Synthesis and Crystal Structure of Dimethyl{N-[(2-oxy-1-naphthyl)methylene]leucinato}silicon
The title compound was prepared by reaction of the Schiff base ligand N-(2-hydroxy-1-naphthylidene)leucine with dichlorodimethylsilane in the presence of triethylamine as base. The resulting pentacoordinate silicon complex was characterized by NMR, IR, UV-Vis spectroscopy and melting point. The stru...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-09-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/13/9/1407 |
| _version_ | 1797580699220312064 |
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| author | Uwe Böhme Sabine Fels |
| author_facet | Uwe Böhme Sabine Fels |
| author_sort | Uwe Böhme |
| collection | DOAJ |
| description | The title compound was prepared by reaction of the Schiff base ligand N-(2-hydroxy-1-naphthylidene)leucine with dichlorodimethylsilane in the presence of triethylamine as base. The resulting pentacoordinate silicon complex was characterized by NMR, IR, UV-Vis spectroscopy and melting point. The structure was confirmed by single-crystal X-ray diffraction data. It crystallizes in the monoclinic space group <i>Ic</i> with unit cell dimensions a = 7.2030(6), b = 22.9842(14), c = 10.8946(12) Å, β = 96.141(7)°, V = 1793.3(3) Å<sup>3</sup>, Z = 4. |
| first_indexed | 2024-03-10T22:53:36Z |
| format | Article |
| id | doaj.art-c99e70a9a1bb4709a4342387b150ac64 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-10T22:53:36Z |
| publishDate | 2023-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-c99e70a9a1bb4709a4342387b150ac642023-11-19T10:10:14ZengMDPI AGCrystals2073-43522023-09-01139140710.3390/cryst13091407Synthesis and Crystal Structure of Dimethyl{N-[(2-oxy-1-naphthyl)methylene]leucinato}siliconUwe Böhme0Sabine Fels1Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, GermanyInstitut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, GermanyThe title compound was prepared by reaction of the Schiff base ligand N-(2-hydroxy-1-naphthylidene)leucine with dichlorodimethylsilane in the presence of triethylamine as base. The resulting pentacoordinate silicon complex was characterized by NMR, IR, UV-Vis spectroscopy and melting point. The structure was confirmed by single-crystal X-ray diffraction data. It crystallizes in the monoclinic space group <i>Ic</i> with unit cell dimensions a = 7.2030(6), b = 22.9842(14), c = 10.8946(12) Å, β = 96.141(7)°, V = 1793.3(3) Å<sup>3</sup>, Z = 4.https://www.mdpi.com/2073-4352/13/9/1407organosiliconsilicon complexSchiff base ligandcrystal structure |
| spellingShingle | Uwe Böhme Sabine Fels Synthesis and Crystal Structure of Dimethyl{N-[(2-oxy-1-naphthyl)methylene]leucinato}silicon Crystals organosilicon silicon complex Schiff base ligand crystal structure |
| title | Synthesis and Crystal Structure of Dimethyl{N-[(2-oxy-1-naphthyl)methylene]leucinato}silicon |
| title_full | Synthesis and Crystal Structure of Dimethyl{N-[(2-oxy-1-naphthyl)methylene]leucinato}silicon |
| title_fullStr | Synthesis and Crystal Structure of Dimethyl{N-[(2-oxy-1-naphthyl)methylene]leucinato}silicon |
| title_full_unstemmed | Synthesis and Crystal Structure of Dimethyl{N-[(2-oxy-1-naphthyl)methylene]leucinato}silicon |
| title_short | Synthesis and Crystal Structure of Dimethyl{N-[(2-oxy-1-naphthyl)methylene]leucinato}silicon |
| title_sort | synthesis and crystal structure of dimethyl n 2 oxy 1 naphthyl methylene leucinato silicon |
| topic | organosilicon silicon complex Schiff base ligand crystal structure |
| url | https://www.mdpi.com/2073-4352/13/9/1407 |
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