Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics
Temperature measurements of dielectric permittivity are performed for nonstoichiometric ferroelectric lead germanate Pb_(4.95)Ge_3O_(11) and multiferroic solid solution [N(C_2H_5)_4]_2CoClBr_3. Unlike the heat capacity data, the analysis of the dielectric permittivity of ferroics is usually performe...
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Format: | Article |
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Institute for Condensed Matter Physics
2023-12-01
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Series: | Condensed Matter Physics |
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Online Access: | https://doi.org/10.5488/CMP.26.43604 |
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author | I. S. Girnyk B. I. Horon V. B. Kapustianyk O. S. Kushnir R. Y. Shopa |
author_facet | I. S. Girnyk B. I. Horon V. B. Kapustianyk O. S. Kushnir R. Y. Shopa |
author_sort | I. S. Girnyk |
collection | DOAJ |
description | Temperature measurements of dielectric permittivity are performed for nonstoichiometric ferroelectric lead germanate Pb_(4.95)Ge_3O_(11) and multiferroic solid solution [N(C_2H_5)_4]_2CoClBr_3. Unlike the heat capacity data, the analysis of the dielectric permittivity of ferroics is usually performed at the assumption that the dielectric `background' is negligible compared with its critical part. In this work we quantitatively interpret the dielectric properties of the single crystals mentioned above and the appropriate literature data for multiferroic Sr2IrO4 crystals, using generalized Curie-Weiss formulas that combine corrections due to a nonlinear temperature-dependent dielectric background, a modified critical index of electric susceptibility, and a diffuse character of phase transition. We argue that taking account of the temperature dependent dielectric background can improve notably the quantitative analysis of PTs for a number of classes of the ferroic materials. |
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institution | Directory Open Access Journal |
issn | 1607-324X 2224-9079 |
language | English |
last_indexed | 2024-03-08T18:25:04Z |
publishDate | 2023-12-01 |
publisher | Institute for Condensed Matter Physics |
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spelling | doaj.art-ca23fb6c5ab6445789bb9c522c4dd6802023-12-30T14:44:34ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2224-90792023-12-012644360410.5488/CMP.26.43604Nonlinear background corrections to dielectric permittivity of ferroics and multiferroicsI. S. GirnykB. I. HoronV. B. KapustianykO. S. KushnirR. Y. ShopaTemperature measurements of dielectric permittivity are performed for nonstoichiometric ferroelectric lead germanate Pb_(4.95)Ge_3O_(11) and multiferroic solid solution [N(C_2H_5)_4]_2CoClBr_3. Unlike the heat capacity data, the analysis of the dielectric permittivity of ferroics is usually performed at the assumption that the dielectric `background' is negligible compared with its critical part. In this work we quantitatively interpret the dielectric properties of the single crystals mentioned above and the appropriate literature data for multiferroic Sr2IrO4 crystals, using generalized Curie-Weiss formulas that combine corrections due to a nonlinear temperature-dependent dielectric background, a modified critical index of electric susceptibility, and a diffuse character of phase transition. We argue that taking account of the temperature dependent dielectric background can improve notably the quantitative analysis of PTs for a number of classes of the ferroic materials.https://doi.org/10.5488/CMP.26.43604ferroelectricsphase transitionsdiffuse phase transitionsdielectric permittivitycritical behaviorlead germanate |
spellingShingle | I. S. Girnyk B. I. Horon V. B. Kapustianyk O. S. Kushnir R. Y. Shopa Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics Condensed Matter Physics ferroelectrics phase transitions diffuse phase transitions dielectric permittivity critical behavior lead germanate |
title | Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics |
title_full | Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics |
title_fullStr | Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics |
title_full_unstemmed | Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics |
title_short | Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics |
title_sort | nonlinear background corrections to dielectric permittivity of ferroics and multiferroics |
topic | ferroelectrics phase transitions diffuse phase transitions dielectric permittivity critical behavior lead germanate |
url | https://doi.org/10.5488/CMP.26.43604 |
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