High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square

A high sensitivity and ultra-low concentration range photoacoustic spectroscopy (PAS) gas detection system, which was based on a novel trapezoid compound ellipsoid resonant photoacoustic cell (TCER-PAC) and partial least square (PLS), was proposed to detect acetylene (C2H2) gas. In the concentration...

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Main Authors: Qiaoyun Wang, Shunyuan Xu, Ziheng Zhu, Jilong Wang, Xin Zou, Chu Zhang, Qiang Liu
Format: Article
Language:English
Published: Elsevier 2024-02-01
Series:Photoacoustics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2213597923001362
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author Qiaoyun Wang
Shunyuan Xu
Ziheng Zhu
Jilong Wang
Xin Zou
Chu Zhang
Qiang Liu
author_facet Qiaoyun Wang
Shunyuan Xu
Ziheng Zhu
Jilong Wang
Xin Zou
Chu Zhang
Qiang Liu
author_sort Qiaoyun Wang
collection DOAJ
description A high sensitivity and ultra-low concentration range photoacoustic spectroscopy (PAS) gas detection system, which was based on a novel trapezoid compound ellipsoid resonant photoacoustic cell (TCER-PAC) and partial least square (PLS), was proposed to detect acetylene (C2H2) gas. In the concentration range of 0.5 ppm ∼ 10.0 ppm, the limit of detection (LOD) values of TCER-PAC-based PAS system without data processing was 66.4 ppb, which was lower than that of the traditional trapezoid compound cylindrical resonant photoacoustic cell (TCCR-PAC). The experimental results indicated that the TCER-PAC had higher sensitivity than of TCCR-PAC. Within the concentration range of 12.5 ppb ∼ 125.0 ppb, the LOD and limit of quantification (LOQ) of TCER-PAC-based PAS system combined with PLS regression algorithm were 1.1 ppb and 3.7 ppb, respectively. The results showed that higher detection sensitivity and lower LOD were obtained by PAS system with TCER-PAC and PLS than that of TCCR-PAC-based PAS system.
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spelling doaj.art-cae2dd58c30b41d0b59158b55f8465d22024-01-23T04:15:38ZengElsevierPhotoacoustics2213-59792024-02-0135100583High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least squareQiaoyun Wang0Shunyuan Xu1Ziheng Zhu2Jilong Wang3Xin Zou4Chu Zhang5Qiang Liu6College of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, China; Hebei Key Laboratory of Micro-Nano Precision Optical Sensing and Measurement Technology, Qinhuangdao 066004, China; Corresponding author at: College of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, China.College of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, ChinaCollege of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, ChinaCollege of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, ChinaCollege of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, ChinaNational Key Laboratory of Science and Technology on Tunable Laser, Harbin Institute of Technology, Harbin 150001, ChinaCollege of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, China; Hebei Key Laboratory of Micro-Nano Precision Optical Sensing and Measurement Technology, Qinhuangdao 066004, ChinaA high sensitivity and ultra-low concentration range photoacoustic spectroscopy (PAS) gas detection system, which was based on a novel trapezoid compound ellipsoid resonant photoacoustic cell (TCER-PAC) and partial least square (PLS), was proposed to detect acetylene (C2H2) gas. In the concentration range of 0.5 ppm ∼ 10.0 ppm, the limit of detection (LOD) values of TCER-PAC-based PAS system without data processing was 66.4 ppb, which was lower than that of the traditional trapezoid compound cylindrical resonant photoacoustic cell (TCCR-PAC). The experimental results indicated that the TCER-PAC had higher sensitivity than of TCCR-PAC. Within the concentration range of 12.5 ppb ∼ 125.0 ppb, the LOD and limit of quantification (LOQ) of TCER-PAC-based PAS system combined with PLS regression algorithm were 1.1 ppb and 3.7 ppb, respectively. The results showed that higher detection sensitivity and lower LOD were obtained by PAS system with TCER-PAC and PLS than that of TCCR-PAC-based PAS system.http://www.sciencedirect.com/science/article/pii/S2213597923001362Photoacoustic spectroscopyTrace gas detectionPartial least squareTrapezoid compound ellipsoidal photoacoustic cellC2H2 gas
spellingShingle Qiaoyun Wang
Shunyuan Xu
Ziheng Zhu
Jilong Wang
Xin Zou
Chu Zhang
Qiang Liu
High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square
Photoacoustics
Photoacoustic spectroscopy
Trace gas detection
Partial least square
Trapezoid compound ellipsoidal photoacoustic cell
C2H2 gas
title High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square
title_full High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square
title_fullStr High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square
title_full_unstemmed High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square
title_short High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square
title_sort high sensitivity and ultra low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square
topic Photoacoustic spectroscopy
Trace gas detection
Partial least square
Trapezoid compound ellipsoidal photoacoustic cell
C2H2 gas
url http://www.sciencedirect.com/science/article/pii/S2213597923001362
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