A kinetic study of the photoinduced oxo-transfer using a Mo complex anchored to TiO2
Kinetic study of the photo-assisted oxygen atom transfer reaction (OAT) using a dioxo-Mo complex anchored on TiO2, stimulated by light, was performed at ambient conditions using triphenylphosphine (PPh3) as a model molecule. The kinetic of the OAT reaction was studied with three catalytic systems:...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Universidad de Antioquia
2021-05-01
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| Series: | Revista Facultad de Ingeniería Universidad de Antioquia |
| Subjects: | |
| Online Access: | https://revistas.udea.edu.co/index.php/ingenieria/article/view/340957 |
| Summary: | Kinetic study of the photo-assisted oxygen atom transfer reaction (OAT) using a dioxo-Mo complex anchored on TiO2, stimulated by light, was performed at ambient conditions using triphenylphosphine (PPh3) as a model molecule. The kinetic of the OAT reaction was studied with three catalytic systems: 4,4’-dicarboxylate-2,2’-bipyridine-dioxochloromolybdenum (MoO2L/TiO2), H2MoO4 (H2MoO4/TiO2) and molybdenum oxide (MoO3/ TiO2) anchored to TiO2. The MoO2L/TiO2 gives conversion higher than 90% and selectivity (to phosphine oxide) close to 100%. MoO3/TiO2 did not allow the oxo-transference, suggesting the importance of the bipyridine ligand as an electronic connector between MoO2L unit and TiO2. With the MoO2L/TiO2 system was observed that when the photonic flux increases, the quantum yield, and the OAT reaction rate increases.
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| ISSN: | 0120-6230 2422-2844 |