Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics

Temperature measurements of dielectric permittivity are performed for nonstoichiometric ferroelectric lead germanate Pb_(4.95)Ge_3O_(11) and multiferroic solid solution [N(C_2H_5)_4]_2CoClBr_3. Unlike the heat capacity data, the analysis of the dielectric permittivity of ferroics is usually performe...

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Main Authors: I. S. Girnyk, B. I. Horon, V. B. Kapustianyk, O. S. Kushnir, R. Y. Shopa
Format: Article
Language:English
Published: Institute for Condensed Matter Physics 2023-12-01
Series:Condensed Matter Physics
Subjects:
Online Access:https://doi.org/10.5488/CMP.26.43604
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author I. S. Girnyk
B. I. Horon
V. B. Kapustianyk
O. S. Kushnir
R. Y. Shopa
author_facet I. S. Girnyk
B. I. Horon
V. B. Kapustianyk
O. S. Kushnir
R. Y. Shopa
author_sort I. S. Girnyk
collection DOAJ
description Temperature measurements of dielectric permittivity are performed for nonstoichiometric ferroelectric lead germanate Pb_(4.95)Ge_3O_(11) and multiferroic solid solution [N(C_2H_5)_4]_2CoClBr_3. Unlike the heat capacity data, the analysis of the dielectric permittivity of ferroics is usually performed at the assumption that the dielectric `background' is negligible compared with its critical part. In this work we quantitatively interpret the dielectric properties of the single crystals mentioned above and the appropriate literature data for multiferroic Sr2IrO4 crystals, using generalized Curie-Weiss formulas that combine corrections due to a nonlinear temperature-dependent dielectric background, a modified critical index of electric susceptibility, and a diffuse character of phase transition. We argue that taking account of the temperature dependent dielectric background can improve notably the quantitative analysis of PTs for a number of classes of the ferroic materials.
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spelling doaj.art-ca23fb6c5ab6445789bb9c522c4dd6802023-12-30T14:44:34ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2224-90792023-12-012644360410.5488/CMP.26.43604Nonlinear background corrections to dielectric permittivity of ferroics and multiferroicsI. S. GirnykB. I. HoronV. B. KapustianykO. S. KushnirR. Y. ShopaTemperature measurements of dielectric permittivity are performed for nonstoichiometric ferroelectric lead germanate Pb_(4.95)Ge_3O_(11) and multiferroic solid solution [N(C_2H_5)_4]_2CoClBr_3. Unlike the heat capacity data, the analysis of the dielectric permittivity of ferroics is usually performed at the assumption that the dielectric `background' is negligible compared with its critical part. In this work we quantitatively interpret the dielectric properties of the single crystals mentioned above and the appropriate literature data for multiferroic Sr2IrO4 crystals, using generalized Curie-Weiss formulas that combine corrections due to a nonlinear temperature-dependent dielectric background, a modified critical index of electric susceptibility, and a diffuse character of phase transition. We argue that taking account of the temperature dependent dielectric background can improve notably the quantitative analysis of PTs for a number of classes of the ferroic materials.https://doi.org/10.5488/CMP.26.43604ferroelectricsphase transitionsdiffuse phase transitionsdielectric permittivitycritical behaviorlead germanate
spellingShingle I. S. Girnyk
B. I. Horon
V. B. Kapustianyk
O. S. Kushnir
R. Y. Shopa
Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics
Condensed Matter Physics
ferroelectrics
phase transitions
diffuse phase transitions
dielectric permittivity
critical behavior
lead germanate
title Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics
title_full Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics
title_fullStr Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics
title_full_unstemmed Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics
title_short Nonlinear background corrections to dielectric permittivity of ferroics and multiferroics
title_sort nonlinear background corrections to dielectric permittivity of ferroics and multiferroics
topic ferroelectrics
phase transitions
diffuse phase transitions
dielectric permittivity
critical behavior
lead germanate
url https://doi.org/10.5488/CMP.26.43604
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