Cementitious Behavior of Argon Oxygen Decarburization Stainless Steel Slag and Its Stabilization on Chromium

The study mainly aims at the potential of Argon Oxygen Decarburization Slag (AODS) as a supplementary cementitious material and explores the mechanisms of stabilization/solidification (S/S) of chromium in cement-based composite pastes. The basic cementitious parameters, such as water requirement, se...

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Main Authors: Ya-Jun Wang, Ya-Nan Zeng, Jun-Guo Li, Yu-Zhu Zhang
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/10/10/876
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author Ya-Jun Wang
Ya-Nan Zeng
Jun-Guo Li
Yu-Zhu Zhang
author_facet Ya-Jun Wang
Ya-Nan Zeng
Jun-Guo Li
Yu-Zhu Zhang
author_sort Ya-Jun Wang
collection DOAJ
description The study mainly aims at the potential of Argon Oxygen Decarburization Slag (AODS) as a supplementary cementitious material and explores the mechanisms of stabilization/solidification (S/S) of chromium in cement-based composite pastes. The basic cementitious parameters, such as water requirement, setting time, soundness, hydration characteristics, and strength indexes of composite binders, were examined through standard methods. The results showed that the most beneficial mineral phase in AODS for cementitious behavior was beta dicalcium silicate (β-C<sub>2</sub>S). The utilization of a higher AODS dosage in composite binders increased the water requirement and the setting time, while it decreased the hydration heat and the strength indexes. Although the AODS possessed limited cementitious properties, it conformed the Grade II steel slag powder qualified for concrete and cement. Sequential leaching tests were conducted targeting the leachability of chromium in the pastes with different AODS dosage and curing time. Results showed that with the lower AODS dosage and the longer curing time, the S/S efficiency for chromium leaching from the composite paste was better. Utilization of AODS as a cement substitute not only can recycle this solid waste and decrease the emission of CO<sub>2</sub> concerning cement production, but also helps to effectively reduce the chromium leaching risk.
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spelling doaj.art-c9372f29086945d191e2777f7f9422682023-11-20T15:16:46ZengMDPI AGCrystals2073-43522020-09-01101087610.3390/cryst10100876Cementitious Behavior of Argon Oxygen Decarburization Stainless Steel Slag and Its Stabilization on ChromiumYa-Jun Wang0Ya-Nan Zeng1Jun-Guo Li2Yu-Zhu Zhang3School of Materials and Metallurgy, Northeastern University, Shenyang 110819, ChinaSchool of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009, ChinaSchool of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009, ChinaSchool of Materials and Metallurgy, Northeastern University, Shenyang 110819, ChinaThe study mainly aims at the potential of Argon Oxygen Decarburization Slag (AODS) as a supplementary cementitious material and explores the mechanisms of stabilization/solidification (S/S) of chromium in cement-based composite pastes. The basic cementitious parameters, such as water requirement, setting time, soundness, hydration characteristics, and strength indexes of composite binders, were examined through standard methods. The results showed that the most beneficial mineral phase in AODS for cementitious behavior was beta dicalcium silicate (β-C<sub>2</sub>S). The utilization of a higher AODS dosage in composite binders increased the water requirement and the setting time, while it decreased the hydration heat and the strength indexes. Although the AODS possessed limited cementitious properties, it conformed the Grade II steel slag powder qualified for concrete and cement. Sequential leaching tests were conducted targeting the leachability of chromium in the pastes with different AODS dosage and curing time. Results showed that with the lower AODS dosage and the longer curing time, the S/S efficiency for chromium leaching from the composite paste was better. Utilization of AODS as a cement substitute not only can recycle this solid waste and decrease the emission of CO<sub>2</sub> concerning cement production, but also helps to effectively reduce the chromium leaching risk.https://www.mdpi.com/2073-4352/10/10/876AOD slagcementitious propertystabilization/solidificationchromiumleachability
spellingShingle Ya-Jun Wang
Ya-Nan Zeng
Jun-Guo Li
Yu-Zhu Zhang
Cementitious Behavior of Argon Oxygen Decarburization Stainless Steel Slag and Its Stabilization on Chromium
Crystals
AOD slag
cementitious property
stabilization/solidification
chromium
leachability
title Cementitious Behavior of Argon Oxygen Decarburization Stainless Steel Slag and Its Stabilization on Chromium
title_full Cementitious Behavior of Argon Oxygen Decarburization Stainless Steel Slag and Its Stabilization on Chromium
title_fullStr Cementitious Behavior of Argon Oxygen Decarburization Stainless Steel Slag and Its Stabilization on Chromium
title_full_unstemmed Cementitious Behavior of Argon Oxygen Decarburization Stainless Steel Slag and Its Stabilization on Chromium
title_short Cementitious Behavior of Argon Oxygen Decarburization Stainless Steel Slag and Its Stabilization on Chromium
title_sort cementitious behavior of argon oxygen decarburization stainless steel slag and its stabilization on chromium
topic AOD slag
cementitious property
stabilization/solidification
chromium
leachability
url https://www.mdpi.com/2073-4352/10/10/876
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AT junguoli cementitiousbehaviorofargonoxygendecarburizationstainlesssteelslaganditsstabilizationonchromium
AT yuzhuzhang cementitiousbehaviorofargonoxygendecarburizationstainlesssteelslaganditsstabilizationonchromium