Comparison the Physico-Chemical Model of Ferrosilicon Smelting Process with Results Observations of the Process under the Industrial Conditions

Based on the minimum Gibbs Free Enthalpy algorithm (FEM), model of the ferrosilicon smelting process has been presented. It is a system of two closed isothermal reactors: an upper one with a lower temperature T1, and a lower one with a higher temperature T2. Between the reactors and the environment...

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Main Authors: Machulec B., Bialik W.
Format: Article
Language:English
Published: Polish Academy of Sciences 2016-03-01
Series:Archives of Metallurgy and Materials
Subjects:
Online Access:http://www.degruyter.com/view/j/amm.2016.61.issue-1/amm-2016-0050/amm-2016-0050.xml?format=INT
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author Machulec B.
Bialik W.
author_facet Machulec B.
Bialik W.
author_sort Machulec B.
collection DOAJ
description Based on the minimum Gibbs Free Enthalpy algorithm (FEM), model of the ferrosilicon smelting process has been presented. It is a system of two closed isothermal reactors: an upper one with a lower temperature T1, and a lower one with a higher temperature T2. Between the reactors and the environment as well as between the reactors inside the system, a periodical exchange of mass occurs at the moments when the equilibrium state is reached. The condensed products of chemical reactions move from the top to the bottom, and the gas phase components move in the opposite direction. It can be assumed that in the model, the Reactor 1 corresponds to the charge zone of submerged arc furnace where heat is released as a result of resistive heating, and the Reactor 2 corresponds to the zones of the furnace where heat is produced by electric arc. Using the model, a series of calculations was performed for the Fe-Si-O-C system and was determined the influence of temperatures T1, T2 on the process. The calculation results show a good agreement model with the real ferrosilicon process. It allows for the determination of the effects of temperature conditions in charge zones and arc zones of the ferrosilicon furnace on the carbothermic silica reduction process. This allows for an explanation of many characteristic states in the ferrosilicon smelting process.
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spelling doaj.art-c9ffe36ec0be4651ad0e5a3350c8f37b2022-12-21T22:40:51ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092016-03-0161126527010.1515/amm-2016-0050amm-2016-0050Comparison the Physico-Chemical Model of Ferrosilicon Smelting Process with Results Observations of the Process under the Industrial ConditionsMachulec B.0Bialik W.1Silesian University of Technology, Department of Engineering Production(1), 8 Str. Krasińskiego, 40-019 Katowice, PolandSilesian University of Technology, Institute of Metals Technology, 8 Str. Krasińskiego, 40-019 Katowice, PolandBased on the minimum Gibbs Free Enthalpy algorithm (FEM), model of the ferrosilicon smelting process has been presented. It is a system of two closed isothermal reactors: an upper one with a lower temperature T1, and a lower one with a higher temperature T2. Between the reactors and the environment as well as between the reactors inside the system, a periodical exchange of mass occurs at the moments when the equilibrium state is reached. The condensed products of chemical reactions move from the top to the bottom, and the gas phase components move in the opposite direction. It can be assumed that in the model, the Reactor 1 corresponds to the charge zone of submerged arc furnace where heat is released as a result of resistive heating, and the Reactor 2 corresponds to the zones of the furnace where heat is produced by electric arc. Using the model, a series of calculations was performed for the Fe-Si-O-C system and was determined the influence of temperatures T1, T2 on the process. The calculation results show a good agreement model with the real ferrosilicon process. It allows for the determination of the effects of temperature conditions in charge zones and arc zones of the ferrosilicon furnace on the carbothermic silica reduction process. This allows for an explanation of many characteristic states in the ferrosilicon smelting process.http://www.degruyter.com/view/j/amm.2016.61.issue-1/amm-2016-0050/amm-2016-0050.xml?format=INTferrosiliconmodelequilibriumFEMsubmerged-arc furnace
spellingShingle Machulec B.
Bialik W.
Comparison the Physico-Chemical Model of Ferrosilicon Smelting Process with Results Observations of the Process under the Industrial Conditions
Archives of Metallurgy and Materials
ferrosilicon
model
equilibrium
FEM
submerged-arc furnace
title Comparison the Physico-Chemical Model of Ferrosilicon Smelting Process with Results Observations of the Process under the Industrial Conditions
title_full Comparison the Physico-Chemical Model of Ferrosilicon Smelting Process with Results Observations of the Process under the Industrial Conditions
title_fullStr Comparison the Physico-Chemical Model of Ferrosilicon Smelting Process with Results Observations of the Process under the Industrial Conditions
title_full_unstemmed Comparison the Physico-Chemical Model of Ferrosilicon Smelting Process with Results Observations of the Process under the Industrial Conditions
title_short Comparison the Physico-Chemical Model of Ferrosilicon Smelting Process with Results Observations of the Process under the Industrial Conditions
title_sort comparison the physico chemical model of ferrosilicon smelting process with results observations of the process under the industrial conditions
topic ferrosilicon
model
equilibrium
FEM
submerged-arc furnace
url http://www.degruyter.com/view/j/amm.2016.61.issue-1/amm-2016-0050/amm-2016-0050.xml?format=INT
work_keys_str_mv AT machulecb comparisonthephysicochemicalmodelofferrosiliconsmeltingprocesswithresultsobservationsoftheprocessundertheindustrialconditions
AT bialikw comparisonthephysicochemicalmodelofferrosiliconsmeltingprocesswithresultsobservationsoftheprocessundertheindustrialconditions