Dynamically stable and amplified circularly polarized excimer emission regulated by solvation of chiral co-assembly process

Chiral supramolecular assembly is an important strategy for the development of excellent circularly polarized luminescent (CPL)-active materials, but often they suffer from low quantum yield and luminescence dissymmetry factor. Herein, the authors we report a chiral coassembly process of achiral pyr...

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Main Authors: Yuxia Zhang, Hang Li, Zhongxing Geng, Wenhua Zheng, Yiwu Quan, Yixiang Cheng
Format: Article
Language:English
Published: Nature Portfolio 2022-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-32714-1
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author Yuxia Zhang
Hang Li
Zhongxing Geng
Wenhua Zheng
Yiwu Quan
Yixiang Cheng
author_facet Yuxia Zhang
Hang Li
Zhongxing Geng
Wenhua Zheng
Yiwu Quan
Yixiang Cheng
author_sort Yuxia Zhang
collection DOAJ
description Chiral supramolecular assembly is an important strategy for the development of excellent circularly polarized luminescent (CPL)-active materials, but often they suffer from low quantum yield and luminescence dissymmetry factor. Herein, the authors we report a chiral coassembly process of achiral pyrene-based dyes leading to chiral excimers emitting with a high dissymmetry factor.
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spelling doaj.art-cacf07ba810b473c9b41c93448b812dd2022-12-22T01:37:18ZengNature PortfolioNature Communications2041-17232022-08-011311810.1038/s41467-022-32714-1Dynamically stable and amplified circularly polarized excimer emission regulated by solvation of chiral co-assembly processYuxia Zhang0Hang Li1Zhongxing Geng2Wenhua Zheng3Yiwu Quan4Yixiang Cheng5State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing UniversityState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing UniversityState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing UniversityState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing UniversityKey Laboratory of High Performance Polymer Material and Technology of Ministry of Education, Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing UniversityState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing UniversityChiral supramolecular assembly is an important strategy for the development of excellent circularly polarized luminescent (CPL)-active materials, but often they suffer from low quantum yield and luminescence dissymmetry factor. Herein, the authors we report a chiral coassembly process of achiral pyrene-based dyes leading to chiral excimers emitting with a high dissymmetry factor.https://doi.org/10.1038/s41467-022-32714-1
spellingShingle Yuxia Zhang
Hang Li
Zhongxing Geng
Wenhua Zheng
Yiwu Quan
Yixiang Cheng
Dynamically stable and amplified circularly polarized excimer emission regulated by solvation of chiral co-assembly process
Nature Communications
title Dynamically stable and amplified circularly polarized excimer emission regulated by solvation of chiral co-assembly process
title_full Dynamically stable and amplified circularly polarized excimer emission regulated by solvation of chiral co-assembly process
title_fullStr Dynamically stable and amplified circularly polarized excimer emission regulated by solvation of chiral co-assembly process
title_full_unstemmed Dynamically stable and amplified circularly polarized excimer emission regulated by solvation of chiral co-assembly process
title_short Dynamically stable and amplified circularly polarized excimer emission regulated by solvation of chiral co-assembly process
title_sort dynamically stable and amplified circularly polarized excimer emission regulated by solvation of chiral co assembly process
url https://doi.org/10.1038/s41467-022-32714-1
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AT hangli dynamicallystableandamplifiedcircularlypolarizedexcimeremissionregulatedbysolvationofchiralcoassemblyprocess
AT zhongxinggeng dynamicallystableandamplifiedcircularlypolarizedexcimeremissionregulatedbysolvationofchiralcoassemblyprocess
AT wenhuazheng dynamicallystableandamplifiedcircularlypolarizedexcimeremissionregulatedbysolvationofchiralcoassemblyprocess
AT yiwuquan dynamicallystableandamplifiedcircularlypolarizedexcimeremissionregulatedbysolvationofchiralcoassemblyprocess
AT yixiangcheng dynamicallystableandamplifiedcircularlypolarizedexcimeremissionregulatedbysolvationofchiralcoassemblyprocess