High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square
A high sensitivity and ultra-low concentration range photoacoustic spectroscopy (PAS) gas detection system, which was based on a novel trapezoid compound ellipsoid resonant photoacoustic cell (TCER-PAC) and partial least square (PLS), was proposed to detect acetylene (C2H2) gas. In the concentration...
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Elsevier
2024-02-01
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Series: | Photoacoustics |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2213597923001362 |
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author | Qiaoyun Wang Shunyuan Xu Ziheng Zhu Jilong Wang Xin Zou Chu Zhang Qiang Liu |
author_facet | Qiaoyun Wang Shunyuan Xu Ziheng Zhu Jilong Wang Xin Zou Chu Zhang Qiang Liu |
author_sort | Qiaoyun Wang |
collection | DOAJ |
description | A high sensitivity and ultra-low concentration range photoacoustic spectroscopy (PAS) gas detection system, which was based on a novel trapezoid compound ellipsoid resonant photoacoustic cell (TCER-PAC) and partial least square (PLS), was proposed to detect acetylene (C2H2) gas. In the concentration range of 0.5 ppm ∼ 10.0 ppm, the limit of detection (LOD) values of TCER-PAC-based PAS system without data processing was 66.4 ppb, which was lower than that of the traditional trapezoid compound cylindrical resonant photoacoustic cell (TCCR-PAC). The experimental results indicated that the TCER-PAC had higher sensitivity than of TCCR-PAC. Within the concentration range of 12.5 ppb ∼ 125.0 ppb, the LOD and limit of quantification (LOQ) of TCER-PAC-based PAS system combined with PLS regression algorithm were 1.1 ppb and 3.7 ppb, respectively. The results showed that higher detection sensitivity and lower LOD were obtained by PAS system with TCER-PAC and PLS than that of TCCR-PAC-based PAS system. |
first_indexed | 2024-03-08T12:09:04Z |
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id | doaj.art-cae2dd58c30b41d0b59158b55f8465d2 |
institution | Directory Open Access Journal |
issn | 2213-5979 |
language | English |
last_indexed | 2024-03-08T12:09:04Z |
publishDate | 2024-02-01 |
publisher | Elsevier |
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series | Photoacoustics |
spelling | doaj.art-cae2dd58c30b41d0b59158b55f8465d22024-01-23T04:15:38ZengElsevierPhotoacoustics2213-59792024-02-0135100583High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least squareQiaoyun Wang0Shunyuan Xu1Ziheng Zhu2Jilong Wang3Xin Zou4Chu Zhang5Qiang Liu6College of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, China; Hebei Key Laboratory of Micro-Nano Precision Optical Sensing and Measurement Technology, Qinhuangdao 066004, China; Corresponding author at: College of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, China.College of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, ChinaCollege of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, ChinaCollege of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, ChinaCollege of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, ChinaNational Key Laboratory of Science and Technology on Tunable Laser, Harbin Institute of Technology, Harbin 150001, ChinaCollege of Information Science and Engineering, Northeastern University, Shenyang, Liaoning Province 110819, China; Hebei Key Laboratory of Micro-Nano Precision Optical Sensing and Measurement Technology, Qinhuangdao 066004, ChinaA high sensitivity and ultra-low concentration range photoacoustic spectroscopy (PAS) gas detection system, which was based on a novel trapezoid compound ellipsoid resonant photoacoustic cell (TCER-PAC) and partial least square (PLS), was proposed to detect acetylene (C2H2) gas. In the concentration range of 0.5 ppm ∼ 10.0 ppm, the limit of detection (LOD) values of TCER-PAC-based PAS system without data processing was 66.4 ppb, which was lower than that of the traditional trapezoid compound cylindrical resonant photoacoustic cell (TCCR-PAC). The experimental results indicated that the TCER-PAC had higher sensitivity than of TCCR-PAC. Within the concentration range of 12.5 ppb ∼ 125.0 ppb, the LOD and limit of quantification (LOQ) of TCER-PAC-based PAS system combined with PLS regression algorithm were 1.1 ppb and 3.7 ppb, respectively. The results showed that higher detection sensitivity and lower LOD were obtained by PAS system with TCER-PAC and PLS than that of TCCR-PAC-based PAS system.http://www.sciencedirect.com/science/article/pii/S2213597923001362Photoacoustic spectroscopyTrace gas detectionPartial least squareTrapezoid compound ellipsoidal photoacoustic cellC2H2 gas |
spellingShingle | Qiaoyun Wang Shunyuan Xu Ziheng Zhu Jilong Wang Xin Zou Chu Zhang Qiang Liu High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square Photoacoustics Photoacoustic spectroscopy Trace gas detection Partial least square Trapezoid compound ellipsoidal photoacoustic cell C2H2 gas |
title | High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square |
title_full | High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square |
title_fullStr | High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square |
title_full_unstemmed | High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square |
title_short | High sensitivity and ultra-low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square |
title_sort | high sensitivity and ultra low concentration range photoacoustic spectroscopy based on trapezoid compound ellipsoid resonant photoacoustic cell and partial least square |
topic | Photoacoustic spectroscopy Trace gas detection Partial least square Trapezoid compound ellipsoidal photoacoustic cell C2H2 gas |
url | http://www.sciencedirect.com/science/article/pii/S2213597923001362 |
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