Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases

Data on thermally induced transformations of Mn exchanged zeolites LTA and FAU topology are presented in this paper. Thermally induced phase transformation of Mn-exchange zeolites are followed in the range from 700 to 1300°C. Both frameworks collapse into amorphous intermediate products aft...

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Bibliographic Details
Main Authors: Radosavljević-Mihajlović Ana, Mitić Vojislav, Šaponjić Aleksandra, Kasić Vladan
Format: Article
Language:English
Published: International Institute for the Science of Sintering, Beograd 2021-01-01
Series:Science of Sintering
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0350-820X/2021/0350-820X2103397R.pdf
Description
Summary:Data on thermally induced transformations of Mn exchanged zeolites LTA and FAU topology are presented in this paper. Thermally induced phase transformation of Mn-exchange zeolites are followed in the range from 700 to 1300°C. Both frameworks collapse into amorphous intermediate products after heating between 600 and 650°C. Prolonged heating of the intermediate product above 1100°C results directly in formation of a disorder Mn-anorthiteLTA and Mn-anorthiteFAU. The parameter of unit cell of Mn-anorthiteLTA and Mn-anorthiteFAU, in temperature range between 700 and 1300°C, was observed in space group C-1. The phase conversions in the temperature range investigated were followed by thermal, X-ray powder diffraction and FT-IR analyses
ISSN:0350-820X
1820-7413