Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs
In this paper, some series of lead borate glasses and glass ceramics singly doped with Dy<sup>3+</sup> ions were prepared and then studied using spectroscopic techniques. Our research includes mainly studies of the luminescence properties of received materials for white light. The lumine...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2020-11-01
|
Series: | Materials |
Subjects: | |
Online Access: | https://www.mdpi.com/1996-1944/13/21/5022 |
_version_ | 1797548636590047232 |
---|---|
author | Agata Górny Marta Kuwik Wojciech A. Pisarski Joanna Pisarska |
author_facet | Agata Górny Marta Kuwik Wojciech A. Pisarski Joanna Pisarska |
author_sort | Agata Górny |
collection | DOAJ |
description | In this paper, some series of lead borate glasses and glass ceramics singly doped with Dy<sup>3+</sup> ions were prepared and then studied using spectroscopic techniques. Our research includes mainly studies of the luminescence properties of received materials for white light. The luminescence bands associated with the characteristic <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>15/2</sub> (blue), <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>13/2</sub> (yellow) and <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>11/2</sub> (red) transitions of trivalent dysprosium in lead borate systems are well observed. In particular, the Commission Internationale de I’Eclairage (CIE) chromaticity coordinates (x, y) were calculated in relation to potential applications for white light-emitting diodes (W-LEDs). Their values depend on the relative B<sub>2</sub>O<sub>3</sub>/PbO ratios and PbX<sub>2</sub> contents (where X = Cl, F, Br) in glass composition. For glass-ceramics, the chromaticity coordinates are changed significantly under different excitation wavelengths. |
first_indexed | 2024-03-10T15:02:28Z |
format | Article |
id | doaj.art-c96305e5516048b0aa7502ae9bbbb0d1 |
institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-10T15:02:28Z |
publishDate | 2020-11-01 |
publisher | MDPI AG |
record_format | Article |
series | Materials |
spelling | doaj.art-c96305e5516048b0aa7502ae9bbbb0d12023-11-20T20:06:31ZengMDPI AGMaterials1996-19442020-11-011321502210.3390/ma13215022Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDsAgata Górny0Marta Kuwik1Wojciech A. Pisarski2Joanna Pisarska3Institute of Chemistry, University of Silesia, Szkolna 9 Street, 40-007 Katowice, PolandInstitute of Chemistry, University of Silesia, Szkolna 9 Street, 40-007 Katowice, PolandInstitute of Chemistry, University of Silesia, Szkolna 9 Street, 40-007 Katowice, PolandInstitute of Chemistry, University of Silesia, Szkolna 9 Street, 40-007 Katowice, PolandIn this paper, some series of lead borate glasses and glass ceramics singly doped with Dy<sup>3+</sup> ions were prepared and then studied using spectroscopic techniques. Our research includes mainly studies of the luminescence properties of received materials for white light. The luminescence bands associated with the characteristic <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>15/2</sub> (blue), <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>13/2</sub> (yellow) and <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>11/2</sub> (red) transitions of trivalent dysprosium in lead borate systems are well observed. In particular, the Commission Internationale de I’Eclairage (CIE) chromaticity coordinates (x, y) were calculated in relation to potential applications for white light-emitting diodes (W-LEDs). Their values depend on the relative B<sub>2</sub>O<sub>3</sub>/PbO ratios and PbX<sub>2</sub> contents (where X = Cl, F, Br) in glass composition. For glass-ceramics, the chromaticity coordinates are changed significantly under different excitation wavelengths.https://www.mdpi.com/1996-1944/13/21/5022lead borate glassesglass-ceramicsdysprosium ionswhite luminescence |
spellingShingle | Agata Górny Marta Kuwik Wojciech A. Pisarski Joanna Pisarska Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs Materials lead borate glasses glass-ceramics dysprosium ions white luminescence |
title | Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs |
title_full | Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs |
title_fullStr | Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs |
title_full_unstemmed | Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs |
title_short | Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs |
title_sort | lead borate glasses and glass ceramics singly doped with dy sup 3 sup for white leds |
topic | lead borate glasses glass-ceramics dysprosium ions white luminescence |
url | https://www.mdpi.com/1996-1944/13/21/5022 |
work_keys_str_mv | AT agatagorny leadborateglassesandglassceramicssinglydopedwithdysup3supforwhiteleds AT martakuwik leadborateglassesandglassceramicssinglydopedwithdysup3supforwhiteleds AT wojciechapisarski leadborateglassesandglassceramicssinglydopedwithdysup3supforwhiteleds AT joannapisarska leadborateglassesandglassceramicssinglydopedwithdysup3supforwhiteleds |