Ultrasonic Cavitation Erosion Behavior of CoCr<sub>x</sub>FeMnNi High-Entropy Alloy Coatings Prepared by Plasma Cladding

CoCr<sub>x</sub>FeMnNi (x represents the atomic percentage of Cr element, x = 20, 25, 30, and 35, denoted as Cr20, Cr25, Cr30, and Cr35 alloys) high-entropy alloy (HEA) coatings were cladded by plasma arc on the surface of 0Cr13Ni5Mo steel. The effects of Cr elements on the cavitation er...

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Main Authors: Kaige Zhang, Danqing Yin, Bin Wang, Maochang Li, Xiao Xiao, Ning Ma, Keke Zhang
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/13/3/515
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author Kaige Zhang
Danqing Yin
Bin Wang
Maochang Li
Xiao Xiao
Ning Ma
Keke Zhang
author_facet Kaige Zhang
Danqing Yin
Bin Wang
Maochang Li
Xiao Xiao
Ning Ma
Keke Zhang
author_sort Kaige Zhang
collection DOAJ
description CoCr<sub>x</sub>FeMnNi (x represents the atomic percentage of Cr element, x = 20, 25, 30, and 35, denoted as Cr20, Cr25, Cr30, and Cr35 alloys) high-entropy alloy (HEA) coatings were cladded by plasma arc on the surface of 0Cr13Ni5Mo steel. The effects of Cr elements on the cavitation erosion mechanisms were studied by comparing the differences of microstructure, microhardness, cavitation erosion volume loss (CVL), cavitation erosion volume loss rate (CER), and eroded surface morphologies between the coatings. As the Cr content increased, the microhardness of the coatings increased continuously, and the microstructure transformed into fine dendrites. The microhardnesses of Cr20, Cr25, Cr30, and Cr35 were 223.9 HV, 250.5 HV, 265.2 HV, and 333.7 HV, respectively. With structural change, the slip pattern shifted from uniform distribution to distribution along the grain boundary, increasing slip resistance. Additionally, strain hardening capacity increased with reduced stacking fault energy (SFE). The resistance to cavitation erosion (CR) of the HEA increased with the increase in Cr content. The CVL of 20 h cavitation erosion of Cr35 coating was only 26.84% of that of 0Cr13Ni5Mo steel, and the peak CER was only 28.75% of that of 0Cr13Ni5Mo steel. The fracture damage mechanisms of the four HEA coatings were an obvious lamellar structure and fibrous fracture.
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spelling doaj.art-ca31c7f799de4419a1ea74a3833e0c002023-11-17T12:38:51ZengMDPI AGMetals2075-47012023-03-0113351510.3390/met13030515Ultrasonic Cavitation Erosion Behavior of CoCr<sub>x</sub>FeMnNi High-Entropy Alloy Coatings Prepared by Plasma CladdingKaige Zhang0Danqing Yin1Bin Wang2Maochang Li3Xiao Xiao4Ning Ma5Keke Zhang6School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, ChinaSchool of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, ChinaSchool of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, ChinaSchool of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, ChinaSchool of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, ChinaSchool of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, ChinaSchool of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, ChinaCoCr<sub>x</sub>FeMnNi (x represents the atomic percentage of Cr element, x = 20, 25, 30, and 35, denoted as Cr20, Cr25, Cr30, and Cr35 alloys) high-entropy alloy (HEA) coatings were cladded by plasma arc on the surface of 0Cr13Ni5Mo steel. The effects of Cr elements on the cavitation erosion mechanisms were studied by comparing the differences of microstructure, microhardness, cavitation erosion volume loss (CVL), cavitation erosion volume loss rate (CER), and eroded surface morphologies between the coatings. As the Cr content increased, the microhardness of the coatings increased continuously, and the microstructure transformed into fine dendrites. The microhardnesses of Cr20, Cr25, Cr30, and Cr35 were 223.9 HV, 250.5 HV, 265.2 HV, and 333.7 HV, respectively. With structural change, the slip pattern shifted from uniform distribution to distribution along the grain boundary, increasing slip resistance. Additionally, strain hardening capacity increased with reduced stacking fault energy (SFE). The resistance to cavitation erosion (CR) of the HEA increased with the increase in Cr content. The CVL of 20 h cavitation erosion of Cr35 coating was only 26.84% of that of 0Cr13Ni5Mo steel, and the peak CER was only 28.75% of that of 0Cr13Ni5Mo steel. The fracture damage mechanisms of the four HEA coatings were an obvious lamellar structure and fibrous fracture.https://www.mdpi.com/2075-4701/13/3/515high-entropic alloysplasma claddingcavitationcorrosionstacking fault energy
spellingShingle Kaige Zhang
Danqing Yin
Bin Wang
Maochang Li
Xiao Xiao
Ning Ma
Keke Zhang
Ultrasonic Cavitation Erosion Behavior of CoCr<sub>x</sub>FeMnNi High-Entropy Alloy Coatings Prepared by Plasma Cladding
Metals
high-entropic alloys
plasma cladding
cavitation
corrosion
stacking fault energy
title Ultrasonic Cavitation Erosion Behavior of CoCr<sub>x</sub>FeMnNi High-Entropy Alloy Coatings Prepared by Plasma Cladding
title_full Ultrasonic Cavitation Erosion Behavior of CoCr<sub>x</sub>FeMnNi High-Entropy Alloy Coatings Prepared by Plasma Cladding
title_fullStr Ultrasonic Cavitation Erosion Behavior of CoCr<sub>x</sub>FeMnNi High-Entropy Alloy Coatings Prepared by Plasma Cladding
title_full_unstemmed Ultrasonic Cavitation Erosion Behavior of CoCr<sub>x</sub>FeMnNi High-Entropy Alloy Coatings Prepared by Plasma Cladding
title_short Ultrasonic Cavitation Erosion Behavior of CoCr<sub>x</sub>FeMnNi High-Entropy Alloy Coatings Prepared by Plasma Cladding
title_sort ultrasonic cavitation erosion behavior of cocr sub x sub femnni high entropy alloy coatings prepared by plasma cladding
topic high-entropic alloys
plasma cladding
cavitation
corrosion
stacking fault energy
url https://www.mdpi.com/2075-4701/13/3/515
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