Semiconductor Quantum Dots as Target Analytes: Properties, Surface Chemistry and Detection

Since the discovery of Quantum Dots (QDs) by Alexey I. Ekimov in 1981, the interest of researchers in that particular type of nanomaterials (NMs) with unique optical and electrical properties has been increasing year by year. Thus, since 2009, the number of scientific articles published on this topi...

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Main Authors: Jesús Sanmartín-Matalobos, Pilar Bermejo-Barrera, Manuel Aboal-Somoza, Matilde Fondo, Ana M. García-Deibe, Julio Corredoira-Vázquez, Yeneva Alves-Iglesias
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/12/14/2501
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author Jesús Sanmartín-Matalobos
Pilar Bermejo-Barrera
Manuel Aboal-Somoza
Matilde Fondo
Ana M. García-Deibe
Julio Corredoira-Vázquez
Yeneva Alves-Iglesias
author_facet Jesús Sanmartín-Matalobos
Pilar Bermejo-Barrera
Manuel Aboal-Somoza
Matilde Fondo
Ana M. García-Deibe
Julio Corredoira-Vázquez
Yeneva Alves-Iglesias
author_sort Jesús Sanmartín-Matalobos
collection DOAJ
description Since the discovery of Quantum Dots (QDs) by Alexey I. Ekimov in 1981, the interest of researchers in that particular type of nanomaterials (NMs) with unique optical and electrical properties has been increasing year by year. Thus, since 2009, the number of scientific articles published on this topic has not been less than a thousand a year. The increasing use of QDs due to their biomedical, pharmaceutical, biological, photovoltaics or computing applications, as well as many other high-tech uses such as for displays and solid-state lighting (SSL), has given rise to a considerable number of studies about its potential toxicity. However, there are a really low number of reported studies on the detection and quantification of QDs, and these include ICP–MS and electrochemical analysis, which are the most common quantification techniques employed for this purpose. The knowledge of chemical phenomena occurring on the surface of QDs is crucial for understanding the interactions of QDs with species dissolved in the dispersion medium, while it paves the way for a widespread use of chemosensors to facilitate its detection. Keeping in mind both human health and environmental risks of QDs as well as the scarcity of analytical techniques and methodological approaches for their detection, the adaptation of existing techniques and methods used with other NMs appears necessary. In order to provide a multidisciplinary perspective on QD detection, this review focused on three interrelated key aspects of QDs: properties, surface chemistry and detection.
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spelling doaj.art-c9758f37ace948dda0a0141bd1dca8b02023-12-03T12:03:46ZengMDPI AGNanomaterials2079-49912022-07-011214250110.3390/nano12142501Semiconductor Quantum Dots as Target Analytes: Properties, Surface Chemistry and DetectionJesús Sanmartín-Matalobos0Pilar Bermejo-Barrera1Manuel Aboal-Somoza2Matilde Fondo3Ana M. García-Deibe4Julio Corredoira-Vázquez5Yeneva Alves-Iglesias6Coordination and Supramolecular Chemistry Group (SupraMetal), Department of Inorganic Chemistry, Faculty of Chemistry, Institute of Materials (iMATUS), Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, SpainTrace Element, Speciation and Spectroscopy Group (GETEE), Department of Analytical Chemistry, Nutrition and Bromatology, Faculty of Chemistry, Institute of Materials (iMATUS), Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, SpainTrace Element, Speciation and Spectroscopy Group (GETEE), Department of Analytical Chemistry, Nutrition and Bromatology, Faculty of Chemistry, Institute of Materials (iMATUS), Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, SpainCoordination and Supramolecular Chemistry Group (SupraMetal), Department of Inorganic Chemistry, Faculty of Chemistry, Institute of Materials (iMATUS), Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, SpainCoordination and Supramolecular Chemistry Group (SupraMetal), Department of Inorganic Chemistry, Faculty of Chemistry, Institute of Materials (iMATUS), Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, SpainCoordination and Supramolecular Chemistry Group (SupraMetal), Department of Inorganic Chemistry, Faculty of Chemistry, Institute of Materials (iMATUS), Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, SpainCoordination and Supramolecular Chemistry Group (SupraMetal), Department of Inorganic Chemistry, Faculty of Chemistry, Institute of Materials (iMATUS), Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, SpainSince the discovery of Quantum Dots (QDs) by Alexey I. Ekimov in 1981, the interest of researchers in that particular type of nanomaterials (NMs) with unique optical and electrical properties has been increasing year by year. Thus, since 2009, the number of scientific articles published on this topic has not been less than a thousand a year. The increasing use of QDs due to their biomedical, pharmaceutical, biological, photovoltaics or computing applications, as well as many other high-tech uses such as for displays and solid-state lighting (SSL), has given rise to a considerable number of studies about its potential toxicity. However, there are a really low number of reported studies on the detection and quantification of QDs, and these include ICP–MS and electrochemical analysis, which are the most common quantification techniques employed for this purpose. The knowledge of chemical phenomena occurring on the surface of QDs is crucial for understanding the interactions of QDs with species dissolved in the dispersion medium, while it paves the way for a widespread use of chemosensors to facilitate its detection. Keeping in mind both human health and environmental risks of QDs as well as the scarcity of analytical techniques and methodological approaches for their detection, the adaptation of existing techniques and methods used with other NMs appears necessary. In order to provide a multidisciplinary perspective on QD detection, this review focused on three interrelated key aspects of QDs: properties, surface chemistry and detection.https://www.mdpi.com/2079-4991/12/14/2501QDssizecompositionpropertiessurface chemistrydetection
spellingShingle Jesús Sanmartín-Matalobos
Pilar Bermejo-Barrera
Manuel Aboal-Somoza
Matilde Fondo
Ana M. García-Deibe
Julio Corredoira-Vázquez
Yeneva Alves-Iglesias
Semiconductor Quantum Dots as Target Analytes: Properties, Surface Chemistry and Detection
Nanomaterials
QDs
size
composition
properties
surface chemistry
detection
title Semiconductor Quantum Dots as Target Analytes: Properties, Surface Chemistry and Detection
title_full Semiconductor Quantum Dots as Target Analytes: Properties, Surface Chemistry and Detection
title_fullStr Semiconductor Quantum Dots as Target Analytes: Properties, Surface Chemistry and Detection
title_full_unstemmed Semiconductor Quantum Dots as Target Analytes: Properties, Surface Chemistry and Detection
title_short Semiconductor Quantum Dots as Target Analytes: Properties, Surface Chemistry and Detection
title_sort semiconductor quantum dots as target analytes properties surface chemistry and detection
topic QDs
size
composition
properties
surface chemistry
detection
url https://www.mdpi.com/2079-4991/12/14/2501
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AT pilarbermejobarrera semiconductorquantumdotsastargetanalytespropertiessurfacechemistryanddetection
AT manuelaboalsomoza semiconductorquantumdotsastargetanalytespropertiessurfacechemistryanddetection
AT matildefondo semiconductorquantumdotsastargetanalytespropertiessurfacechemistryanddetection
AT anamgarciadeibe semiconductorquantumdotsastargetanalytespropertiessurfacechemistryanddetection
AT juliocorredoiravazquez semiconductorquantumdotsastargetanalytespropertiessurfacechemistryanddetection
AT yenevaalvesiglesias semiconductorquantumdotsastargetanalytespropertiessurfacechemistryanddetection