Synthesis of Fumed-Pr-Pi-TCT as a Fluorescent Chemosensor for the Detection of Cyanide Ions in Aqueous Media
In this research, fumed silica scaffolds modified via treatment with (3-chloropropyl)-triethoxysilane, piperazine, and trichlorotriazine groups were deployed for the specific detection of cyanide ions, thus paving the way for the detection of environmental hazards and pollutants with high specificit...
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| Format: | Article |
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MDPI AG
2022-12-01
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| Series: | Water |
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| Online Access: | https://www.mdpi.com/2073-4441/14/24/4137 |
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| author | Sepideh Saberi Afshar Ghodsi Mohammadi Ziarani Fatemeh Mohajer Alireza Badiei Siavash Iravani Rajender S. Varma |
| author_facet | Sepideh Saberi Afshar Ghodsi Mohammadi Ziarani Fatemeh Mohajer Alireza Badiei Siavash Iravani Rajender S. Varma |
| author_sort | Sepideh Saberi Afshar |
| collection | DOAJ |
| description | In this research, fumed silica scaffolds modified via treatment with (3-chloropropyl)-triethoxysilane, piperazine, and trichlorotriazine groups were deployed for the specific detection of cyanide ions, thus paving the way for the detection of environmental hazards and pollutants with high specificity. Fumed-propyl -piperazine-trichlorotriazine (fumed-Pr-Pi-TCT) was synthesized in three steps starting from fume silica. It was functionalized subsequently using 3-(choloropropyl)-trimethoxysilane, piperazine, and trichlorotriazine, and then, the product was characterized through several methods including Fourier-transform infrared spectroscopy (FTIR) spectrum, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Fumed-Pr-Pi-TCT was exposed as a nanoparticle sensor to a range of different anions in aqueous media. This novel sensor could detect cyanide ions as a hazardous material, with the limit of detection being 0.82 × 10<sup>−4</sup> M. |
| first_indexed | 2024-03-09T15:44:12Z |
| format | Article |
| id | doaj.art-c909df14072c4c38ab10dbecd441b335 |
| institution | Directory Open Access Journal |
| issn | 2073-4441 |
| language | English |
| last_indexed | 2024-03-09T15:44:12Z |
| publishDate | 2022-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Water |
| spelling | doaj.art-c909df14072c4c38ab10dbecd441b3352023-11-24T18:43:36ZengMDPI AGWater2073-44412022-12-011424413710.3390/w14244137Synthesis of Fumed-Pr-Pi-TCT as a Fluorescent Chemosensor for the Detection of Cyanide Ions in Aqueous MediaSepideh Saberi Afshar0Ghodsi Mohammadi Ziarani1Fatemeh Mohajer2Alireza Badiei3Siavash Iravani4Rajender S. Varma5Department of Organic Chemistry, Faculty of Chemistry, University of Alzahra, Tehran 19938-91176, IranDepartment of Organic Chemistry, Faculty of Chemistry, University of Alzahra, Tehran 19938-91176, IranDepartment of Organic Chemistry, Faculty of Chemistry, University of Alzahra, Tehran 19938-91176, IranSchool of Chemistry, College of Science, University of Tehran, Tehran 14155-6455, IranFaculty of Pharmacy and Pharmaceutical Sciences, Isfahan University of Medical Sciences, Isfahan 81746-73441, IranRegional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute, Palacky University, Šlechtitelů 27, 783 71 Olomouc, Czech RepublicIn this research, fumed silica scaffolds modified via treatment with (3-chloropropyl)-triethoxysilane, piperazine, and trichlorotriazine groups were deployed for the specific detection of cyanide ions, thus paving the way for the detection of environmental hazards and pollutants with high specificity. Fumed-propyl -piperazine-trichlorotriazine (fumed-Pr-Pi-TCT) was synthesized in three steps starting from fume silica. It was functionalized subsequently using 3-(choloropropyl)-trimethoxysilane, piperazine, and trichlorotriazine, and then, the product was characterized through several methods including Fourier-transform infrared spectroscopy (FTIR) spectrum, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Fumed-Pr-Pi-TCT was exposed as a nanoparticle sensor to a range of different anions in aqueous media. This novel sensor could detect cyanide ions as a hazardous material, with the limit of detection being 0.82 × 10<sup>−4</sup> M.https://www.mdpi.com/2073-4441/14/24/4137Fumed-Pr-Pi-TCTpiperazinetrichlorotriazinefluorescent spectroscopycyanide ions |
| spellingShingle | Sepideh Saberi Afshar Ghodsi Mohammadi Ziarani Fatemeh Mohajer Alireza Badiei Siavash Iravani Rajender S. Varma Synthesis of Fumed-Pr-Pi-TCT as a Fluorescent Chemosensor for the Detection of Cyanide Ions in Aqueous Media Water Fumed-Pr-Pi-TCT piperazine trichlorotriazine fluorescent spectroscopy cyanide ions |
| title | Synthesis of Fumed-Pr-Pi-TCT as a Fluorescent Chemosensor for the Detection of Cyanide Ions in Aqueous Media |
| title_full | Synthesis of Fumed-Pr-Pi-TCT as a Fluorescent Chemosensor for the Detection of Cyanide Ions in Aqueous Media |
| title_fullStr | Synthesis of Fumed-Pr-Pi-TCT as a Fluorescent Chemosensor for the Detection of Cyanide Ions in Aqueous Media |
| title_full_unstemmed | Synthesis of Fumed-Pr-Pi-TCT as a Fluorescent Chemosensor for the Detection of Cyanide Ions in Aqueous Media |
| title_short | Synthesis of Fumed-Pr-Pi-TCT as a Fluorescent Chemosensor for the Detection of Cyanide Ions in Aqueous Media |
| title_sort | synthesis of fumed pr pi tct as a fluorescent chemosensor for the detection of cyanide ions in aqueous media |
| topic | Fumed-Pr-Pi-TCT piperazine trichlorotriazine fluorescent spectroscopy cyanide ions |
| url | https://www.mdpi.com/2073-4441/14/24/4137 |
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