Dicaesium tetramagnesium pentakis(carbonate) decahydrate, Cs2Mg4(CO3)5·10H2O
The title carbonate hydrate, Cs2Mg4(CO3)5·10H2O, was crystallized at room temperature out of aqueous solutions containing caesium bicarbonate and magnesium nitrate. Its monoclinic crystal structure (P21/n) consists of double chains of composition 1∞[Mg(H2O)2/1(CO3)3/3], isolated [Mg(H2O)(CO3)2]2– un...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-02-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314620001650 |
| _version_ | 1818952619149754368 |
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| author | Christine Rincke Horst Schmidt Wolfgang Voigt |
| author_facet | Christine Rincke Horst Schmidt Wolfgang Voigt |
| author_sort | Christine Rincke |
| collection | DOAJ |
| description | The title carbonate hydrate, Cs2Mg4(CO3)5·10H2O, was crystallized at room temperature out of aqueous solutions containing caesium bicarbonate and magnesium nitrate. Its monoclinic crystal structure (P21/n) consists of double chains of composition 1∞[Mg(H2O)2/1(CO3)3/3], isolated [Mg(H2O)(CO3)2]2– units, two crystallographically distinct Cs+ ions and a free water molecule. The crystal under investigation was twinned by reticular pseudomerohedry. |
| first_indexed | 2024-12-20T09:53:15Z |
| format | Article |
| id | doaj.art-c91a47070ab746b3ad9bafc63528eebf |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-20T09:53:15Z |
| publishDate | 2020-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-c91a47070ab746b3ad9bafc63528eebf2022-12-21T19:44:32ZengInternational Union of CrystallographyIUCrData2414-31462020-02-0152x20016510.1107/S2414314620001650wm4122Dicaesium tetramagnesium pentakis(carbonate) decahydrate, Cs2Mg4(CO3)5·10H2OChristine Rincke0Horst Schmidt1Wolfgang Voigt2Institute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09599 Freiberg, GermanyInstitute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09599 Freiberg, GermanyInstitute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09599 Freiberg, GermanyThe title carbonate hydrate, Cs2Mg4(CO3)5·10H2O, was crystallized at room temperature out of aqueous solutions containing caesium bicarbonate and magnesium nitrate. Its monoclinic crystal structure (P21/n) consists of double chains of composition 1∞[Mg(H2O)2/1(CO3)3/3], isolated [Mg(H2O)(CO3)2]2– units, two crystallographically distinct Cs+ ions and a free water molecule. The crystal under investigation was twinned by reticular pseudomerohedry.http://scripts.iucr.org/cgi-bin/paper?S2414314620001650carbonatehydratemagnesium compoundcaesium compoundtwinningcrystal structure |
| spellingShingle | Christine Rincke Horst Schmidt Wolfgang Voigt Dicaesium tetramagnesium pentakis(carbonate) decahydrate, Cs2Mg4(CO3)5·10H2O IUCrData carbonate hydrate magnesium compound caesium compound twinning crystal structure |
| title | Dicaesium tetramagnesium pentakis(carbonate) decahydrate, Cs2Mg4(CO3)5·10H2O |
| title_full | Dicaesium tetramagnesium pentakis(carbonate) decahydrate, Cs2Mg4(CO3)5·10H2O |
| title_fullStr | Dicaesium tetramagnesium pentakis(carbonate) decahydrate, Cs2Mg4(CO3)5·10H2O |
| title_full_unstemmed | Dicaesium tetramagnesium pentakis(carbonate) decahydrate, Cs2Mg4(CO3)5·10H2O |
| title_short | Dicaesium tetramagnesium pentakis(carbonate) decahydrate, Cs2Mg4(CO3)5·10H2O |
| title_sort | dicaesium tetramagnesium pentakis carbonate decahydrate cs2mg4 co3 5·10h2o |
| topic | carbonate hydrate magnesium compound caesium compound twinning crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314620001650 |
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