2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate
In the title compound, C15H17NOS·H2O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)°. The intramolecular S...O distance [2.737 (3) Å] is shorter than expected and, in terms of hybridization principles, the N—C&...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808029255 |
| _version_ | 1818997795837706240 |
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| author | Dieter Schollmeyer H. Johnson Jeyakumar Samuel Robinson Jebas B. Ravindran Durai Nayagam |
| author_facet | Dieter Schollmeyer H. Johnson Jeyakumar Samuel Robinson Jebas B. Ravindran Durai Nayagam |
| author_sort | Dieter Schollmeyer |
| collection | DOAJ |
| description | In the title compound, C15H17NOS·H2O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)°. The intramolecular S...O distance [2.737 (3) Å] is shorter than expected and, in terms of hybridization principles, the N—C—S angle [114.1 (2)°] is smaller than expected. The crystal structure is stabilized by intermolecular O—H...O and weak C—H...O hydrogen bonds. In addition, weak π–π stacking interactions with a centroid–centroid distance of 3.778 (3) Å are also observed. |
| first_indexed | 2024-12-20T21:51:19Z |
| format | Article |
| id | doaj.art-c97745babcf04e4ebfb07291ae2fc646 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T21:51:19Z |
| publishDate | 2008-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c97745babcf04e4ebfb07291ae2fc6462022-12-21T19:25:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410o1952o195210.1107/S16005368080292552-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrateDieter SchollmeyerH. Johnson JeyakumarSamuel Robinson JebasB. Ravindran Durai NayagamIn the title compound, C15H17NOS·H2O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)°. The intramolecular S...O distance [2.737 (3) Å] is shorter than expected and, in terms of hybridization principles, the N—C—S angle [114.1 (2)°] is smaller than expected. The crystal structure is stabilized by intermolecular O—H...O and weak C—H...O hydrogen bonds. In addition, weak π–π stacking interactions with a centroid–centroid distance of 3.778 (3) Å are also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536808029255 |
| spellingShingle | Dieter Schollmeyer H. Johnson Jeyakumar Samuel Robinson Jebas B. Ravindran Durai Nayagam 2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate Acta Crystallographica Section E |
| title | 2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate |
| title_full | 2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate |
| title_fullStr | 2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate |
| title_full_unstemmed | 2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate |
| title_short | 2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate |
| title_sort | 2 mesitylmethylsulfanyl pyridine n oxide monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808029255 |
| work_keys_str_mv | AT dieterschollmeyer 2mesitylmethylsulfanylpyridinenoxidemonohydrate AT hjohnsonjeyakumar 2mesitylmethylsulfanylpyridinenoxidemonohydrate AT samuelrobinsonjebas 2mesitylmethylsulfanylpyridinenoxidemonohydrate AT bravindrandurainayagam 2mesitylmethylsulfanylpyridinenoxidemonohydrate |