Synthesis, Characterization, and Crystal Structure of a Triazine Anion Pentafluoroosmium(VI) Complex
The synthesis and characterization of a novel triazine anion pentafluoroosmium(VI) complex are presented. The single crystal determination of the title compound (hereafter denoted 1) was carried out at −140 °C. Compound 1, C3F4N3OsF5, crystallizes in the monoclinic space group, P21/n, with unit cell...
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| Language: | English |
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MDPI AG
2018-01-01
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| Series: | Crystals |
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| Online Access: | http://www.mdpi.com/2073-4352/8/2/63 |
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| author | Monther A. Khanfar Basem F. Ali Hashem Shorafa Konrad Seppelt |
| author_facet | Monther A. Khanfar Basem F. Ali Hashem Shorafa Konrad Seppelt |
| author_sort | Monther A. Khanfar |
| collection | DOAJ |
| description | The synthesis and characterization of a novel triazine anion pentafluoroosmium(VI) complex are presented. The single crystal determination of the title compound (hereafter denoted 1) was carried out at −140 °C. Compound 1, C3F4N3OsF5, crystallizes in the monoclinic space group, P21/n, with unit cell dimensions: a = 8.6809(17) Å, b = 7.6848(15) Å, c = 12.415(3) Å, β = 102.633(4)°, V = 808.2(3) Å3, and Z = 4. Synthesis, characterization, X-ray diffraction study along with the crystal supramolecular analysis of the title complex were carried out. The complex contains the anionic triazine unit C3N3F4− acting as a mono dentate ligand to osmium(VI) with five fluoro ligands in a slightly distorted octahedral geometry around osmium(VI) ion (osmium is denoted as Os). The C3N3F4−, triazine anion ring deviates from planarity, only with the C1 being tetrahedral. The crystal lattice of the title compound displays significant intermolecular X···X interactions, namly F···F, F···N and F···C. All types of X···X bonding consolidate to form a three-dimensional network. |
| first_indexed | 2024-04-12T19:43:35Z |
| format | Article |
| id | doaj.art-c90bb0f99d064bf2b9325a48539ad0c5 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-12T19:43:35Z |
| publishDate | 2018-01-01 |
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| record_format | Article |
| series | Crystals |
| spelling | doaj.art-c90bb0f99d064bf2b9325a48539ad0c52022-12-22T03:19:02ZengMDPI AGCrystals2073-43522018-01-01826310.3390/cryst8020063cryst8020063Synthesis, Characterization, and Crystal Structure of a Triazine Anion Pentafluoroosmium(VI) ComplexMonther A. Khanfar0Basem F. Ali1Hashem Shorafa2Konrad Seppelt3Department of Chemistry, The University of Jordan, Amman 11942, JordanDepartment of Chemistry, King Faisal University, Al-Ahssa, Hufof 31982, Saudi ArabiaInstitut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstraße 34/36, 14195 Berlin, GermanyInstitut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstraße 34/36, 14195 Berlin, GermanyThe synthesis and characterization of a novel triazine anion pentafluoroosmium(VI) complex are presented. The single crystal determination of the title compound (hereafter denoted 1) was carried out at −140 °C. Compound 1, C3F4N3OsF5, crystallizes in the monoclinic space group, P21/n, with unit cell dimensions: a = 8.6809(17) Å, b = 7.6848(15) Å, c = 12.415(3) Å, β = 102.633(4)°, V = 808.2(3) Å3, and Z = 4. Synthesis, characterization, X-ray diffraction study along with the crystal supramolecular analysis of the title complex were carried out. The complex contains the anionic triazine unit C3N3F4− acting as a mono dentate ligand to osmium(VI) with five fluoro ligands in a slightly distorted octahedral geometry around osmium(VI) ion (osmium is denoted as Os). The C3N3F4−, triazine anion ring deviates from planarity, only with the C1 being tetrahedral. The crystal lattice of the title compound displays significant intermolecular X···X interactions, namly F···F, F···N and F···C. All types of X···X bonding consolidate to form a three-dimensional network.http://www.mdpi.com/2073-4352/8/2/63triazine anioncrystal structurefluoroosmium(VI) complexessupramolecular crystalF···FF···NF···C intermolecular interactions |
| spellingShingle | Monther A. Khanfar Basem F. Ali Hashem Shorafa Konrad Seppelt Synthesis, Characterization, and Crystal Structure of a Triazine Anion Pentafluoroosmium(VI) Complex Crystals triazine anion crystal structure fluoroosmium(VI) complexes supramolecular crystal F···F F···N F···C intermolecular interactions |
| title | Synthesis, Characterization, and Crystal Structure of a Triazine Anion Pentafluoroosmium(VI) Complex |
| title_full | Synthesis, Characterization, and Crystal Structure of a Triazine Anion Pentafluoroosmium(VI) Complex |
| title_fullStr | Synthesis, Characterization, and Crystal Structure of a Triazine Anion Pentafluoroosmium(VI) Complex |
| title_full_unstemmed | Synthesis, Characterization, and Crystal Structure of a Triazine Anion Pentafluoroosmium(VI) Complex |
| title_short | Synthesis, Characterization, and Crystal Structure of a Triazine Anion Pentafluoroosmium(VI) Complex |
| title_sort | synthesis characterization and crystal structure of a triazine anion pentafluoroosmium vi complex |
| topic | triazine anion crystal structure fluoroosmium(VI) complexes supramolecular crystal F···F F···N F···C intermolecular interactions |
| url | http://www.mdpi.com/2073-4352/8/2/63 |
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