Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based Thereon

Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based Thereon

The crystal structure of 3,3′,5,5′-tetrabromo-4,4′-bipyridine (BrBipy, <b>1</b>) was determined, and the features of non-covalent interactions in solid state were investigated by theoretical methods. Using BrBipy as a linker ligand, 1D coordination polymer {[Co(BrBipy)(NO<sub>3<...

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Bibliographic Details
Main Authors: Ilyas F. Sakhapov, Almaz A. Zagidullin, Alexey B. Dobrynin, Igor A. Litvinov, Dmitry G. Yakhvarov, Mikhail A. Bondarenko, Alexander S. Novikov, Vladimir P. Fedin, Sergey A. Adonin
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Crystals
Subjects:
non-covalent interactions
coordination polymers
halogen bonding
complexes
cobalt
Online Access:https://www.mdpi.com/2073-4352/13/4/704
Description
Summary:The crystal structure of 3,3′,5,5′-tetrabromo-4,4′-bipyridine (BrBipy, <b>1</b>) was determined, and the features of non-covalent interactions in solid state were investigated by theoretical methods. Using BrBipy as a linker ligand, 1D coordination polymer {[Co(BrBipy)(NO<sub>3</sub>)<sub>2</sub>(CH<sub>3</sub>OH)<sub>2</sub>]} (<b>2</b>) was obtained and characterized.
ISSN:2073-4352

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