Use of Vanadium Complexes Bearing Naphthalene-Bridged Nitrogen-Sulfonate Ligands as Catalysts for Copolymerization of Ethylene and Propylene

Use of Vanadium Complexes Bearing Naphthalene-Bridged Nitrogen-Sulfonate Ligands as Catalysts for Copolymerization of Ethylene and Propylene

Vanadium complexes bearing naphthalene-bridged nitrogen-sulfonate ligand ([ê2(N,O)-8-(PhN)-1-naphthalenesulfonato]VOCl (1a) and [ê2(N,O)-8-(PhN)-1-naphthalenesulfonato]VCl2 (1b)) were synthesized. Activated by ethylaluminium sesquichloride (EASC) and in the presence of ethyl trichloroacetate (ETCA)...

Full description

Bibliographic Details
Main Authors:	Xiufeng Hao, Chundi Zhang, Lin Li, Hexin Zhang, Yanming Hu, Daifeng Hao, Xuequan Zhang
Format:	Article
Language:	English
Published:	MDPI AG 2017-07-01
Series:	Polymers
Subjects:	vanadium catalyst ethylene/propylene copolymerization polyolefin
Online Access:	https://www.mdpi.com/2073-4360/9/8/325

Similar Items

Influence of reaction conditions on catalytic properties of rac-Et(2-MeInd)2ZrMe2/(2,6-tBu2PhO-)AliBu2 in ethylene-propylene copolymerization
by: Evgeny Faingol'd, et al.
Published: (2023-11-01)

Synthesis and Properties of Ethylene/propylene and Ethylene/propylene/5-ethylidene-2-norbornene Copolymers Obtained on <i>Rac</i>-Et(2-MeInd)<sub>2</sub>ZrMe<sub>2</sub>/Isobutylaluminium Aryloxide Catalytic Systems
by: Evgeny E. Faingol’d, et al.
Published: (2023-01-01)

Advances in carbon dioxide and propylene oxide copolymerization to form poly(propylene carbonate) over heterogeneous catalysts
by: Ruth Mbabazi, et al.
Published: (2022-01-01)

A New Dinuclear Cobalt Complex for Copolymerization of CO<sub>2</sub> and Propylene Oxide: High Activity and Selectivity
by: Wen-Zhen Wang, et al.
Published: (2020-09-01)

Promotion of B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> as Ligand for Titanium (or Vanadium) Catalysts in the Copolymerization of Ethylene and 1-Hexene: A Computational Study
by: Shuyuan Yu, et al.
Published: (2023-05-01)

Crystallization, morphology, and thermal behaviour of ethylene/propylene copolymers /
by: Greco, Roberto

Synthesis of Degradable Polyolefins Bearing Disulfide Units via Metathesis Copolymerization
by: Yu Xia, et al.
Published: (2023-07-01)

Copolymerization of Ethylene with Alpha-Olefins over Supported Titanium–Magnesium Catalysts Containing Titanium Compounds in Different Oxidation and Coordination States
by: Tatiana B. Mikenas, et al.
Published: (2023-04-01)

Evaluation of general purpose ethylene-propylene-diene rubber (EPDM)
by: 8096 British Standards Institution, et al.

"Vulcanization kinetics and properties of ethylene-propylene-diene monomer /ethylene-propylene rubber blends "
by: ZHANG Wei-jian1, LIU Xu2, GAO Zhen-liang1, LIU Li1, ZHANG Bao-gang1
Published: (2023-10-01)

Ethylene propylene rubber compounds
by: 8096 British Standards Institution

Copolymerization of Ethylene with Functionalized 1,1-Disubstituted Olefins Using a Fluorenylamido-Ligated Titanium Catalyst
by: Oluwaseyi Aderemi Ajala, et al.
Published: (2024-01-01)

Methods of test for non-oil extended raw general purpose ethylene-propylene-diene rubbers (EPDM)
by: 8096 British Standards Institution

Hard ethylene propylene rubber insulation of electric cables
by: 8096 British Standards Institution

Copolymerization of Ethylene and Methyl Acrylate by Dibenzocycloheptyl-Substituted Aryliminopyridyl Ni(II) Catalysts
by: Ilaria D’Auria, et al.
Published: (2022-10-01)

Recent Advances in Synthesis of Non-Alternating Polyketone Generated by Copolymerization of Carbon Monoxide and Ethylene
by: Xieyi Xiao, et al.
Published: (2024-01-01)

The study of the methanol conversion to ethylene and propylene using small pore size zeolites / [mikrofilem]
by: 362921 Vera-Castaneda, Ernesto

