Stannous Tungstate Semiconductor for Photocatalytic Degradation and Photoelectrochemical Water Splitting: A Review
The use of photocatalysis and photoelectrocatalysis is expected to achieve the efficient utilization of solar energy to alleviate and even solve the problems of energy depletion and environmental pfollution. At present, stannous tungstate materials have attracted extensive attention in the fields of...
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MDPI AG
2022-12-01
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Online Access: | https://www.mdpi.com/1996-1073/15/23/9194 |
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author | Weixin Qiu Yang Liu |
author_facet | Weixin Qiu Yang Liu |
author_sort | Weixin Qiu |
collection | DOAJ |
description | The use of photocatalysis and photoelectrocatalysis is expected to achieve the efficient utilization of solar energy to alleviate and even solve the problems of energy depletion and environmental pfollution. At present, stannous tungstate materials have attracted extensive attention in the fields of photocatalysis and photoelectrocatalysis as favorable candidates for such utilization because of their narrow band gap energy (which is ~1.7 eV for the α phase and ~2.7 eV for the β phase, respectively) and unique band structure (which covers the oxidation and reduction potential of water). However, their practical application is still limited by excessive electron–hole recombination and poor stability. In this review, basic information (crystal and electronic structures) related to photocatalysis and photoelectrocatalysis is presented. Additionally, various strategies to enhance the photocatalytic and photoelectrochemical properties of stannous tungstate materials, such as morphological modification, crystal facet engineering, doping modification, and multicomponent compositing, are summarized. Furthermore, the achievements and difficulties of the relevant studies are discussed. The information presented in this review can provide a reference for subsequent research on the photocatalytic and photoelectrochemical performance of tungstate-based materials. |
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issn | 1996-1073 |
language | English |
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spelling | doaj.art-c90b9a2e209945bbbc134d6d9e952cf62023-11-24T10:56:50ZengMDPI AGEnergies1996-10732022-12-011523919410.3390/en15239194Stannous Tungstate Semiconductor for Photocatalytic Degradation and Photoelectrochemical Water Splitting: A ReviewWeixin Qiu0Yang Liu1School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, ChinaSchool of Chemistry and Chemical Engineering, Central South University, Changsha 410083, ChinaThe use of photocatalysis and photoelectrocatalysis is expected to achieve the efficient utilization of solar energy to alleviate and even solve the problems of energy depletion and environmental pfollution. At present, stannous tungstate materials have attracted extensive attention in the fields of photocatalysis and photoelectrocatalysis as favorable candidates for such utilization because of their narrow band gap energy (which is ~1.7 eV for the α phase and ~2.7 eV for the β phase, respectively) and unique band structure (which covers the oxidation and reduction potential of water). However, their practical application is still limited by excessive electron–hole recombination and poor stability. In this review, basic information (crystal and electronic structures) related to photocatalysis and photoelectrocatalysis is presented. Additionally, various strategies to enhance the photocatalytic and photoelectrochemical properties of stannous tungstate materials, such as morphological modification, crystal facet engineering, doping modification, and multicomponent compositing, are summarized. Furthermore, the achievements and difficulties of the relevant studies are discussed. The information presented in this review can provide a reference for subsequent research on the photocatalytic and photoelectrochemical performance of tungstate-based materials.https://www.mdpi.com/1996-1073/15/23/9194stannous tungstatephotocatalysisphotoelectrocatalysiswater splittingdegradation |
spellingShingle | Weixin Qiu Yang Liu Stannous Tungstate Semiconductor for Photocatalytic Degradation and Photoelectrochemical Water Splitting: A Review Energies stannous tungstate photocatalysis photoelectrocatalysis water splitting degradation |
title | Stannous Tungstate Semiconductor for Photocatalytic Degradation and Photoelectrochemical Water Splitting: A Review |
title_full | Stannous Tungstate Semiconductor for Photocatalytic Degradation and Photoelectrochemical Water Splitting: A Review |
title_fullStr | Stannous Tungstate Semiconductor for Photocatalytic Degradation and Photoelectrochemical Water Splitting: A Review |
title_full_unstemmed | Stannous Tungstate Semiconductor for Photocatalytic Degradation and Photoelectrochemical Water Splitting: A Review |
title_short | Stannous Tungstate Semiconductor for Photocatalytic Degradation and Photoelectrochemical Water Splitting: A Review |
title_sort | stannous tungstate semiconductor for photocatalytic degradation and photoelectrochemical water splitting a review |
topic | stannous tungstate photocatalysis photoelectrocatalysis water splitting degradation |
url | https://www.mdpi.com/1996-1073/15/23/9194 |
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