Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs

In this paper, some series of lead borate glasses and glass ceramics singly doped with Dy<sup>3+</sup> ions were prepared and then studied using spectroscopic techniques. Our research includes mainly studies of the luminescence properties of received materials for white light. The lumine...

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Main Authors: Agata Górny, Marta Kuwik, Wojciech A. Pisarski, Joanna Pisarska
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/21/5022
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author Agata Górny
Marta Kuwik
Wojciech A. Pisarski
Joanna Pisarska
author_facet Agata Górny
Marta Kuwik
Wojciech A. Pisarski
Joanna Pisarska
author_sort Agata Górny
collection DOAJ
description In this paper, some series of lead borate glasses and glass ceramics singly doped with Dy<sup>3+</sup> ions were prepared and then studied using spectroscopic techniques. Our research includes mainly studies of the luminescence properties of received materials for white light. The luminescence bands associated with the characteristic <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>15/2</sub> (blue), <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>13/2</sub> (yellow) and <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>11/2</sub> (red) transitions of trivalent dysprosium in lead borate systems are well observed. In particular, the Commission Internationale de I’Eclairage (CIE) chromaticity coordinates (x, y) were calculated in relation to potential applications for white light-emitting diodes (W-LEDs). Their values depend on the relative B<sub>2</sub>O<sub>3</sub>/PbO ratios and PbX<sub>2</sub> contents (where X = Cl, F, Br) in glass composition. For glass-ceramics, the chromaticity coordinates are changed significantly under different excitation wavelengths.
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spelling doaj.art-c96305e5516048b0aa7502ae9bbbb0d12023-11-20T20:06:31ZengMDPI AGMaterials1996-19442020-11-011321502210.3390/ma13215022Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDsAgata Górny0Marta Kuwik1Wojciech A. Pisarski2Joanna Pisarska3Institute of Chemistry, University of Silesia, Szkolna 9 Street, 40-007 Katowice, PolandInstitute of Chemistry, University of Silesia, Szkolna 9 Street, 40-007 Katowice, PolandInstitute of Chemistry, University of Silesia, Szkolna 9 Street, 40-007 Katowice, PolandInstitute of Chemistry, University of Silesia, Szkolna 9 Street, 40-007 Katowice, PolandIn this paper, some series of lead borate glasses and glass ceramics singly doped with Dy<sup>3+</sup> ions were prepared and then studied using spectroscopic techniques. Our research includes mainly studies of the luminescence properties of received materials for white light. The luminescence bands associated with the characteristic <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>15/2</sub> (blue), <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>13/2</sub> (yellow) and <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>11/2</sub> (red) transitions of trivalent dysprosium in lead borate systems are well observed. In particular, the Commission Internationale de I’Eclairage (CIE) chromaticity coordinates (x, y) were calculated in relation to potential applications for white light-emitting diodes (W-LEDs). Their values depend on the relative B<sub>2</sub>O<sub>3</sub>/PbO ratios and PbX<sub>2</sub> contents (where X = Cl, F, Br) in glass composition. For glass-ceramics, the chromaticity coordinates are changed significantly under different excitation wavelengths.https://www.mdpi.com/1996-1944/13/21/5022lead borate glassesglass-ceramicsdysprosium ionswhite luminescence
spellingShingle Agata Górny
Marta Kuwik
Wojciech A. Pisarski
Joanna Pisarska
Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs
Materials
lead borate glasses
glass-ceramics
dysprosium ions
white luminescence
title Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs
title_full Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs
title_fullStr Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs
title_full_unstemmed Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs
title_short Lead Borate Glasses and Glass-Ceramics Singly Doped with Dy<sup>3+</sup> for White LEDs
title_sort lead borate glasses and glass ceramics singly doped with dy sup 3 sup for white leds
topic lead borate glasses
glass-ceramics
dysprosium ions
white luminescence
url https://www.mdpi.com/1996-1944/13/21/5022
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