Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases

Data on thermally induced transformations of Mn exchanged zeolites LTA and FAU topology are presented in this paper. Thermally induced phase transformation of Mn-exchange zeolites are followed in the range from 700 to 1300°C. Both frameworks collapse into amorphous intermediate products aft...

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Main Authors: Radosavljević-Mihajlović Ana, Mitić Vojislav, Šaponjić Aleksandra, Kasić Vladan
Format: Article
Language:English
Published: International Institute for the Science of Sintering, Beograd 2021-01-01
Series:Science of Sintering
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0350-820X/2021/0350-820X2103397R.pdf
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author Radosavljević-Mihajlović Ana
Mitić Vojislav
Šaponjić Aleksandra
Kasić Vladan
author_facet Radosavljević-Mihajlović Ana
Mitić Vojislav
Šaponjić Aleksandra
Kasić Vladan
author_sort Radosavljević-Mihajlović Ana
collection DOAJ
description Data on thermally induced transformations of Mn exchanged zeolites LTA and FAU topology are presented in this paper. Thermally induced phase transformation of Mn-exchange zeolites are followed in the range from 700 to 1300°C. Both frameworks collapse into amorphous intermediate products after heating between 600 and 650°C. Prolonged heating of the intermediate product above 1100°C results directly in formation of a disorder Mn-anorthiteLTA and Mn-anorthiteFAU. The parameter of unit cell of Mn-anorthiteLTA and Mn-anorthiteFAU, in temperature range between 700 and 1300°C, was observed in space group C-1. The phase conversions in the temperature range investigated were followed by thermal, X-ray powder diffraction and FT-IR analyses
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spelling doaj.art-cac7abd2fc8f4573b80921d6bae3395f2022-12-21T23:33:37ZengInternational Institute for the Science of Sintering, BeogradScience of Sintering0350-820X1820-74132021-01-0153339740610.2298/SOS2103397R0350-820X2103397RThermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phasesRadosavljević-Mihajlović Ana0https://orcid.org/0000-0002-9194-161XMitić Vojislav1Šaponjić Aleksandra2https://orcid.org/0000-0002-6983-6485Kasić Vladan3Institute for technology of nuclear and other mineral raw materials, Belgrade, SerbiaInstitute of Technical Sciences of the Serbian Academy of Science and Arts, Belgrade, Serbia + University of electronic Niš, Niš, SerbiaDepartment of physical chemistry ”VINCA” Institute of Nuclear Science-National Institute of the Republic of Serbia, University of Belgrade, SerbiaInstitute for technology of nuclear and other mineral raw materials, Belgrade, SerbiaData on thermally induced transformations of Mn exchanged zeolites LTA and FAU topology are presented in this paper. Thermally induced phase transformation of Mn-exchange zeolites are followed in the range from 700 to 1300°C. Both frameworks collapse into amorphous intermediate products after heating between 600 and 650°C. Prolonged heating of the intermediate product above 1100°C results directly in formation of a disorder Mn-anorthiteLTA and Mn-anorthiteFAU. The parameter of unit cell of Mn-anorthiteLTA and Mn-anorthiteFAU, in temperature range between 700 and 1300°C, was observed in space group C-1. The phase conversions in the temperature range investigated were followed by thermal, X-ray powder diffraction and FT-IR analyseshttp://www.doiserbia.nb.rs/img/doi/0350-820X/2021/0350-820X2103397R.pdfion exchange of zeolitethermal treatmentx-ray powder diffraction analysis
spellingShingle Radosavljević-Mihajlović Ana
Mitić Vojislav
Šaponjić Aleksandra
Kasić Vladan
Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases
Science of Sintering
ion exchange of zeolite
thermal treatment
x-ray powder diffraction analysis
title Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases
title_full Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases
title_fullStr Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases
title_full_unstemmed Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases
title_short Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases
title_sort thermally induced phase transformation of mn lta and mn fau zeolite to anorthite phases
topic ion exchange of zeolite
thermal treatment
x-ray powder diffraction analysis
url http://www.doiserbia.nb.rs/img/doi/0350-820X/2021/0350-820X2103397R.pdf
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AT miticvojislav thermallyinducedphasetransformationofmnltaandmnfauzeolitetoanorthitephases
AT saponjicaleksandra thermallyinducedphasetransformationofmnltaandmnfauzeolitetoanorthitephases
AT kasicvladan thermallyinducedphasetransformationofmnltaandmnfauzeolitetoanorthitephases