Recent Advancements in Mechanistic Studies of Palladium- and Nickel-Catalyzed Ethylene Copolymerization with Polar Monomers
by: Zhihui Song, et al.
Published: (2023-11-01)

Stabilization Activity of Kelp Extract in Ethylene–Propylene Rubber as Safe Packaging Material
by: Traian Zaharescu
Published: (2023-02-01)

High-Temperature Cracking of Pentene to Ethylene and Propylene over H-ZSM-5 Zeolites: Effect of Reaction Conditions and Mechanistic Insights
by: Yueyang Han, et al.
Published: (2022-12-01)

Effect of processing additives on the properties of resins based on ternary ethylene-propylene rubber
by: D. V. Sitnikova, et al.
Published: (2012-04-01)

Effects of molecular weight of SEBS triblock copolymer on the morphology, impact strength, and rheological property of syndiotactic polystyrene/ethylene-propylene rubber blends /
by: 450663 Hong, B. K., et al.

Thermal Degradation Kinetics Analysis of Ethylene-Propylene Copolymer and EP-1-Hexene Terpolymer
by: Hassam Mazhar, et al.
Published: (2022-02-01)

Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review
by: Marzena Białek, et al.
Published: (2021-12-01)

Homogeneous Group IVB Catalysts of New Generations for Synthesis of Ethylene-Propylene-Diene Rubbers: A Mini-Review
by: Natalia M. Bravaya, et al.
Published: (2022-06-01)

Hybrid Copolymerization of Ethylene Oxide and <i>tert</i>-Butyl Methacrylate with Organocatalyst
by: Wenhao Xiao, et al.
Published: (2021-07-01)

Flow visualization and phase morphology development in blends of nitrile and ethylene propylene rubber in an internal mixer /
by: 221206 Setua, D. K., et al.

Effect of SILPs on the Vulcanization and Properties of Ethylene–Propylene–Diene Elastomer
by: Anna Sowińska, et al.
Published: (2020-05-01)

Polymerization of Ethylene Catalyzed by Vanadium(III) Complexes
by: Hamdi Ali Elagab
Published: (2017-07-01)

Kinetic and Thermal Study of Ethylene and Propylene Homo Polymerization Catalyzed by <i>ansa</i>-Zirconocene Activated with Alkylaluminum/Borate: Effects of Alkylaluminum on Polymerization Kinetics and Polymer Structure
by: Amjad Ali, et al.
Published: (2021-01-01)

Efficient Propylene/Ethylene Separation in Highly Porous Metal–Organic Frameworks
by: Xiao-Min Liu, et al.
Published: (2022-12-01)

Ethylene Copolymerization with Linear and End-Cyclized Olefins via a Metallocene Catalyst: Polymerization Behavior and Thermal Properties of Copolymers
by: Changjiang Wu, et al.
Published: (2023-11-01)

Tungsten Oxide-Modified SSZ-13 Zeolite as an Efficient Catalyst for Ethylene-To-Propylene Reaction
by: Mansurbek Urol ugli Abdullaev, et al.
Published: (2021-04-01)

"Determination of trace amount of arsine and phosphine in ethylene and propylene"
by: HUO Da, SHI De-jun, CHEN Fei, WANG Chun-yan, MA Chen-fei, ZHENG Fang
Published: (2024-03-01)

Significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano‐SiO2 particles
by: Chunyu Xu, et al.
Published: (2021-06-01)

Living Chain-Walking (Co)Polymerization of Propylene and 1-Decene by Nickel <i>α</i>-Diimine Catalysts
by: Pei Li, et al.
Published: (2020-08-01)

Influence of compatibilizing agents on rate of mixing and phase morphology development in blends of nitrile and ethylene propylene rubber in an internal mixer : a flow visualization study /
by: 221206 Setua, D. K., et al.

Study on Thermal-Oxidative Aging Properties of Ethylene-Propylene-Diene Monomer Composites Filled with Silica and Carbon Nanotubes
by: Xiaoming Zhang, et al.
Published: (2022-03-01)

Detailed microstructure analysis through monomeric insertion modes of poly(propylene-co-norbornene) copolymers and poly(propylene-co-ethylene-co-norbornene) terpolymers with low norbornene contents
by: Sergio Fernández-Delgado, et al.
Published: (2023-07-01)

A DFT Study of the Copolymerization of Methyl Vinyl Sulfone and Ethylene Catalyzed by Phosphine–Sulfonate and α-Diimine Palladium Complexes
by: Ling Zhu, et al.
Published: (2023-06-01)