Influence of Calcareous Deposits on Hydrogen Embrittlement Susceptibility of Q460 Steel

Cathodic protection is widely used to protect structural steel from corrosion in marine environments. However, an inappropriate cathodic potential may lead to hydrogen embrittlement (HE). Therefore, this study investigates the relationship between cathodic protection potential, structure and composi...

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Main Authors: Xilin Xiong, Haichun Yang, Tongqian Chen, Na Zhang, Tong Niu
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/17/5/1110
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author Xilin Xiong
Haichun Yang
Tongqian Chen
Na Zhang
Tong Niu
author_facet Xilin Xiong
Haichun Yang
Tongqian Chen
Na Zhang
Tong Niu
author_sort Xilin Xiong
collection DOAJ
description Cathodic protection is widely used to protect structural steel from corrosion in marine environments. However, an inappropriate cathodic potential may lead to hydrogen embrittlement (HE). Therefore, this study investigates the relationship between cathodic protection potential, structure and composition of calcareous deposits, and hydrogen embrittlement susceptibility of Q460 steel. The slow strain rate test results and fracture analysis reveal that Q460 steel had the smallest HE susceptibility when covered with the calcareous deposits formed under −1.1 V<sub>SCE</sub>. The deposits have a relatively thin calcium-rich inner layer and a condensed magnesium-rich outer layer, which can significantly inhibit hydrogen entry. A sustained deposition reaction during slow strain rate testing (SSRT) in artificial seawater can also decrease the HE susceptibility of Q460 steel.
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spelling doaj.art-c8fb044d1261404dade7d390dda42a492024-03-12T16:49:17ZengMDPI AGMaterials1996-19442024-02-01175111010.3390/ma17051110Influence of Calcareous Deposits on Hydrogen Embrittlement Susceptibility of Q460 SteelXilin Xiong0Haichun Yang1Tongqian Chen2Na Zhang3Tong Niu4Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, ChinaQingdao ZITN Micro-Electronics Co., Ltd., Qingdao 266114, ChinaSchool of Materials Science and Engineering, Chongqing University of Technology, Chongqing 400054, ChinaInstitute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, ChinaNCS Testing Technology Co., Ltd., Beijing 100081, ChinaCathodic protection is widely used to protect structural steel from corrosion in marine environments. However, an inappropriate cathodic potential may lead to hydrogen embrittlement (HE). Therefore, this study investigates the relationship between cathodic protection potential, structure and composition of calcareous deposits, and hydrogen embrittlement susceptibility of Q460 steel. The slow strain rate test results and fracture analysis reveal that Q460 steel had the smallest HE susceptibility when covered with the calcareous deposits formed under −1.1 V<sub>SCE</sub>. The deposits have a relatively thin calcium-rich inner layer and a condensed magnesium-rich outer layer, which can significantly inhibit hydrogen entry. A sustained deposition reaction during slow strain rate testing (SSRT) in artificial seawater can also decrease the HE susceptibility of Q460 steel.https://www.mdpi.com/1996-1944/17/5/1110Q460 steelcalcareous depositsslow strain testhydrogen embrittlement susceptibility
spellingShingle Xilin Xiong
Haichun Yang
Tongqian Chen
Na Zhang
Tong Niu
Influence of Calcareous Deposits on Hydrogen Embrittlement Susceptibility of Q460 Steel
Materials
Q460 steel
calcareous deposits
slow strain test
hydrogen embrittlement susceptibility
title Influence of Calcareous Deposits on Hydrogen Embrittlement Susceptibility of Q460 Steel
title_full Influence of Calcareous Deposits on Hydrogen Embrittlement Susceptibility of Q460 Steel
title_fullStr Influence of Calcareous Deposits on Hydrogen Embrittlement Susceptibility of Q460 Steel
title_full_unstemmed Influence of Calcareous Deposits on Hydrogen Embrittlement Susceptibility of Q460 Steel
title_short Influence of Calcareous Deposits on Hydrogen Embrittlement Susceptibility of Q460 Steel
title_sort influence of calcareous deposits on hydrogen embrittlement susceptibility of q460 steel
topic Q460 steel
calcareous deposits
slow strain test
hydrogen embrittlement susceptibility
url https://www.mdpi.com/1996-1944/17/5/1110
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AT tongqianchen influenceofcalcareousdepositsonhydrogenembrittlementsusceptibilityofq460steel
AT nazhang influenceofcalcareousdepositsonhydrogenembrittlementsusceptibilityofq460steel
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