Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based Thereon

The crystal structure of 3,3′,5,5′-tetrabromo-4,4′-bipyridine (BrBipy, <b>1</b>) was determined, and the features of non-covalent interactions in solid state were investigated by theoretical methods. Using BrBipy as a linker ligand, 1D coordination polymer {[Co(BrBipy)(NO<sub>3<...

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Main Authors: Ilyas F. Sakhapov, Almaz A. Zagidullin, Alexey B. Dobrynin, Igor A. Litvinov, Dmitry G. Yakhvarov, Mikhail A. Bondarenko, Alexander S. Novikov, Vladimir P. Fedin, Sergey A. Adonin
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/13/4/704
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author Ilyas F. Sakhapov
Almaz A. Zagidullin
Alexey B. Dobrynin
Igor A. Litvinov
Dmitry G. Yakhvarov
Mikhail A. Bondarenko
Alexander S. Novikov
Vladimir P. Fedin
Sergey A. Adonin
author_facet Ilyas F. Sakhapov
Almaz A. Zagidullin
Alexey B. Dobrynin
Igor A. Litvinov
Dmitry G. Yakhvarov
Mikhail A. Bondarenko
Alexander S. Novikov
Vladimir P. Fedin
Sergey A. Adonin
author_sort Ilyas F. Sakhapov
collection DOAJ
description The crystal structure of 3,3′,5,5′-tetrabromo-4,4′-bipyridine (BrBipy, <b>1</b>) was determined, and the features of non-covalent interactions in solid state were investigated by theoretical methods. Using BrBipy as a linker ligand, 1D coordination polymer {[Co(BrBipy)(NO<sub>3</sub>)<sub>2</sub>(CH<sub>3</sub>OH)<sub>2</sub>]} (<b>2</b>) was obtained and characterized.
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spelling doaj.art-c9a7fa513bf2441a8a2d0f0e3ff83fc82023-11-17T18:52:18ZengMDPI AGCrystals2073-43522023-04-0113470410.3390/cryst13040704Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based ThereonIlyas F. Sakhapov0Almaz A. Zagidullin1Alexey B. Dobrynin2Igor A. Litvinov3Dmitry G. Yakhvarov4Mikhail A. Bondarenko5Alexander S. Novikov6Vladimir P. Fedin7Sergey A. Adonin8South Ural State University, 454080 Chelyabinsk, RussiaArbuzov Institute of Organic and Physical Chemistry RAS, 420088 Kazan, RussiaArbuzov Institute of Organic and Physical Chemistry RAS, 420088 Kazan, RussiaArbuzov Institute of Organic and Physical Chemistry RAS, 420088 Kazan, RussiaKazan Federal University, 420008 Kazan, RussiaSouth Ural State University, 454080 Chelyabinsk, RussiaInstitute of Chemistry, Saint Petersburg University, 198504 Saint Petersburg, RussiaNikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, RussiaSouth Ural State University, 454080 Chelyabinsk, RussiaThe crystal structure of 3,3′,5,5′-tetrabromo-4,4′-bipyridine (BrBipy, <b>1</b>) was determined, and the features of non-covalent interactions in solid state were investigated by theoretical methods. Using BrBipy as a linker ligand, 1D coordination polymer {[Co(BrBipy)(NO<sub>3</sub>)<sub>2</sub>(CH<sub>3</sub>OH)<sub>2</sub>]} (<b>2</b>) was obtained and characterized.https://www.mdpi.com/2073-4352/13/4/704non-covalent interactionscoordination polymershalogen bondingcomplexescobalt
spellingShingle Ilyas F. Sakhapov
Almaz A. Zagidullin
Alexey B. Dobrynin
Igor A. Litvinov
Dmitry G. Yakhvarov
Mikhail A. Bondarenko
Alexander S. Novikov
Vladimir P. Fedin
Sergey A. Adonin
Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based Thereon
Crystals
non-covalent interactions
coordination polymers
halogen bonding
complexes
cobalt
title Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based Thereon
title_full Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based Thereon
title_fullStr Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based Thereon
title_full_unstemmed Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based Thereon
title_short Crystal Structures of 3,3′,5,5′-Tetrabromo-4,4′-bipyridine and Co(II) Coordination Polymer Based Thereon
title_sort crystal structures of 3 3 5 5 tetrabromo 4 4 bipyridine and co ii coordination polymer based thereon
topic non-covalent interactions
coordination polymers
halogen bonding
complexes
cobalt
url https://www.mdpi.com/2073-4352/13/4/704
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