Decomposition of Ruthenium Olefin Metathesis Catalyst
Ruthenium olefin metathesis catalysts are one of the most commonly used class of catalysts. There are multiple reviews on their uses in various branches of chemistry and other sciences but a detailed review of their decomposition is missing, despite a large number of recent and important advances in...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-08-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/10/8/887 |
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| author | Magdalena Jawiczuk Anna Marczyk Bartosz Trzaskowski |
| author_facet | Magdalena Jawiczuk Anna Marczyk Bartosz Trzaskowski |
| author_sort | Magdalena Jawiczuk |
| collection | DOAJ |
| description | Ruthenium olefin metathesis catalysts are one of the most commonly used class of catalysts. There are multiple reviews on their uses in various branches of chemistry and other sciences but a detailed review of their decomposition is missing, despite a large number of recent and important advances in this field. In particular, in the last five years several new mechanism of decomposition, both olefin-driven as well as induced by external agents, have been suggested and used to explain differences in the decomposition rates and the metathesis activities of both standard, N-heterocyclic carbene-based systems and the recently developed cyclic alkyl amino carbene-containing complexes. Here we present a review which explores the last 30 years of the decomposition studied on ruthenium olefin metathesis catalyst driven by both intrinsic features of such catalysts as well as external chemicals. |
| first_indexed | 2024-03-10T17:57:22Z |
| format | Article |
| id | doaj.art-c98715e44acc410bbbaaffb93b3e3ebe |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T17:57:22Z |
| publishDate | 2020-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-c98715e44acc410bbbaaffb93b3e3ebe2023-11-20T09:10:10ZengMDPI AGCatalysts2073-43442020-08-0110888710.3390/catal10080887Decomposition of Ruthenium Olefin Metathesis CatalystMagdalena Jawiczuk0Anna Marczyk1Bartosz Trzaskowski2Centre of New Technologies, University of Warsaw, Banacha 2c, 02-097 Warsaw, PolandCentre of New Technologies, University of Warsaw, Banacha 2c, 02-097 Warsaw, PolandCentre of New Technologies, University of Warsaw, Banacha 2c, 02-097 Warsaw, PolandRuthenium olefin metathesis catalysts are one of the most commonly used class of catalysts. There are multiple reviews on their uses in various branches of chemistry and other sciences but a detailed review of their decomposition is missing, despite a large number of recent and important advances in this field. In particular, in the last five years several new mechanism of decomposition, both olefin-driven as well as induced by external agents, have been suggested and used to explain differences in the decomposition rates and the metathesis activities of both standard, N-heterocyclic carbene-based systems and the recently developed cyclic alkyl amino carbene-containing complexes. Here we present a review which explores the last 30 years of the decomposition studied on ruthenium olefin metathesis catalyst driven by both intrinsic features of such catalysts as well as external chemicals.https://www.mdpi.com/2073-4344/10/8/887decompositionrutheniumolefin metathesiscatalysis |
| spellingShingle | Magdalena Jawiczuk Anna Marczyk Bartosz Trzaskowski Decomposition of Ruthenium Olefin Metathesis Catalyst Catalysts decomposition ruthenium olefin metathesis catalysis |
| title | Decomposition of Ruthenium Olefin Metathesis Catalyst |
| title_full | Decomposition of Ruthenium Olefin Metathesis Catalyst |
| title_fullStr | Decomposition of Ruthenium Olefin Metathesis Catalyst |
| title_full_unstemmed | Decomposition of Ruthenium Olefin Metathesis Catalyst |
| title_short | Decomposition of Ruthenium Olefin Metathesis Catalyst |
| title_sort | decomposition of ruthenium olefin metathesis catalyst |
| topic | decomposition ruthenium olefin metathesis catalysis |
| url | https://www.mdpi.com/2073-4344/10/8/887 |
| work_keys_str_mv | AT magdalenajawiczuk decompositionofrutheniumolefinmetathesiscatalyst AT annamarczyk decompositionofrutheniumolefinmetathesiscatalyst AT bartosztrzaskowski decompositionofrutheniumolefinmetathesiscatalyst |