Recent Progress and Required Developments in Atmospheric Corrosion of Galvanised Steel and Zinc

This paper reviews the progress in atmospheric corrosion of zinc since 2009. It firstly summarises the state of the art in 2009, then outlines progress since 2009, and then looks at the significance of this progress and the areas the need more research. Within this framework, it looks at climate eff...

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Main Author: Ivan S. Cole
Format: Article
Language:English
Published: MDPI AG 2017-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/10/11/1288
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author Ivan S. Cole
author_facet Ivan S. Cole
author_sort Ivan S. Cole
collection DOAJ
description This paper reviews the progress in atmospheric corrosion of zinc since 2009. It firstly summarises the state of the art in 2009, then outlines progress since 2009, and then looks at the significance of this progress and the areas the need more research. Within this framework, it looks at climate effects, oxide formation, oxide properties, pitting, laboratory duplication of atmospheric corrosion, and modelling. The major findings are that there have been major advances in the fields understanding of the structure of corrosion patina, in particular their layered structure and the presence of compact layers, local corrosion attacks have been found to be a significant process in atmospheric corrosion and experiments under droplets are leading to new understanding of the criticality of drop size in regulating atmospheric corrosion processes. Further research is indicating that zinc oxide within corrosion products may promote the oxygen reduction reaction (ORR) and that, in porous oxides, the ORR would control pore chemistry and may promote oxide densification. There is a strong need for more research to understand more deeply the formation and properties of these layered oxides as well as additional research to refine and quantify our emerging understanding of corrosion under droplets.
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spelling doaj.art-caa81999613e4f7abdb2c78d8cb093522022-12-22T02:40:13ZengMDPI AGMaterials1996-19442017-11-011011128810.3390/ma10111288ma10111288Recent Progress and Required Developments in Atmospheric Corrosion of Galvanised Steel and ZincIvan S. Cole0School of Engineering, RMIT University, Melbourne, Victoria 3001, AustraliaThis paper reviews the progress in atmospheric corrosion of zinc since 2009. It firstly summarises the state of the art in 2009, then outlines progress since 2009, and then looks at the significance of this progress and the areas the need more research. Within this framework, it looks at climate effects, oxide formation, oxide properties, pitting, laboratory duplication of atmospheric corrosion, and modelling. The major findings are that there have been major advances in the fields understanding of the structure of corrosion patina, in particular their layered structure and the presence of compact layers, local corrosion attacks have been found to be a significant process in atmospheric corrosion and experiments under droplets are leading to new understanding of the criticality of drop size in regulating atmospheric corrosion processes. Further research is indicating that zinc oxide within corrosion products may promote the oxygen reduction reaction (ORR) and that, in porous oxides, the ORR would control pore chemistry and may promote oxide densification. There is a strong need for more research to understand more deeply the formation and properties of these layered oxides as well as additional research to refine and quantify our emerging understanding of corrosion under droplets.https://www.mdpi.com/1996-1944/10/11/1288zinccorrosionoxidesdroplets
spellingShingle Ivan S. Cole
Recent Progress and Required Developments in Atmospheric Corrosion of Galvanised Steel and Zinc
Materials
zinc
corrosion
oxides
droplets
title Recent Progress and Required Developments in Atmospheric Corrosion of Galvanised Steel and Zinc
title_full Recent Progress and Required Developments in Atmospheric Corrosion of Galvanised Steel and Zinc
title_fullStr Recent Progress and Required Developments in Atmospheric Corrosion of Galvanised Steel and Zinc
title_full_unstemmed Recent Progress and Required Developments in Atmospheric Corrosion of Galvanised Steel and Zinc
title_short Recent Progress and Required Developments in Atmospheric Corrosion of Galvanised Steel and Zinc
title_sort recent progress and required developments in atmospheric corrosion of galvanised steel and zinc
topic zinc
corrosion
oxides
droplets
url https://www.mdpi.com/1996-1944/10/11/1288
work_keys_str_mv AT ivanscole recentprogressandrequireddevelopmentsinatmosphericcorrosionofgalvanisedsteelandzinc