Results of an Eight-Year Extraction of Phosphorus Minerals within the Seymchan Meteorite

In-fall of extraterrestrial material including meteorites and interstellar dust particles during the late heavy bombardment are known to have brought substantial amounts of reduced oxidation-state phosphorus to the early Earth in the form of siderophilic minerals, e.g., schreibersite ((FeNi)<sub&...

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Main Authors: Maheen Gull, Tian Feng, Matthew A. Pasek
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Life
Subjects:
Online Access:https://www.mdpi.com/2075-1729/12/10/1591
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author Maheen Gull
Tian Feng
Matthew A. Pasek
author_facet Maheen Gull
Tian Feng
Matthew A. Pasek
author_sort Maheen Gull
collection DOAJ
description In-fall of extraterrestrial material including meteorites and interstellar dust particles during the late heavy bombardment are known to have brought substantial amounts of reduced oxidation-state phosphorus to the early Earth in the form of siderophilic minerals, e.g., schreibersite ((FeNi)<sub>3</sub>P). In this report, we present results on the reaction of meteoritic phosphide minerals in the Seymchan meteorite in ultrapure water for 8 years. The ions produced during schreibersite corrosion (phosphite, hypophosphate, pyrophosphate, and phosphate) are stable and persistent in aqueous solution over this timescale. These results were also compared with the short-term corrosion reactions of the meteoritic mineral schreibersite’s synthetic analog Fe<sub>3</sub>P in aqueous and non-aqueous solutions (ultrapure water and formamide). This finding suggests that the reduced-oxidation-state phosphorus (P) compounds including phosphite could be ubiquitous and stable on the early Earth over a long span of time and such compounds could be readily available on the early Earth.
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spelling doaj.art-ca60e0bf5d5e499e9dae3d10e72866122023-11-24T00:56:54ZengMDPI AGLife2075-17292022-10-011210159110.3390/life12101591Results of an Eight-Year Extraction of Phosphorus Minerals within the Seymchan MeteoriteMaheen Gull0Tian Feng1Matthew A. Pasek2School of Geosciences, University of South Florida, Tampa, FL 33584, USASchool of Geosciences, University of South Florida, Tampa, FL 33584, USASchool of Geosciences, University of South Florida, Tampa, FL 33584, USAIn-fall of extraterrestrial material including meteorites and interstellar dust particles during the late heavy bombardment are known to have brought substantial amounts of reduced oxidation-state phosphorus to the early Earth in the form of siderophilic minerals, e.g., schreibersite ((FeNi)<sub>3</sub>P). In this report, we present results on the reaction of meteoritic phosphide minerals in the Seymchan meteorite in ultrapure water for 8 years. The ions produced during schreibersite corrosion (phosphite, hypophosphate, pyrophosphate, and phosphate) are stable and persistent in aqueous solution over this timescale. These results were also compared with the short-term corrosion reactions of the meteoritic mineral schreibersite’s synthetic analog Fe<sub>3</sub>P in aqueous and non-aqueous solutions (ultrapure water and formamide). This finding suggests that the reduced-oxidation-state phosphorus (P) compounds including phosphite could be ubiquitous and stable on the early Earth over a long span of time and such compounds could be readily available on the early Earth.https://www.mdpi.com/2075-1729/12/10/1591phosphorusearly Earthorigin of lifemeteoritesphosphidesphosphite
spellingShingle Maheen Gull
Tian Feng
Matthew A. Pasek
Results of an Eight-Year Extraction of Phosphorus Minerals within the Seymchan Meteorite
Life
phosphorus
early Earth
origin of life
meteorites
phosphides
phosphite
title Results of an Eight-Year Extraction of Phosphorus Minerals within the Seymchan Meteorite
title_full Results of an Eight-Year Extraction of Phosphorus Minerals within the Seymchan Meteorite
title_fullStr Results of an Eight-Year Extraction of Phosphorus Minerals within the Seymchan Meteorite
title_full_unstemmed Results of an Eight-Year Extraction of Phosphorus Minerals within the Seymchan Meteorite
title_short Results of an Eight-Year Extraction of Phosphorus Minerals within the Seymchan Meteorite
title_sort results of an eight year extraction of phosphorus minerals within the seymchan meteorite
topic phosphorus
early Earth
origin of life
meteorites
phosphides
phosphite
url https://www.mdpi.com/2075-1729/12/10/1591
work_keys_str_mv AT maheengull resultsofaneightyearextractionofphosphorusmineralswithintheseymchanmeteorite
AT tianfeng resultsofaneightyearextractionofphosphorusmineralswithintheseymchanmeteorite
AT matthewapasek resultsofaneightyearextractionofphosphorusmineralswithintheseymchanmeteorite