Journal |
issn | 1899-4741 |
language | English |
last_indexed | 2024-12-18T00:10:02Z |
publishDate | 2015-06-01 |
publisher | Sciendo |
record_format | Article |
series | Polish Journal of Chemical Technology |
spelling | doaj.art-c8eb2c2f2c4d44dc91e36cb63ae6f0582022-12-21T21:27:42ZengSciendoPolish Journal of Chemical Technology1899-47412015-06-01172434610.1515/pjct-2015-0027Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzeneLokhat David0Oliver Mike1Carsky Milan2University of KwaZulu-Natal, School of Engineering, Reactor Technology Research Group, Durban 4041, South AfricaEnergy Engineering International, Durban, 3610, South AfricaUniversity of KwaZulu-Natal, School of Engineering, Reactor Technology Research Group, Durban 4041, South AfricaA series of iron oxide nanocatalysts were prepared using an ultrasonically assisted co-precipitation technique. Molybdenum promoted Fe3O4 and Fe2O3 were prepared from the original materials by wet impregnation using a solution of ammonium molybdate. The catalysts were tested in the liquid phase oxidation of benzene at atmospheric pressure and at 60°C using molecular oxygen. Phenol yields between 7% and 14.5% were obtained. The major products were pyrogallol and catechol.https://doi.org/10.1515/pjct-2015-0027iron oxide nanocatalystbenzeneoxidationphenolliquid phase |
spellingShingle | Lokhat David Oliver Mike Carsky Milan Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene Polish Journal of Chemical Technology iron oxide nanocatalyst benzene oxidation phenol liquid phase |
title | Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene |
title_full | Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene |
title_fullStr | Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene |
title_full_unstemmed | Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene |
title_short | Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene |
title_sort | preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene |
topic | iron oxide nanocatalyst benzene oxidation phenol liquid phase |
url | https://doi.org/10.1515/pjct-2015-0027 |
work_keys_str_mv | AT lokhatdavid preparationofironoxidenanocatalystsandapplicationintheliquidphaseoxidationofbenzene AT olivermike preparationofironoxidenanocatalystsandapplicationintheliquidphaseoxidationofbenzene AT carskymilan preparationofironoxidenanocatalystsandapplicationintheliquidphaseoxidationofbenzene |