Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases
Data on thermally induced transformations of Mn exchanged zeolites LTA and FAU topology are presented in this paper. Thermally induced phase transformation of Mn-exchange zeolites are followed in the range from 700 to 1300°C. Both frameworks collapse into amorphous intermediate products aft...
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International Institute for the Science of Sintering, Beograd
2021-01-01
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Series: | Science of Sintering |
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Online Access: | http://www.doiserbia.nb.rs/img/doi/0350-820X/2021/0350-820X2103397R.pdf |
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author | Radosavljević-Mihajlović Ana Mitić Vojislav Šaponjić Aleksandra Kasić Vladan |
author_facet | Radosavljević-Mihajlović Ana Mitić Vojislav Šaponjić Aleksandra Kasić Vladan |
author_sort | Radosavljević-Mihajlović Ana |
collection | DOAJ |
description | Data on thermally induced transformations of Mn exchanged zeolites LTA and
FAU topology are presented in this paper. Thermally induced phase
transformation of Mn-exchange zeolites are followed in the range from 700 to
1300°C. Both frameworks collapse into amorphous intermediate products after
heating between 600 and 650°C. Prolonged heating of the intermediate
product above 1100°C results directly in formation of a disorder
Mn-anorthiteLTA and Mn-anorthiteFAU. The parameter of unit cell of
Mn-anorthiteLTA and Mn-anorthiteFAU, in temperature range between 700 and
1300°C, was observed in space group C-1. The phase conversions in the
temperature range investigated were followed by thermal, X-ray powder
diffraction and FT-IR analyses |
first_indexed | 2024-12-13T19:43:17Z |
format | Article |
id | doaj.art-cac7abd2fc8f4573b80921d6bae3395f |
institution | Directory Open Access Journal |
issn | 0350-820X 1820-7413 |
language | English |
last_indexed | 2024-12-13T19:43:17Z |
publishDate | 2021-01-01 |
publisher | International Institute for the Science of Sintering, Beograd |
record_format | Article |
series | Science of Sintering |
spelling | doaj.art-cac7abd2fc8f4573b80921d6bae3395f2022-12-21T23:33:37ZengInternational Institute for the Science of Sintering, BeogradScience of Sintering0350-820X1820-74132021-01-0153339740610.2298/SOS2103397R0350-820X2103397RThermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phasesRadosavljević-Mihajlović Ana0https://orcid.org/0000-0002-9194-161XMitić Vojislav1Šaponjić Aleksandra2https://orcid.org/0000-0002-6983-6485Kasić Vladan3Institute for technology of nuclear and other mineral raw materials, Belgrade, SerbiaInstitute of Technical Sciences of the Serbian Academy of Science and Arts, Belgrade, Serbia + University of electronic Niš, Niš, SerbiaDepartment of physical chemistry ”VINCA” Institute of Nuclear Science-National Institute of the Republic of Serbia, University of Belgrade, SerbiaInstitute for technology of nuclear and other mineral raw materials, Belgrade, SerbiaData on thermally induced transformations of Mn exchanged zeolites LTA and FAU topology are presented in this paper. Thermally induced phase transformation of Mn-exchange zeolites are followed in the range from 700 to 1300°C. Both frameworks collapse into amorphous intermediate products after heating between 600 and 650°C. Prolonged heating of the intermediate product above 1100°C results directly in formation of a disorder Mn-anorthiteLTA and Mn-anorthiteFAU. The parameter of unit cell of Mn-anorthiteLTA and Mn-anorthiteFAU, in temperature range between 700 and 1300°C, was observed in space group C-1. The phase conversions in the temperature range investigated were followed by thermal, X-ray powder diffraction and FT-IR analyseshttp://www.doiserbia.nb.rs/img/doi/0350-820X/2021/0350-820X2103397R.pdfion exchange of zeolitethermal treatmentx-ray powder diffraction analysis |
spellingShingle | Radosavljević-Mihajlović Ana Mitić Vojislav Šaponjić Aleksandra Kasić Vladan Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases Science of Sintering ion exchange of zeolite thermal treatment x-ray powder diffraction analysis |
title | Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases |
title_full | Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases |
title_fullStr | Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases |
title_full_unstemmed | Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases |
title_short | Thermally induced phase transformation of Mn-LTA and Mn-FAU zeolite to anorthite phases |
title_sort | thermally induced phase transformation of mn lta and mn fau zeolite to anorthite phases |
topic | ion exchange of zeolite thermal treatment x-ray powder diffraction analysis |
url | http://www.doiserbia.nb.rs/img/doi/0350-820X/2021/0350-820X2103397R.pdf |
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