Preparation and Properties of Magnetic Molecularly Imprinted Polymers and Their Use as Adsorbents for Selective Adsorption of Indole
A novel method for selective adsorption of indole using magnetic molecularly imprinted polymers (MMIPs) as the adsorbent is proposed in this work. The MMIPs were synthesized by microemulsion polymerization, using Fe 3 O 4 nanoparticles as the magnetically susceptible component, acrylamide as the fun...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
SAGE Publications
2014-07-01
|
| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263-6174.32.7.509 |
| _version_ | 1797285557828583424 |
|---|---|
| author | Dandan Niu Zhiping Zhou Chen Wu Wanzhen Xu |
| author_facet | Dandan Niu Zhiping Zhou Chen Wu Wanzhen Xu |
| author_sort | Dandan Niu |
| collection | DOAJ |
| description | A novel method for selective adsorption of indole using magnetic molecularly imprinted polymers (MMIPs) as the adsorbent is proposed in this work. The MMIPs were synthesized by microemulsion polymerization, using Fe 3 O 4 nanoparticles as the magnetically susceptible component, acrylamide as the functional monomer, ethylene glycol dimethacrylate as the cross-linker and indole as template molecule. The products obtained were characterized by Fourier transform infrared spectroscopy, transmission electron microscopy, vibrating sample magnetometry and thermogravimetric analysis. The adsorption performances of MMIPs were investigated by batch adsorption experiments in terms of selective recognition, adsorption kinetics and adsorption isotherms, respectively. The maximum amount of adsorption on MMIPs occurs at approximately 120 minutes. The results indicate that MMIPs possess high adsorption capacity for indole. The adsorption fits with the pseudo-second-order kinetic model and the Langmuir isotherm model. |
| first_indexed | 2024-03-07T18:04:56Z |
| format | Article |
| id | doaj.art-cad9298ed8ae465f9b42ce2a184c8b08 |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T18:04:56Z |
| publishDate | 2014-07-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-cad9298ed8ae465f9b42ce2a184c8b082024-03-02T09:53:05ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382014-07-013210.1260/0263-6174.32.7.509Preparation and Properties of Magnetic Molecularly Imprinted Polymers and Their Use as Adsorbents for Selective Adsorption of IndoleDandan Niu0Zhiping Zhou1Chen Wu2Wanzhen Xu3 Department of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, P.R. China Department of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, P.R. China Department of Environment, Jiangsu University, Zhenjiang 212013, P.R. China Department of Environment, Jiangsu University, Zhenjiang 212013, P.R. ChinaA novel method for selective adsorption of indole using magnetic molecularly imprinted polymers (MMIPs) as the adsorbent is proposed in this work. The MMIPs were synthesized by microemulsion polymerization, using Fe 3 O 4 nanoparticles as the magnetically susceptible component, acrylamide as the functional monomer, ethylene glycol dimethacrylate as the cross-linker and indole as template molecule. The products obtained were characterized by Fourier transform infrared spectroscopy, transmission electron microscopy, vibrating sample magnetometry and thermogravimetric analysis. The adsorption performances of MMIPs were investigated by batch adsorption experiments in terms of selective recognition, adsorption kinetics and adsorption isotherms, respectively. The maximum amount of adsorption on MMIPs occurs at approximately 120 minutes. The results indicate that MMIPs possess high adsorption capacity for indole. The adsorption fits with the pseudo-second-order kinetic model and the Langmuir isotherm model.https://doi.org/10.1260/0263-6174.32.7.509 |
| spellingShingle | Dandan Niu Zhiping Zhou Chen Wu Wanzhen Xu Preparation and Properties of Magnetic Molecularly Imprinted Polymers and Their Use as Adsorbents for Selective Adsorption of Indole Adsorption Science & Technology |
| title | Preparation and Properties of Magnetic Molecularly Imprinted Polymers and Their Use as Adsorbents for Selective Adsorption of Indole |
| title_full | Preparation and Properties of Magnetic Molecularly Imprinted Polymers and Their Use as Adsorbents for Selective Adsorption of Indole |
| title_fullStr | Preparation and Properties of Magnetic Molecularly Imprinted Polymers and Their Use as Adsorbents for Selective Adsorption of Indole |
| title_full_unstemmed | Preparation and Properties of Magnetic Molecularly Imprinted Polymers and Their Use as Adsorbents for Selective Adsorption of Indole |
| title_short | Preparation and Properties of Magnetic Molecularly Imprinted Polymers and Their Use as Adsorbents for Selective Adsorption of Indole |
| title_sort | preparation and properties of magnetic molecularly imprinted polymers and their use as adsorbents for selective adsorption of indole |
| url | https://doi.org/10.1260/0263-6174.32.7.509 |
| work_keys_str_mv | AT dandanniu preparationandpropertiesofmagneticmolecularlyimprintedpolymersandtheiruseasadsorbentsforselectiveadsorptionofindole AT zhipingzhou preparationandpropertiesofmagneticmolecularlyimprintedpolymersandtheiruseasadsorbentsforselectiveadsorptionofindole AT chenwu preparationandpropertiesofmagneticmolecularlyimprintedpolymersandtheiruseasadsorbentsforselectiveadsorptionofindole AT wanzhenxu preparationandpropertiesofmagneticmolecularlyimprintedpolymersandtheiruseasadsorbentsforselectiveadsorptionofindole |