Degradation kinetic of Methyl Tert-Butyl Ether (MTBE)by O3/ H2O2(O3/ H2O2对MTBE的氧化降解动力学研究)
近年来汽油添加剂甲基叔丁基醚(MTBE)对环境造成的持久性的危害已越来越受到人们的重视.地下水中MTBE的污染主要是常见于通过地下储藏罐或管道渗漏造成.本文试验研究探讨了O3/H2O2氧化MTBE的降解过程及反应动力学.结果表明：pH值及温度的升高可以明显提高反应速率.MTBE降解过程符合拟一级动力学.当pH为6.5时,速率常数k为1.20×106exp(- 40.5/ RT)....
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| Format: | Article |
| Language: | zho |
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Zhejiang University Press
2009-01-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/10.3785/j.issn.1008-9497.2009.01.017 |
| _version_ | 1797236186971897856 |
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| author | HUQin-hai(胡勤海) ZHANGXin-qing(张杏青) MAOKe-hui(毛柯辉) WULi-li(武丽丽) WANGDan(王丹) |
| author_facet | HUQin-hai(胡勤海) ZHANGXin-qing(张杏青) MAOKe-hui(毛柯辉) WULi-li(武丽丽) WANGDan(王丹) |
| author_sort | HUQin-hai(胡勤海) |
| collection | DOAJ |
| description | 近年来汽油添加剂甲基叔丁基醚(MTBE)对环境造成的持久性的危害已越来越受到人们的重视.地下水中MTBE的污染主要是常见于通过地下储藏罐或管道渗漏造成.本文试验研究探讨了O3/H2O2氧化MTBE的降解过程及反应动力学.结果表明：pH值及温度的升高可以明显提高反应速率.MTBE降解过程符合拟一级动力学.当pH为6.5时,速率常数k为1.20×106exp(- 40.5/ RT). |
| first_indexed | 2024-04-24T16:59:52Z |
| format | Article |
| id | doaj.art-cae483b5b2504bca869818843807823f |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T16:59:52Z |
| publishDate | 2009-01-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-cae483b5b2504bca869818843807823f2024-03-29T01:58:26ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972009-01-01361808310.3785/j.issn.1008-9497.2009.01.017Degradation kinetic of Methyl Tert-Butyl Ether (MTBE)by O3/ H2O2(O3/ H2O2对MTBE的氧化降解动力学研究)HUQin-hai(胡勤海)0ZHANGXin-qing(张杏青)1MAOKe-hui(毛柯辉)2WULi-li(武丽丽)3WANGDan(王丹)4College of Environmental and Resource, Zhejiang University, Hangzhou 310029, China(浙江大学环境与资源学院，浙江 杭州 310029)College of Environmental and Resource, Zhejiang University, Hangzhou 310029, China(浙江大学环境与资源学院，浙江 杭州 310029)College of Environmental and Resource, Zhejiang University, Hangzhou 310029, China(浙江大学环境与资源学院，浙江 杭州 310029)College of Environmental and Resource, Zhejiang University, Hangzhou 310029, China(浙江大学环境与资源学院，浙江 杭州 310029)College of Environmental and Resource, Zhejiang University, Hangzhou 310029, China(浙江大学环境与资源学院，浙江 杭州 310029)近年来汽油添加剂甲基叔丁基醚(MTBE)对环境造成的持久性的危害已越来越受到人们的重视.地下水中MTBE的污染主要是常见于通过地下储藏罐或管道渗漏造成.本文试验研究探讨了O3/H2O2氧化MTBE的降解过程及反应动力学.结果表明：pH值及温度的升高可以明显提高反应速率.MTBE降解过程符合拟一级动力学.当pH为6.5时,速率常数k为1.20×106exp(- 40.5/ RT).https://doi.org/10.3785/j.issn.1008-9497.2009.01.017mtbeo3/h2o2降解动力学 |
| spellingShingle | HUQin-hai(胡勤海) ZHANGXin-qing(张杏青) MAOKe-hui(毛柯辉) WULi-li(武丽丽) WANGDan(王丹) Degradation kinetic of Methyl Tert-Butyl Ether (MTBE)by O3/ H2O2(O3/ H2O2对MTBE的氧化降解动力学研究) Zhejiang Daxue xuebao. Lixue ban mtbe o3/h2o2 降解 动力学 |
| title | Degradation kinetic of Methyl Tert-Butyl Ether (MTBE)by O3/ H2O2(O3/ H2O2对MTBE的氧化降解动力学研究) |
| title_full | Degradation kinetic of Methyl Tert-Butyl Ether (MTBE)by O3/ H2O2(O3/ H2O2对MTBE的氧化降解动力学研究) |
| title_fullStr | Degradation kinetic of Methyl Tert-Butyl Ether (MTBE)by O3/ H2O2(O3/ H2O2对MTBE的氧化降解动力学研究) |
| title_full_unstemmed | Degradation kinetic of Methyl Tert-Butyl Ether (MTBE)by O3/ H2O2(O3/ H2O2对MTBE的氧化降解动力学研究) |
| title_short | Degradation kinetic of Methyl Tert-Butyl Ether (MTBE)by O3/ H2O2(O3/ H2O2对MTBE的氧化降解动力学研究) |
| title_sort | degradation kinetic of methyl tert butyl ether mtbe by o3 h2o2 o3 h2o2对mtbe的氧化降解动力学研究 |
| topic | mtbe o3/h2o2 降解 动力学 |
| url | https://doi.org/10.3785/j.issn.1008-9497.2009.01.017 |
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