Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethylformamide disolvate
The title compound, [Pb2Zn2(C22H18N2O4)2Cl4]·2C3H7NO, was synthesized using a step-by-step method and has a slipped sandwich configuration. The coordination environment of the Zn2+ ion is distorted square-pyramidal and it is coordinated by N2O2 of the Schiff base ligand and chloride; each P...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808032704 |
| _version_ | 1798019036670328832 |
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| author | Hailong Wang Daopeng Zhang Li-Fang Zhang |
| author_facet | Hailong Wang Daopeng Zhang Li-Fang Zhang |
| author_sort | Hailong Wang |
| collection | DOAJ |
| description | The title compound, [Pb2Zn2(C22H18N2O4)2Cl4]·2C3H7NO, was synthesized using a step-by-step method and has a slipped sandwich configuration. The coordination environment of the Zn2+ ion is distorted square-pyramidal and it is coordinated by N2O2 of the Schiff base ligand and chloride; each Pb2+ ion is coordinated by the four 6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolate (L) O atoms and two chloride ions. The ZnIIPbII dinuclear unit, through an inversion-symmetry operation, forms a tetrameric complex with double chloride bridges. |
| first_indexed | 2024-04-11T16:34:12Z |
| format | Article |
| id | doaj.art-c8f89e75bab74103bd1164f018bd81c9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:34:12Z |
| publishDate | 2008-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c8f89e75bab74103bd1164f018bd81c92022-12-22T04:13:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1408m140910.1107/S1600536808032704Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethylformamide disolvateHailong WangDaopeng ZhangLi-Fang ZhangThe title compound, [Pb2Zn2(C22H18N2O4)2Cl4]·2C3H7NO, was synthesized using a step-by-step method and has a slipped sandwich configuration. The coordination environment of the Zn2+ ion is distorted square-pyramidal and it is coordinated by N2O2 of the Schiff base ligand and chloride; each Pb2+ ion is coordinated by the four 6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolate (L) O atoms and two chloride ions. The ZnIIPbII dinuclear unit, through an inversion-symmetry operation, forms a tetrameric complex with double chloride bridges.http://scripts.iucr.org/cgi-bin/paper?S1600536808032704 |
| spellingShingle | Hailong Wang Daopeng Zhang Li-Fang Zhang Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethylformamide disolvate Acta Crystallographica Section E |
| title | Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethylformamide disolvate |
| title_full | Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethylformamide disolvate |
| title_fullStr | Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethylformamide disolvate |
| title_full_unstemmed | Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethylformamide disolvate |
| title_short | Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethylformamide disolvate |
| title_sort | di 956 chlorido dichlorido bis 956 6 6 8242 dimethoxy 2 2 8242 o phenylenebis nitrilomethylidyne diphenolato dilead ii dizinc ii n n 8242 dimethylformamide disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808032704 |
| work_keys_str_mv | AT hailongwang di956chloridodichloridobis956668242dimethoxy228242ophenylenebisnitrilomethylidynediphenolatodileadiidizinciinn8242dimethylformamidedisolvate AT daopengzhang di956chloridodichloridobis956668242dimethoxy228242ophenylenebisnitrilomethylidynediphenolatodileadiidizinciinn8242dimethylformamidedisolvate AT lifangzhang di956chloridodichloridobis956668242dimethoxy228242ophenylenebisnitrilomethylidynediphenolatodileadiidizinciinn8242dimethylformamidedisolvate |