Poly[[(μ4-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide]
In the structure of the title compound, {[Na(C6H15N3O3)]Br}n, the sodium cation and the bromide anion are both located on threefold rotation axes. The sodium cation is bonded to the three hydroxy groups of one 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci) ligand, with the taci ligand residing ar...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813005618 |
| _version_ | 1798019037328834560 |
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| author | Guido J. Reiss Kaspar Hegetschweiler |
| author_facet | Guido J. Reiss Kaspar Hegetschweiler |
| author_sort | Guido J. Reiss |
| collection | DOAJ |
| description | In the structure of the title compound, {[Na(C6H15N3O3)]Br}n, the sodium cation and the bromide anion are both located on threefold rotation axes. The sodium cation is bonded to the three hydroxy groups of one 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci) ligand, with the taci ligand residing around the same threefold rotation axis as the sodium ion. The coordination sphere of the sodium ion is completed by three amino groups of three neighbouring taci molecules. Hence, this type of coordination constitutes a three-dimensional open framework with channels along the c axis which are filled with the bromide counter-anions. Each bromide ion forms three symmetry-related hydrogen bonds to both the hydroxy and the amino groups of neighbouring taci ligands. |
| first_indexed | 2024-04-11T16:34:12Z |
| format | Article |
| id | doaj.art-ca54ad40741a4de4b55d23d218dd19a0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:34:12Z |
| publishDate | 2013-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ca54ad40741a4de4b55d23d218dd19a02022-12-22T04:13:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-04-01694m185m18610.1107/S1600536813005618Poly[[(μ4-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide]Guido J. ReissKaspar HegetschweilerIn the structure of the title compound, {[Na(C6H15N3O3)]Br}n, the sodium cation and the bromide anion are both located on threefold rotation axes. The sodium cation is bonded to the three hydroxy groups of one 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci) ligand, with the taci ligand residing around the same threefold rotation axis as the sodium ion. The coordination sphere of the sodium ion is completed by three amino groups of three neighbouring taci molecules. Hence, this type of coordination constitutes a three-dimensional open framework with channels along the c axis which are filled with the bromide counter-anions. Each bromide ion forms three symmetry-related hydrogen bonds to both the hydroxy and the amino groups of neighbouring taci ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536813005618 |
| spellingShingle | Guido J. Reiss Kaspar Hegetschweiler Poly[[(μ4-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] Acta Crystallographica Section E |
| title | Poly[[(μ4-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
| title_full | Poly[[(μ4-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
| title_fullStr | Poly[[(μ4-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
| title_full_unstemmed | Poly[[(μ4-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
| title_short | Poly[[(μ4-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
| title_sort | poly 956 4 1 3 5 triamino 1 3 5 trideoxy cis inositol sodium bromide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813005618 |
| work_keys_str_mv | AT guidojreiss poly9564135triamino135trideoxycisinositolsodiumbromide AT kasparhegetschweiler poly9564135triamino135trideoxycisinositolsodiumbromide |