Can methane pyrolysis based hydrogen production lead to the decarbonisation of iron and steel industry?

Decarbonisation of the iron and steel industry would require the use of innovative low-carbon production technologies. Use of 100% hydrogen in a shaft furnace (SF) to reduce iron ore has the potential to reduce emissions from iron and steel production significantly. In this work, results from the te...

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Main Authors: Abhinav Bhaskar, Mohsen Assadi, Homam Nikpey Somehsaraei
Format: Article
Language:English
Published: Elsevier 2021-06-01
Series:Energy Conversion and Management: X
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590174521000040
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author Abhinav Bhaskar
Mohsen Assadi
Homam Nikpey Somehsaraei
author_facet Abhinav Bhaskar
Mohsen Assadi
Homam Nikpey Somehsaraei
author_sort Abhinav Bhaskar
collection DOAJ
description Decarbonisation of the iron and steel industry would require the use of innovative low-carbon production technologies. Use of 100% hydrogen in a shaft furnace (SF) to reduce iron ore has the potential to reduce emissions from iron and steel production significantly. In this work, results from the techno-economic assessment of a H2-SF connected to an electric arc furnace(EAF) for steel production are presented under two scenarios. In the first scenario H2 is produced from molten metal methane pyrolysis in an electrically heated liquid metal bubble column reactor. Grid connected low-temperature alkaline electrolyser was considered for H2 production in the second scenario. In both cases, 59.25 kgH2 was required for the production of one ton of liquid steel (tls). The specific energy consumption (SEC) for the methane pyrolysis based system was found to be 5.16 MWh/tls. The system used 1.51 MWh/tls of electricity, and required 263 kg/tls of methane, corresponding to an energy consumption of 3.65 MWh/tls. The water electrolysis based system consumed 3.96 MWh/tls of electricity, at an electrolyser efficiency of 50 KWh/kgH2. Both systems have direct emissions of 129.4 kgCO2/tls. The indirect emissions are dependent on the source of natural gas, pellet making process and the grid-emission factor. Indirect emissions for the electrolysis based system could be negligible, if the electricity is generated from renewable energy sources. The levellized cost of production(LCOP) was found to be $631, and $669 respectively at a discount rate of 8%, for a plant-life of 20 years. The LCOP of a natural gas reforming based direct reduction steelmaking plant of operating under similar conditions was found to be $414. Uncertainty analysis was conducted for the NPV and IRR values.
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spelling doaj.art-ca48aed6137e4100a921caa781b9c8382022-12-21T18:56:54ZengElsevierEnergy Conversion and Management: X2590-17452021-06-0110100079Can methane pyrolysis based hydrogen production lead to the decarbonisation of iron and steel industry?Abhinav Bhaskar0Mohsen Assadi1Homam Nikpey Somehsaraei2Corresponding author.; University of Stavanger, 4036, NorwayUniversity of Stavanger, 4036, NorwayUniversity of Stavanger, 4036, NorwayDecarbonisation of the iron and steel industry would require the use of innovative low-carbon production technologies. Use of 100% hydrogen in a shaft furnace (SF) to reduce iron ore has the potential to reduce emissions from iron and steel production significantly. In this work, results from the techno-economic assessment of a H2-SF connected to an electric arc furnace(EAF) for steel production are presented under two scenarios. In the first scenario H2 is produced from molten metal methane pyrolysis in an electrically heated liquid metal bubble column reactor. Grid connected low-temperature alkaline electrolyser was considered for H2 production in the second scenario. In both cases, 59.25 kgH2 was required for the production of one ton of liquid steel (tls). The specific energy consumption (SEC) for the methane pyrolysis based system was found to be 5.16 MWh/tls. The system used 1.51 MWh/tls of electricity, and required 263 kg/tls of methane, corresponding to an energy consumption of 3.65 MWh/tls. The water electrolysis based system consumed 3.96 MWh/tls of electricity, at an electrolyser efficiency of 50 KWh/kgH2. Both systems have direct emissions of 129.4 kgCO2/tls. The indirect emissions are dependent on the source of natural gas, pellet making process and the grid-emission factor. Indirect emissions for the electrolysis based system could be negligible, if the electricity is generated from renewable energy sources. The levellized cost of production(LCOP) was found to be $631, and $669 respectively at a discount rate of 8%, for a plant-life of 20 years. The LCOP of a natural gas reforming based direct reduction steelmaking plant of operating under similar conditions was found to be $414. Uncertainty analysis was conducted for the NPV and IRR values.http://www.sciencedirect.com/science/article/pii/S2590174521000040Industrial decarbonisationHydrogen direct reductionMethane PyrolysisWater electrolysisGreen steel
spellingShingle Abhinav Bhaskar
Mohsen Assadi
Homam Nikpey Somehsaraei
Can methane pyrolysis based hydrogen production lead to the decarbonisation of iron and steel industry?
Energy Conversion and Management: X
Industrial decarbonisation
Hydrogen direct reduction
Methane Pyrolysis
Water electrolysis
Green steel
title Can methane pyrolysis based hydrogen production lead to the decarbonisation of iron and steel industry?
title_full Can methane pyrolysis based hydrogen production lead to the decarbonisation of iron and steel industry?
title_fullStr Can methane pyrolysis based hydrogen production lead to the decarbonisation of iron and steel industry?
title_full_unstemmed Can methane pyrolysis based hydrogen production lead to the decarbonisation of iron and steel industry?
title_short Can methane pyrolysis based hydrogen production lead to the decarbonisation of iron and steel industry?
title_sort can methane pyrolysis based hydrogen production lead to the decarbonisation of iron and steel industry
topic Industrial decarbonisation
Hydrogen direct reduction
Methane Pyrolysis
Water electrolysis
Green steel
url http://www.sciencedirect.com/science/article/pii/S2590174521000040
work_keys_str_mv AT abhinavbhaskar canmethanepyrolysisbasedhydrogenproductionleadtothedecarbonisationofironandsteelindustry
AT mohsenassadi canmethanepyrolysisbasedhydrogenproductionleadtothedecarbonisationofironandsteelindustry
AT homamnikpeysomehsaraei canmethanepyrolysisbasedhydrogenproductionleadtothedecarbonisationofironandsteelindustry