Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review

Significant efforts are being made across academia and industry to better characterize lithium ion battery cells as reliance on the technology for applications ranging from green energy storage to electric mobility increases. The measurement of short-term and long-term volume expansion in lithium-io...

Full description

Bibliographic Details
Main Authors: Tessa Krause, Daniel Nusko, Luciana Pitta Bauermann, Matthias Vetter, Marcel Schäfer, Carlo Holly
Format: Article
Language:English
Published: MDPI AG 2024-03-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/17/7/1566
_version_ 1797212663054336000
author Tessa Krause
Daniel Nusko
Luciana Pitta Bauermann
Matthias Vetter
Marcel Schäfer
Carlo Holly
author_facet Tessa Krause
Daniel Nusko
Luciana Pitta Bauermann
Matthias Vetter
Marcel Schäfer
Carlo Holly
author_sort Tessa Krause
collection DOAJ
description Significant efforts are being made across academia and industry to better characterize lithium ion battery cells as reliance on the technology for applications ranging from green energy storage to electric mobility increases. The measurement of short-term and long-term volume expansion in lithium-ion battery cells is relevant for several reasons. For instance, expansion provides information about the quality and homogeneity of battery cells during charge and discharge cycles. Expansion also provides information about aging over the cell’s lifetime. Expansion measurements are useful for the evaluation of new materials and the improvement of end-of-line quality tests during cell production. These measurements may also indicate the safety of battery cells by aiding in predicting the state of charge and the state of health over the lifetime of the cell. Expansion measurements can also assess inhomogeneities on the electrodes, in addition to defects such as gas accumulation and lithium plating. In this review, we first establish the mechanisms through which reversible and irreversible volume expansion occur. We then explore the current state-of-the-art for both contact and noncontact measurements of volume expansion. This review compiles the existing literature on four approaches to contact measurement and eight noncontact measurement approaches. Finally, we discuss the different considerations when selecting an appropriate measurement technique.
first_indexed 2024-04-24T10:45:57Z
format Article
id doaj.art-c9489f5b0ab346b2a61b60d64b84853e
institution Directory Open Access Journal
issn 1996-1073
language English
last_indexed 2024-04-24T10:45:57Z
publishDate 2024-03-01
publisher MDPI AG
record_format Article
series Energies
spelling doaj.art-c9489f5b0ab346b2a61b60d64b84853e2024-04-12T13:17:44ZengMDPI AGEnergies1996-10732024-03-01177156610.3390/en17071566Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A ReviewTessa Krause0Daniel Nusko1Luciana Pitta Bauermann2Matthias Vetter3Marcel Schäfer4Carlo Holly5Chair for Technology of Optical Systems TOS, RWTH Aachen University, Steinbachstraße 15, 52074 Aachen, GermanyFraunhofer Institute for Solar Energy Systems ISE, Heidenhofstr. 2, 79110 Freiburg, GermanyFraunhofer Institute for Solar Energy Systems ISE, Heidenhofstr. 2, 79110 Freiburg, GermanyFraunhofer Institute for Solar Energy Systems ISE, Heidenhofstr. 2, 79110 Freiburg, GermanyPrecitec GmbH & Co., KG, Draisstraße 1, 76571 Gaggenau, GermanyChair for Technology of Optical Systems TOS, RWTH Aachen University, Steinbachstraße 15, 52074 Aachen, GermanySignificant efforts are being made across academia and industry to better characterize lithium ion battery cells as reliance on the technology for applications ranging from green energy storage to electric mobility increases. The measurement of short-term and long-term volume expansion in lithium-ion battery cells is relevant for several reasons. For instance, expansion provides information about the quality and homogeneity of battery cells during charge and discharge cycles. Expansion also provides information about aging over the cell’s lifetime. Expansion measurements are useful for the evaluation of new materials and the improvement of end-of-line quality tests during cell production. These measurements may also indicate the safety of battery cells by aiding in predicting the state of charge and the state of health over the lifetime of the cell. Expansion measurements can also assess inhomogeneities on the electrodes, in addition to defects such as gas accumulation and lithium plating. In this review, we first establish the mechanisms through which reversible and irreversible volume expansion occur. We then explore the current state-of-the-art for both contact and noncontact measurements of volume expansion. This review compiles the existing literature on four approaches to contact measurement and eight noncontact measurement approaches. Finally, we discuss the different considerations when selecting an appropriate measurement technique.https://www.mdpi.com/1996-1073/17/7/1566lithium-ionbattery cellsexpansion measurementsvolume expansionthickness changes
spellingShingle Tessa Krause
Daniel Nusko
Luciana Pitta Bauermann
Matthias Vetter
Marcel Schäfer
Carlo Holly
Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review
Energies
lithium-ion
battery cells
expansion measurements
volume expansion
thickness changes
title Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review
title_full Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review
title_fullStr Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review
title_full_unstemmed Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review
title_short Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review
title_sort methods for quantifying expansion in lithium ion battery cells resulting from cycling a review
topic lithium-ion
battery cells
expansion measurements
volume expansion
thickness changes
url https://www.mdpi.com/1996-1073/17/7/1566
work_keys_str_mv AT tessakrause methodsforquantifyingexpansioninlithiumionbatterycellsresultingfromcyclingareview
AT danielnusko methodsforquantifyingexpansioninlithiumionbatterycellsresultingfromcyclingareview
AT lucianapittabauermann methodsforquantifyingexpansioninlithiumionbatterycellsresultingfromcyclingareview
AT matthiasvetter methodsforquantifyingexpansioninlithiumionbatterycellsresultingfromcyclingareview
AT marcelschafer methodsforquantifyingexpansioninlithiumionbatterycellsresultingfromcyclingareview
AT carloholly methodsforquantifyingexpansioninlithiumionbatterycellsresultingfromcyclingareview